Abstract: A high-performance thin-film composite polyamide membrane upcycled from a substrate fouled with a biopolymer and a preparation method thereof are provided. The method includes fouling the substrate preferably with the biopolymer to obtain a composite of the substrate and a biopolymer foulant layer; then immersing the composite into a first solution formed by dissolving a polyamine monomer in water, followed by taking the composite out of the first solution and removing excess droplets from a surface of the composite; then immersing the composite treated in the previous step into a second solution formed by dissolving an acyl chloride monomer in n-hexane for interfacial polymerization to form a rejection layer on the surface of the composite; and after completion of the reaction, taking the composite out of the second solution, followed by drying and heat treatment, to obtain the target polyamide membrane.

Abstract: A high-performance thin-film composite polyamide membrane upcycled from a substrate fouled with a biopolymer and a preparation method thereof are provided. The method includes fouling the substrate preferably with the biopolymer to obtain a composite of the substrate and a biopolymer foulant layer; then immersing the composite into a first solution formed by dissolving a polyamine monomer in water, followed by taking the composite out of the first solution and removing excess droplets from a surface of the composite; then immersing the composite treated in the previous step into a second solution formed by dissolving an acyl chloride monomer in n-hexane for interfacial polymerization to form a rejection layer on the surface of the composite; and after completion of the reaction, taking the composite out of the second solution, followed by drying and heat treatment, to obtain the target polyamide membrane.

Abstract: Disclosed is a polyvinylidene fluoride/ultra-high molecular weight polyethylene blend microporous membrane and preparation method thereof, which belongs to the field of microporous membrane. The blend microporous membrane has good hydrophobicity, mechanical properties and permeability. The preparation method includes: preparing a suspension by polyvinylidene fluoride, ultra-high molecular weight polyethylene, antioxidant and diluent; then feeding the obtained suspension into a twin-screw extruder, and the cast membrane gel extruded from the outlet is directly injected into a metal mold for injection molding; the mold temperature and the outlet temperature of the extruder are the same, and the cavity surface of the mold has micro-prism array structure; then cooling the mold in aqueous medium to obtain a nascent gel membrane; drying the obtained nascent gel membrane in a freeze dryer after removal of the diluents by extraction.

Abstract: A device for decomplexation and enhanced removal of copper based on self-induced Fenton-like reaction constructed by electrochemistry coupled with membrane separation is disclosed. The device includes a reactor, two electrocatalytic anodes capable of generating hydroxyl radicals, an electrocatalytic cathode membrane assembly, a direct current power supply, an aeration system, an inlet pipe and an outlet pipe. The device of the present invention has a simple construction. Using this device to treat industrial wastewater containing copper complexes under specific conditions allows the decomplexation and the removal of the industrial wastewater containing the copper complexes to be simultaneously realized at a low consumption and a high efficiency. The coupling of electrochemistry with membrane separation can be achieved to protect the cathode from being contaminated by pollutants in the sewage and prolong the service life of the electrode.

Abstract: A flexible electrocatalytic membrane for removing nitrate from water, a preparation method and use thereof are provided. The method of the present invention includes dropwise adding an aramid fiber solution into deionized water to prepare an aramid nanofiber sol, then reacting an ethanol solution containing 3,4-ethylenedioxythiophene and ferric nitrate with the aramid nanofiber sol to prepare a conductive aramid nanofiber sol, and finally dropwise adding MXene nanosheets ultrasonically pretreated by a tetramethylammonium hydroxide solution into the conductive aramid nanofiber sol to prepare the flexible electrocatalytic membrane. The prepared flexible electrocatalytic membrane possesses good mechanical strength and flexibility, and can not only effectively remove nitrate but also avoid failure of electrocatalytic materials due to surface fouling in the process of electrocatalytic reduction of nitrate, and thus has a long service life.

Abstract: A thin-film composite polyamide reverse osmosis membrane with anti-bacterial and anti-biofouling effects and a preparation method thereof are disclosed. The preparation method includes: dissolving a highly water-stable metal organic framework CuBTTri in an n-hexane solution containing trimesoyl chloride by ultrasonic wave, immersing a polyethersulfone ultrafiltration membrane in an aqueous solution of m-phenylene diamine and taking out, and then immersing the ultrafiltration membrane in the trimesoyl chloride-n-hexane solution containing the aforementioned metal organic framework for reaction and modification, so as to obtain the thin-film composite polyamide reverse osmosis membrane. The resulting composite reverse osmosis membrane integrated with the anti-bacterial metal organic framework CuBTTri has a high reverse osmosis membrane permeability and possesses greatly improved and persistent anti-bacterial and anti-biofouling properties.

Abstract: A nanofiltration membrane with a high flux for selectively removing hydrophobic endocrine disrupting chemicals and a preparation method thereof are provided. The method includes the following steps: immersing a porous support layer into a first solution, removing excess droplets from a surface of the support layer after taking the support layer out of the first solution, and then immersing the support layer attached with the first solution into a second solution for an interfacial polymerization reaction, followed by washing after completion of the reaction to obtain the subject nanofiltration membrane. The first solution is an aqueous solution containing a polyamine monomer and an acid binding agent, and the second solution is an organic solution containing an acid chloride monomer and a metal-organic framework.

Abstract: The invention relates to a preparation method of a polymeric phase-change material, comprising: using 1, 2 or 3 of (meth)acrylate poly(ethylene glycol) n-alkyl ether ester as a raw material, wherein the (meth)acrylate poly(ethylene glycol) n-alkyl ether ester has a structural general formula of CH2?C(CH3)—COO(CH2CH2O)mCnH2n+1 or CH2?CH—COO(CH2CH2O)mCnH2n+1, m=1 to 100, and n=10 to 50; washing the raw material with a solution of sodium hydroxide, potassium hydroxide, sodium carbonate or potassium carbonate having a mass percentage of 1% to 10% to remove a polymerization inhibitor, and subjecting reduced-pressure distillation, and then to a polymerization reaction by adopting one of the following process; 1. polymerization reaction initiated by irradiation; 2. polymerization reaction initiated by an initiator; 3.

Abstract: A composition for preparation of a hollow fiber porous membrane including 40-60 wt. % a polymer matrix, 20-30 wt. % an organic mixed solution, and 20-40 wt. % a water-soluble substance. The polymer matrix is a polymer capable of dissolving in an organic solvent and melt processing. The organic mixed solution is a mixture comprising 60-90 wt. % a first liquid soluble to the polymer matrix and 10-40 wt. % a second liquid insoluble to the polymer matrix. The water-soluble substance is a water-soluble polymer, a low molecular weight water-soluble particle, or a mixture thereof. A method for producing the hollow fiber porous membrane using the composition including a) preparing the organic mixed solution, b) mixing the components of the composition, c) applying melt spinning, d) drawing, and e) washing. The hollow fiber membrane has high strength, large flux, and low cost.

Abstract: A preparation method of a perfluorinated polymer hollow fiber membrane comprises: evenly mixing a first mixture that is mixed by a perfluorinated polymer, PS, a polymer additive, and a composite pore-forming agent; evenly mixing a second mixture that is mixed by the first mixture and an organic liquid; under 300° C.-350° C., processing the second mixture with a melt to spin by a twin-screw extruder; extruding a hollow fiber by a hollow fiber spinneret; dipping the hollow fiber membrane into deionized water for 48 hours; putting the hollow fiber membrane aired into a concentrated sulfuric acid to process with a sulfonation; washing the hollow fiber membrane by deionized water; and drying the hollow fiber membrane; in such a manner that the hydrophilic perfluorinated polymer hollow fiber membrane is obtained.

Abstract: A method of preparing oil-absorbing fibers by: a) fully dissolving a dispersant and a deionized water in a reaction vessel, adding a methacrylate monomer and an initiator to a reactor and stirring to form a homogenous solution, transferring the homogenous solution into the reaction vessel, charging nitrogen gas, stirring, raising temperature to 70-80° C., allowing to react for 2-6 hours, raising temperature to 90-100° C., allowing to react for 2-4 hours, collecting a resultant product, washing, drying, and obtaining a white resin; b) drying the white resin, mixing with a swelling agent, and sealing the mixture at room temperature for 48-96 hours to yield a homogenous gel; c) grinding the gel completely, spinning by a plunger spinner, and coagulating with a coagulation bath to yield an as-spun oil-absorbing fiber; and d) drawing the as-spun oil-absorbing fiber with a draw ratio of 2-6 to yield oil-absorbing fibers.