Patents Assigned to Toa Nenryo Kogyo Kabushiki Kaisha
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Patent number: 4844343Abstract: An ultrasonic vibrator horn for use with ultrasonic atomizing apparatus for atomizing liquids, such as liquid fuels, employed in gasoline engines, diesel engines, gas turbines and various combustors such as industrial, commercial and domestic boilers. The ultrasonic vibrator horn has a body portion connected at one axial end thereof to an ultrasonic vibration generating means. The other axial end of the body, at which atomization of liquid material fed to the horn takes place when the horn is driven by the vibration generating means, is of conical shape. The body has at least one external groove formed in it. The groove communicates with the conical end of the body for receiving the liquid material and directing it to the conical end.Type: GrantFiled: July 30, 1987Date of Patent: July 4, 1989Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Hitoshi Kurokawa, Kouji Nakayama, Hirokazu Takenaka
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Patent number: 4840778Abstract: Novel primarily chain inorganic polysilazanes of average molecular weight of 690 to 2000 are prepared from novel adducts of a halosilane and a base by reacting the adducts with ammonia in unreactive solvents. Silicon nitride is prepared by heating the polysilazanes at 1000.degree. to 1600.degree. C., preferably below 1300.degree. C., most preferably 1000.degree. to 1100.degree. C.Type: GrantFiled: November 26, 1985Date of Patent: June 20, 1989Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Mikiro Arai, Takeshi Isoda, Takuji Itoh
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Patent number: 4837193Abstract: Hydrotreating catalyst comprising silica/alumina or silica/alumina-containing carrier comprising 2 to 35 wt. % silica and Group VIII and/or Group VIB metals as hydrogenation active components is prepared by first step impregnation with at least one Group VIII metal and a second step impregnation with at least one Group VIB metal. Preferably the impregnation is via ion exchange using a complex salt, preferably an ammine or amine salt, of the metal. The carrier is characterized by a maximum of pores in 30 to 100 .ANG. range and a minimum of pores in 0 to 30 .ANG. and in 300 .ANG.+.Type: GrantFiled: August 10, 1987Date of Patent: June 6, 1989Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Ikuo Akizuki, Hiroshi Kaya, Shohei Okano, Nobuo Otake, Keiji Kumagai, Yoshihito Kaneko
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Patent number: 4833107Abstract: Fired nitride-base ceramics, i.e., silicon nitride or oxynitride, having a low carbon content and, therefore, low electrical and thermal conductivities, can be produced by heat treating a ceramic precursor comprising polysilazane, polysiloxazane or polycarbosilazane or a mixture thereof as the main ingredient in a reducing atmosphere such as hydrogen, ammonia or a gas containing these components, followed by firing.Type: GrantFiled: October 4, 1988Date of Patent: May 23, 1989Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Hiroshi Kaya, Kozaburo Tamura, Takeshi Isoda
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Patent number: 4822587Abstract: Extremely high modulus carbon fibers can be produced by carbonization at a substantially lower temperature, for example, at about 2500.degree. C. This is made possible by selectively stabilizing only an outer surface layer portion of a carbonaceous pitch-based fiber comprised mainly of optically anisotropic components, while retaining the inner portion of the fiber in a non-stabilized state and without damage to the crystallinity thereof.Type: GrantFiled: May 1, 1987Date of Patent: April 18, 1989Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Takashi Hino, Tsutomu Naito, Hiroyuki Kuroda, Eiki Tsushima, Tomio Nomura
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Patent number: 4820674Abstract: A process for preparing a hydrosilylation catalyst by dissolving chloroplatinic acid H.sub.2 PtCl.sub.6 in a cyclic ether or cyclic ester containing at least 3 carbon atoms, and maintaining the resulting solution at a temperature of at least 30.degree. C.Type: GrantFiled: January 27, 1988Date of Patent: April 11, 1989Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Kouji Shiozawa, Yoshiharu Okumura, Chihiro Imai, Nobukazu Okamoto
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Patent number: 4814313Abstract: A method for the production of a catalyst carrier for use in the polymerization of an olefin, which method comprises causing a magnesium-containing solid obtained by contact of (A) magnesium metal, (B) a halogenated hydrocarbon represented by the general formula, RX wherein R stands for an alkyl, aryl, or cycloalkyl group having 1 to 20 carbon atoms and X for a halogen atom, and (C) a compound of the general formula, X.sub.n.sup.1 M(OR.sup.1).sub.m-n wherein X.sup.1 stands for a hydrogen atom, a halogen atom, or a hydrocarbon group having 1 to 20 carbon atoms, M for a boron, carbon, silicon, aluminum, or phosphorus atom, R.sup.1 for a hydrocarbon group having 1 to 20 carbon atoms, and m for the valency of said atom M, providing that m>n.gtoreq.0 is satisfied, to contact (D) a halogen-containing alcohol.Type: GrantFiled: December 14, 1987Date of Patent: March 21, 1989Assignee: TOA Nenryo Kogyo Kabushiki KaishaInventors: Masahide Murata, Masafumi Imai, Hiroyuki Furuhashi, Kouji Maruyama, Hiroshi Ueno
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Patent number: 4814311Abstract: A method for the production of a catalyst component for use in the polymerization of an olefin, which method comprises causing a magnesium-containing solid obtained by contact of (A) magnesium metal, (B) a halogenated hydrocarbon represented by the general formula, RX, wherein R stands for an alkyl, aryl, or cycloalkyl group having 1 to 20 carbon atoms and X for a halogen atom, and (C) a compound of the general formula, X.sub.n.sup.1 M(OR.sup.1).sub.m-n, wherein X.sup.1 stands for a hydrogen atom, a halogen atom, or a hydrocarbon group having 1 to 20 carbon atoms, M for a boron, carbon, silicon, aluminum, or phosphorus atom, R.sup.1 for a hydrocarbon group having 1 to 20 carbon atoms, and m for the valency of said atom M, providing that m>n.gtoreq.0 is satisfied, to contact (D) a halogen-containing alcohol and then contact (E) a titanium compound.Type: GrantFiled: December 14, 1987Date of Patent: March 21, 1989Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Masahide Murata, Masafumi Imai, Hiroyuki Furuhashi, Kouji Maruyama, Hiroshi Ueno
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Patent number: 4814312Abstract: A method for the production of a catalyst component for use in the polymerization of an olefin, which method comprises causing a magnesium-containing solid obtained by contact of (A) magnesium metal, (B) a halogenated hydrocarbon represented by the general formula, RX [wherein R stands for an alkyl, aryl, or cycloalkyl group having 1 to 20 carbon atoms and X for a halogen atom], and (C) a compound of the general formula, X.sub.n.sup.1 M(OR.sup.1).sub.m-n [wherein X.sup.1 stands for a hydrogen atom, a halogen atom, or a hydrocarbon group having 1 to 20 carbon atoms, M for a boron, carbon, silicon, aluminum, or phosphorus atom, R.sup.1 for a hydrocarbon group having 1 to 20 carbon atoms, and m for the valency of said atom M, providing that m>n.gtoreq.0 is satisfied], to contact (D) a halogen-containing alcohol and then contact (E) an electron donor type compound and (F) a titanium compound.Type: GrantFiled: December 14, 1987Date of Patent: March 21, 1989Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Masahide Murata, Masafumi Imai, Hiroyuki Furuhashi, Kouji Maruyama, Hiroshi Ueno
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Patent number: 4812634Abstract: An IC card having a plastics card body which mounts a CPU, a RAM, a ROM, a solar battery mounts also to EEPROM (electrically erasable programmable read only memory), which is used for identification of a card owner. Due to high power consumption of said EEPROM, a tandem type solar battery in which a plurality of opto-electric conversion cells are laminated on a substrate is used. The present IC card can operate with only the solar battery mounted inside of the IC card, and has no secondary battery.Type: GrantFiled: July 12, 1988Date of Patent: March 14, 1989Assignees: Oki Electric Industry Co., Ltd., Toa Nenryo Kogyo Kabushiki KaishaInventors: Satoshi Ohta, Kouzi Tanagawa, Hideo Yamamoto, Keiji Kumagai
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Patent number: 4795622Abstract: A silicon halide, preferably SiCl.sub.4, is reacted with an excess of a base, e.g. a Lewis base or Bronsted base with steric hindrance group to produce an adduct. The adduct, which need not be separated, is treated with ammonia gas to produce the imide of silicon. A light organic solvent is used. The temperature used is -78.degree. C. to 100.degree. C. and the reaction is rapid.Byproduct ammonium halide is removed, and the imide is heated at 1000.degree. C. to 1600.degree. C. in an oven in an atmosphere containing nitrogen, to produce silicon nitride of good sintering characteristics and more than 70 wt % of which is of the .alpha.-crystal form.Type: GrantFiled: April 24, 1986Date of Patent: January 3, 1989Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Takeshi Isoda, Mikiro Arai
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Patent number: 4794171Abstract: A calcium-phosphate type hydroxyapatite which belongs to a series of hexagonal systems has unit lattice constants of 9.58.+-.0.08 .ANG. for the a axis and 7.00.+-.0.05 .ANG. for the c axis. Its Ca/P ratio is in the range of 1.50 to 1.90. It is for use as a column packing material for chromatographic separation of biopolymers. The hydroxyapatite is produced by firing it in the form of a gel or powder at a temperature of 400.degree. to 700.degree. C. As a gel the hydroxyapatite takes the form of a suspension or slurry. A powder is prepared by removing moisture from the hydroxyapatite in the gel form and then drying. Either gel or powder is fired by heating in the presence of oxygen or air at 500.degree. to 600.degree.0 C.Type: GrantFiled: September 22, 1986Date of Patent: December 27, 1988Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Nobuaki Tagaya, Hideyuki Kuwahara, Takao Hashimoto, Noriko Komatsu, Keiko Fukamachi, Tsugio Maeshima
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Patent number: 4788261Abstract: A polyarylene sulfide resin composition with an improved moldability and heat resistance is provided which comprises (a) 40 to 99% by weight of a polyarylene sulfide resin and (b) 1 to 60% by weight of a polyparabanic acid having the following recurring unit: ##STR1## wherein Z and Z.sup.1 are oxygen atoms or NH group, Z and Z.sup.1 being not simultaneously NH groups, and R is ##STR2## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are hydrogen atoms or methyl groups, and X and X.sup.1 are bonds, CH.sub.2 groups, oxygen atoms, sulfur atoms, SO.sub.Type: GrantFiled: July 27, 1987Date of Patent: November 29, 1988Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Yoshio Taguchi, Youichi Imai, Tadashi Niwa, Masayuki Kato, Chihiro Imai
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Patent number: 4783003Abstract: An ultrasonic injection nozzle includes an ultrasonic vibration generating device and a vibrating element. The vibrating element; connected to the vibration generating device so as to be vibrated thereby. The vibrating element has formed at its forward end an edged portion to and along which a liquid material is delivered to be atomized.Type: GrantFiled: March 3, 1987Date of Patent: November 8, 1988Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Hideo Hirabayashi, Masami Endo, Kakuro Kokubo
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Patent number: 4781947Abstract: A sizing agent for a carbon fiber comprized mainly of an unsaturated urethane compound produced by a reaction of an unsaturated alcohol with an isocyanate which is able to couple the carbon fiber with an unsaturated polyester resin or vinylester resin is disclosed. The preferably unsaturated alcohols are allylalcohols and reaction products of an unsaturated carboxylic acids with an alkyleneoxides.Type: GrantFiled: August 12, 1987Date of Patent: November 1, 1988Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Makoto Saito, Hiroshi Toki, Makoto Miyazaki, Hiroshi Inoue
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Patent number: 4775651Abstract: Silanes are produced by the disproportionation and/or redistribution reaction of chlorosilanes using a novel catalyst having a longer life and consisting of a quaternary phosphonium salt bonded to an organic macromolecule or polymer, represented by the following general formula: ##STR1## wherein .circle.P.circle. is an organic macromolecule or polymer, A is a bridging group between phosphorus and the organic macromolecule or polymer, R.sup.1, R.sup.2 and R.sup.3 are selected from the group consisting of hydrogen, C.sub.1 -C.sub.20 alkyl groups and aralkyl groups such as benzyl and phenethyl groups, which can contain oxygen or halogen atoms, and X is a halogen atom.Type: GrantFiled: November 17, 1987Date of Patent: October 4, 1988Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Mamoru Tachikawa, Kazutoshi Takatsuna, Kouji Shiozawa, Yoshiharu Okumura, Takeo Koyama
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Patent number: 4756478Abstract: The present invention is directed to the combination of a vibrating element and an ultrasonic nozzle having an ultrasonic vibrator. The combination includes a body having a liquid supply passage therethrough and a chamber having a first and second end. The liquid supply passage is in communication with the chamber via its first end. The second end of the chamber defines an opening. An inner peripheral wall forms a portion of the chamber intermediate the first and second end. A multistepped edged portion is formed on the inner peripheral wall and each step defines an edge which severs and atomizes the liquid which cascades thereover from the liquid passage.Type: GrantFiled: December 6, 1985Date of Patent: July 12, 1988Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Masami Endo, Kakuro Kokubo, Hideo Hirabayashi, Yoshinobu Nakamura, Daijiro Hosogai
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Patent number: 4754006Abstract: A process for producing catalyst ingredient for use in olefin polymerization which comprises contacting (A) a magnesium hydrocarbyloxide and (B) a silicon compound having hydrogen-silicon bonds in the presence of a hydrocarbon medium, contacting the thus obtained solid product with (C) a halogenated titanium compound in the presence or absence of a hydrocarbon medium and then adding to contact (D) an electron donating compound.Type: GrantFiled: August 3, 1987Date of Patent: June 28, 1988Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Masahide Murata, Hiroyuki Furuhashi, Masafumi Imai, Hiroshi Ueno
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Patent number: 4743494Abstract: A process for producing a hydrophilic polyolefin nonwoven fabric which comprises treating with a plasma a nonwoven fabric composed of fibers of a polyolefin containing more than 0.1 parts by weight of hindered amine compound for 100 parts by weight of polyolefin.Type: GrantFiled: December 1, 1986Date of Patent: May 10, 1988Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Masato Komatsu, Kiyotada Narukawa, Noboru Yamamoto
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Patent number: RE32792Abstract: A substantially uniform mesophase pitch is prepared by treating a mesophase forming pitch material at elevated temperatures above about 380.degree. C. to produce a mixture of mesophase and non-mesophase pitch containing about 20% to about 80% mesophase. The mixture is then maintained at a temperature below about 400.degree. C. for a time sufficient to allow the mesophase to coalesce and settle as a lower separable layer. A mesophase pitch so produced may contain from 90 to 100% mesophase with a softening point of less than 320.degree. C.Type: GrantFiled: November 3, 1986Date of Patent: November 29, 1988Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Takayuki Izumi, Tsutomu Naito, Seiko Igarashi