Abstract: An initiator for cationic polymerization comprises a salt of a protic acid as well as a protic add. The molar ratio of protic acid to salt is in the range from 1:0.01 to 1:2000. The initiator is used for example for cationic homo- or copolymerization of trioxane, and permits stable and flexible operation of the polymerization.
Type:
Application
Filed:
April 7, 2014
Publication date:
August 7, 2014
Applicant:
Ticona GmbH
Inventors:
MICHAEL HOFFMOCKEL, Michael Haubs, Horst Roschert
Abstract: A polyoxymethylene polymer is disclosed that contains long-chain alkylene glycol end groups. The polyoxymethylene polymer may be formed by using a Bis-oligo-alkylene glycol-formal as a chain transfer agent during production of the polymer. The end groups on the polyoxymethylene polymer may comprise ethylene oxide end groups and/or propylene oxide end groups. The resulting polymer has excellent flow characteristics and may be used as a flow additive for other thermoplastic polymers. Alternatively, the polymer may be used to form various molded articles with excellent tribological properties.
Abstract: A polyoxymethylene polymer is disclosed that contains long-chain alkyl end groups. The polyoxymethylene polymer may be formed by using a Bis-alkylformal as a chain transfer agent during production of the polymer. In one embodiment, the Bis-alkylformal is dissolved in a monomer, such as trioxane, during production of the polymer. In one embodiment, a branching agent may also be present with one or more monomers for producing a branched polyoxymethylene polymer. In this manner, greater amounts of alkyl end groups can be incorporated into the polymer. The resulting polymer has excellent flow characteristics. The polymer may be used to form various molded articles with excellent tribological properties.
Type:
Application
Filed:
December 20, 2013
Publication date:
July 3, 2014
Applicant:
Ticona GmbH
Inventors:
Andre Hebel, Michael Haubs, Ursula Ziegler
Abstract: The present disclosure relates to a molding composition and to molded products made from the composition. In accordance with the present disclosure, the polymer composition contains a polyoxymethylene copolymer having a relatively low amount of comonomer units. The polyoxymethylene polymer is combined with at least one reinforcing fiber and a coupling agent. The above polymer produces a composition have a relatively high heat deflection temperature, while also having excellent mechanical properties.
Abstract: Oxymethylene polymers having a bimodal distribution or having a distribution of higher modality and having a targeted content of a low molecular weight fraction of from 1 to 5 percent by mass are described. Moldings of these polymers are distinguished by high low-temperature notched impact strength associated with a high modulus of elasticity.
Type:
Grant
Filed:
May 29, 2012
Date of Patent:
June 3, 2014
Assignee:
Ticona GmbH
Inventors:
Michael Haubs, Michael Hoffmockel, Jürgen Lingnau, Robert Gronner, Horst Roeschert
Abstract: In a process for producing polyethylene having a molecular weight of at least 3×105 g/mol as determined by ASTM 4020, ethylene is contacted under polymerization conditions with a slurry of a catalyst composition comprising a Group 4 metal complex of a phenolate ether ligand, wherein the slurry further includes a scavenger comprising an alkyl magnesium compound.
Type:
Grant
Filed:
July 1, 2011
Date of Patent:
May 13, 2014
Assignee:
Ticona GmbH
Inventors:
Dominique Robert, Julia Hufen, Kerstin Lüdtke, Jens Ehlers, Gary Diamond, Margarete Lecrec, Guang Zhu
Abstract: An initiator for cationic polymerization comprises a salt of a protic acid as well as a protic add. The molar ratio of protic acid to salt is in the range from 1:0.01 to 1:2000. The initiator is used for example for cationic homo- or copolymerization of trioxane, and permits stable and flexible operation of the polymerization.
Type:
Grant
Filed:
June 19, 2012
Date of Patent:
April 8, 2014
Assignee:
Ticona GmbH
Inventors:
Michael Hoffmockel, Michael Haubs, Horst Röschert
Abstract: A long-fiber-reinforced, thermoplastic molding compound of plastics material has outstanding impact strength and notched impact strength if it contains 30 to 90% by weight of at least one thermoplastic polyolefin, 9 to 69% by weight of at least one glass-like reinforcing fiber and 1 to 30% by weight of at least one mineral filler of an average particle size in the range from 0.1 to 2 ?m. The molding compound is produced by the pultrusion method and is used in the production of domestic appliances such as washing machines or washer-dryers or electrical appliances such as coffeemakers or toasters or refrigerators or in automobile construction.
Type:
Grant
Filed:
January 23, 2008
Date of Patent:
January 28, 2014
Assignee:
Ticona GmbH
Inventors:
Heinz Bernd, Bruno Wagner, Thomas Borgner, Olaf Herd
Abstract: The present invention relates to a molding composition, a process for the manufacturing of said molding composition, molded parts obtainable therefrom as well as the use of the molding composition for the manufacturing of molded parts used in the automotive industry, for housings, latches, window winding systems, wiper systems, pulleys, sun roof systems, seat adjustments, levers, gears, claws, pivot housing, brackets, wiper arms or seat rails.
Abstract: The present invention relates to a molding composition, molded parts obtainable therefrom as well as the use of the molding composition for the manufacturing of molded parts used in the automotive industry, as well as for cables, pipes, tubes, corrugated pipes, fuel pipes, air pipes, fuel hoses, break hoses, air hoses, hydraulic hoses, pneumatic hoses, pressure hoses, and connection assemblies.
Abstract: The present invention relates to a process for the preparation of oxymethylene polymers as well as oxymethylene polymers obtainable therefrom. The process includes polymerization of a monomer, which forms —CH2—O— units in the presence of an acetal of formaldehyde or a polyhydric alcohol and an initiator for cationic polymerization. The initiator may be a heteropoly acid or an acid salt thereof which is dissolved in an alkyl ester of a polybasic carboxylic acid.
Type:
Grant
Filed:
May 26, 2010
Date of Patent:
July 9, 2013
Assignee:
Ticona GmbH
Inventors:
Michael Haubs, Michael Hoffmockel, Jurgen Lingnau, Robert M. Gronner, Lowell Larson
Abstract: The present invention relates to a molding composition, a process for the manufacturing of said molding composition, molded parts obtainable therefrom as well as the use of the molding composition for the manufacturing of molded parts used in the automotive industry, for housings, latches, window winding systems, wiper systems, sun roof systems, seat adjustments, levers, gears, claws, pivot housing or wiper arms.
Abstract: In a process for producing polyethylene having a molecular weight of at least 1×106 g/mol as determined by ASTM 4020, ethylene is contacted under polymerization conditions with a slurry of a catalyst composition comprising a particulate support having an average particle size, d50, of less than 58 microns and a Group 4 metal complex of a phenolate ether ligand carried by the support.
Type:
Application
Filed:
July 1, 2011
Publication date:
April 11, 2013
Applicant:
TICONA GmbH
Inventors:
Dominique Robert, Julia Hufen, Kerstin Lüdtke, Jens Ehlers
Abstract: In a process for producing polyethylene having a molecular weight of at least 3×105 g/mol as determined by ASTM 4020, ethylene is contacted under polymerization conditions with a slurry of a catalyst composition comprising a Group 4 metal complex of a phenolate ether ligand, wherein the slurry further includes a scavenger comprising an alkyl magnesium compound.
Type:
Application
Filed:
July 1, 2011
Publication date:
April 11, 2013
Applicant:
TICONA GMBH
Inventors:
Dominique Robert, Julia Hufen, Kerstin Lüdtke, Jens Ehlers, Gary Diamond, Margarete Lecrec, Guang Zhu
Abstract: In a process for producing polyethylene having a molecular weight of at least 3×105 g/mol as determined by ASTM 4020, ethylene is contacted under polymerization conditions with a slurry of a catalyst composition in at least one hydrocarbon. The catalyst composition comprises a Group 4 metal complex of a phenolate ether ligand and the slurry includes from about 5 to less than 40 ppm per liter of a compound effective to increase the conductivity of said at least one hydrocarbon.
Type:
Application
Filed:
July 1, 2011
Publication date:
April 11, 2013
Applicant:
TICONA GMBH
Inventors:
Dominique Robert, Julia Hufen, Kerstin Lüdtke, Jens Ehlers
Abstract: In a process for producing an elongated polyethylene component, such as a fiber or membrane, polyethylene powder having a molecular weight of at least 3×105 g/mol as determined by ASTM 4020 is dissolved in a solvent to produce an extrudable solution. The solution is then extruded through a die to form an elongated component and at least part of said solvent is removed from the elongated component. The polyethylene powder used in the process is produced by polymerizing ethylene in the presence of a catalyst composition comprising a Group 4 metal complex of a phenolate ether ligand.
Type:
Application
Filed:
July 1, 2011
Publication date:
March 28, 2013
Applicant:
TICONA GMBH
Inventors:
Dominique Robert, Julia Hufen, Kerstin Lüdtke, Jens Ehlers
Abstract: Ultra-high molecular weight polyethylene has a molecular weight greater than 20×106 gm/mol as determined by ASTM 4020 or by size exclusion chromatography (SEC) and is produced by polymerizing ethylene with a catalyst composition comprising a Group 4 metal complex of a phenolate ether ligand.
Type:
Application
Filed:
July 1, 2011
Publication date:
March 21, 2013
Applicant:
TICONA GmbH
Inventors:
Kerstin Lüdtke, Jens Ehlers, Dominique Robert
Abstract: In a process for producing high molecular weight polyethylene, ethylene is contacted with a slurry of a catalyst composition comprising a Group 4 metal complex of a phenolate ether ligand under polymerization conditions comprising a temperature of about 20° C. to less than 90° C. and a pressure of about 4 bar to about 40 bar.
Abstract: A shaped article, suitable for in a prosthetic device, is formed of polyethylene having a molecular weight of at least 3×105 g/mol as determined by ASTM 4020, and has a yield strength greater than 20 as determined by DIN EN ISO 527. The polyethylene is produced by polymerizing ethylene in the presence of a catalyst composition comprising a Group 4 metal complex of a phenolate ether ligand.
Type:
Application
Filed:
July 6, 2011
Publication date:
March 14, 2013
Applicant:
TICONA GMBH
Inventors:
Dominique Robert, Julia Hufen, Kerstin Lüdtke, Christian Meermann, Jens Ehlers
Abstract: The present invention relates to a plastics composite encompassing at least one hard component whose modulus of elasticity is greater than or equal to 1000 MPa and one soft component whose modulus of elasticity is less than or equal to 500 MPa, where the hard and the soft component have electrical conductivity, and where the bond strength of the composite is at least 0.5 N/mm2.