Abstract: A colored composition comprising: a) NIR scattering TiO2 particulate material with an average crystal size of greater than 0.40 ?m and a particle size distribution such that 30% or more of the particles are less than 1 ?m; b) one or more non-white colorant; wherein the particulate material and the non-white colorant are dispersed within a vehicle. This material with a large crystal size has unusually high reflection of NIR radiation and, simultaneously, noticeably diminished reflectance of visible light. Also disclosed is a coated particulate TiO2 material, wherein the material has an average crystal size of greater than 0.40 ?m, and the coating comprises one or more oxide material; this provides low levels of photocatalytic activity that were previously unattainable. This coated TiO2 material may be provided in a composition.

Abstract: The invention provides a method of characterizing a scattering colored pigment for use in the determination of the absorption and scattering coefficients of the scattering colored pigment, the method comprising the step of obtaining a reflectance spectrum of a mixture of the scattering colored pigment with a substantially non-absorbing scattering pigment at a plurality of different volume fractions wherein the substantially non-absorbing scattering pigment has a particle size greater than 0.6 micron. Also provided is a pigment characterization system adapted to perform the method of the invention to characterize a scattering colored pigment.

Abstract: A colored composition comprising: a) NIR scattering TiO2 particulate material with an average crystal size of greater than 0.40 ?m and a particle size distribution such that 30% or more of the particles are less than 1 ?m; b) one or more non-white colorant; wherein the particulate material and the non-white colorant are dispersed within a vehicle. This material with a large crystal size has unusually high reflection of NIR radiation and, simultaneously, noticeably diminished reflectance of visible light. Also disclosed is a coated particulate TiO2 material, wherein the material has an average crystal size of greater than 0.40 ?m, and the coating comprises one or more oxide material; this provides low levels of photocatalytic activity that were previously unattainable. This coated TiO2 material may be provided in a composition.

Abstract: The invention provides a layered colored solar reflective system comprising (i) a first layer comprising a first particulate material having a substantially rutile crystal habit and an average particle size within a range of about 0.55 ?m and about 0.95 ?m, dispersed in a vehicle and (ii) a second layer positioned on at least a portion of the first layer, the second layer comprising a second particulate material having a substantially rutile crystal habit and an average particle size within a range of about 1.0 ?m and 1.6 ?m, and a colorant dispersed in a vehicle. The layered color solar reflective system may be applied onto a structure to provide a dark, intense color as well as enhanced total solar reflectance.

Abstract: A process for forming a coating layer on a substrate comprising: depositing a thin film of a concentrated aqueous nano titania sol onto at least a portion of the substrate; exposing at least a portion of the deposited film to a sufficient amount of ultraviolet radiation in order to gel the film of aqueous sol; and drying at least a portion of the gelled portion, thereby forming the coating layer.

Abstract: The invention provides a layered colored solar reflective system comprising (i) a first layer comprising a first particulate material having a substantially rutile crystal habit and an average particle size within a range of about 0.55 ?m and about 0.95 ?m, dispersed in a vehicle and (ii) a second layer positioned on at least a portion of the first layer, the second layer comprising a second particulate material having a substantially rutile crystal habit and an average particle size within a range of about 1.0 ?m and 1.6 ?m, and a colorant dispersed in a vehicle. The layered color solar reflective system may be applied onto a structure to provide a dark, intense color as well as enhanced total solar reflectance.

Abstract: The invention provides a process for the production of ferrous sulphate monohydrate which comprises: (a) reacting a source of iron with an aqueous solution of sulphuric acid in at least a first reaction vessel, to obtain a process liquor comprising ferrous sulphate and acid solution; and then (b) combining the process liquor with concentrated sulphuric acid in a mixing vessel, causing the solution to self crystallize, thus forming a slurry comprising crystalline ferrous sulfate monohydrate. The slurry can, if desired, then be converted to ferric sulphate.

Abstract: The present invention provides a colored solar reflective system comprising (1) a particulate material having a substantially rutile crystal habit and having an average particle size of between about 0.5 ?m and about 2.0 ?m and (2) an organic pigment having a maximum absorption coefficient of about 5,000 mm?1 or greater in the visible light region, a maximum scattering coefficient of about 500 mm?1 or less in the visible light region and an average absorption coefficient of about 50 mm?1 or less in the infrared region. The solar reflective system, which may be used in a coating composition or as a composition from which articles can be formed, exhibits a dark, intense color while also providing enhanced total solar reflectance.

Abstract: The present invention provides a process for producing a concentrated aqueous nano titania sol in the mild pH range (4.0 to 10.0) comprising contacting an acidic nano titania sol with a dispersant and with an alkalizing agent, and subjecting the nano titania sol to membrane filtration until the nano titania sol contains more than 300 g TiO2 nanoparticles/dm3. The nano titania sol may further be subjected to a coating treatment within any of the steps of the above described process. The concentrated aqueous nano titania sol of this disclosure is suitable for use in a variety of applications, including providing UV protection and photochemically degrading or inactivating contaminants.

Abstract: A coloured composition comprising: a) NIR scattering TiO2 particulate material with an average crystal size of greater than 0.40 ?m and a particle size distribution such that 30% or more of the particles are less than 1 ?m; b) one or more non-white colorant; wherein the particulate material and the non-white colorant are dispersed within a vehicle. This material with a large crystal size has unusually high reflection of NIR radiation and, simultaneously, noticeably diminished reflectance of visible light. Also disclosed is a coated particulate TiO2 material, wherein the material has an average crystal size of greater than 0.40 ?m, and the coating comprises one or more oxide material; this provides low levels of photocatalytic activity that were previously unattainable. This coated TiO2 material may be provided in a composition.