Abstract: Luminescent microspheres and a preparation method thereof are disclosed. The preparation method includes: 1) preparing cadmium oxide-doped silica microspheres; 2) adding the silica microspheres to a mixed solution of octadecene/oleic acid or trioctylamine (TOA)/oleic acid, and heating a resulting mixture to a boiling point so that the microspheres swell at high temperature and the oleic acid penetrates into the microspheres to react with CdO to obtain an organic cadmium-adsorbed silica suspension; and 3) adding a selenium precursor to the obtained organic cadmium-adsorbed silica suspension to obtain the luminescent microspheres, where, the selenium precursor reacts with the adsorbed organic cadmium to form CdSe.
Type:
Grant
Filed:
February 26, 2021
Date of Patent:
November 29, 2022
Assignee:
TIANJIN NAMEI NAMI TECHNOLOGY CO., LTD.
Inventors:
Guang Liu, Baojie Zhao, Haipeng Liu, Yi Wang
Abstract: Luminescent microspheres and a preparation method thereof are disclosed. The preparation method includes: 1) preparing cadmium oxide-doped silica microspheres; 2) adding the silica microspheres to a mixed solution of octadecene/oleic acid or trioctylamine (TOA)/oleic acid, and heating a resulting mixture to a boiling point so that the microspheres swell at high temperature and the oleic acid penetrates into the microspheres to react with CdO to obtain an organic cadmium-adsorbed silica suspension; and 3) adding a selenium precursor to the obtained organic cadmium-adsorbed silica suspension to obtain the luminescent microspheres, where, the selenium precursor reacts with the adsorbed organic cadmium to form CdSe.