Patents Assigned to Toa Nenryo Kogyo Kabushiki Kaisha
  • Patent number: 4426498
    Abstract: An improved polyethylene composition is disclosed. The composition comprises linear low density polyethylene (an ethylene/alpha-olefin copolymer) and a synthetic rubber. In one embodiment the composition includes a synthetic rubber reacted with a carboxylic acid.
    Type: Grant
    Filed: March 18, 1982
    Date of Patent: January 17, 1984
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Hiroshi Inoue, Masaaki Isoi, Kazuo Sei
  • Patent number: 4426314
    Abstract: According to a first aspect of this invention, there is provided A magnesium-containing solid, obtained by contacting the reaction product of (1):(A) metallic magnesium;(B) a halogenated hydrocarbon of the general formula RX in which R stands for an alkyl, aryl or cycloalkyl group having 1 to 20 carbon atoms, and X stands for a halogen atom; and(C) an alkoxy compound of the general formula X'.sub.m C(OR').sub.4-m in which X' stands for a hydrogen or halogen atom, or an alkyl, aryl or cycloalkyl group having 1 to 10 carbon atoms, R' stands for an alkyl, aryl or cycloalkyl group having 1 to 20 carbon atoms, and m is 0, 1 or 2, with (2) an electron donative compound and hydrogen halide. The supported transition metal in combination with an organoaluminum co-catalyst is employed as an olefin polymerization catalyst.
    Type: Grant
    Filed: November 10, 1981
    Date of Patent: January 17, 1984
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Makoto Miyazaki, Takeshi Nomura, Chihiro Imai, Makoto Yoda
  • Patent number: 4422924
    Abstract: An improved dewaxing aid for solvent dewaxing process comprising a mixture of (A) an .alpha.-olefin polymer having an average molecular weight of from about 10,000 to 1,000,000 and a wide molecular weight distribution exceeding the range of from about 10,000 to 1,000,000 but falling within the range of from about 2,000 to 3,000,000 wherein the .alpha.-olefin polymer is a homopolymer made up of a C.sub.10 to C.sub.25 alpha-olefin monomer or is a copolymer made up of a monomer mixture comprising more than 50 wt. % of at least 2 C.sub.10 to C.sub.25 alpha-olefin monomers and a melt index greater than 1.8 g/10 min. and (B) an olefin vinyl acetate copolymer having a vinyl acetate content of from about 15 to 40 wt. % and an average molecular weight of from about 50,000 to 1,000,000 and a melt index greater than 2 g/10 min. The .alpha.
    Type: Grant
    Filed: August 23, 1982
    Date of Patent: December 27, 1983
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Takashi Onodera, Kikuji Komine, Fumis Ohashi, Tsutomu Naito
  • Patent number: 4417019
    Abstract: An improved molding compound comprising a polyolefin modified with an unsaturated carboxylic acid, and has dispersed therein a filler material comprising a mixture of glass fiber and calcium silicate. In one embodiment the molding compound also includes an ethylene-.alpha.-olefin copolymer rubber.
    Type: Grant
    Filed: August 5, 1982
    Date of Patent: November 22, 1983
    Assignee: TOA Nenryo Kogyo Kabushiki Kaisha
    Inventors: Noboru Yamamoto, Keiichi Morikubo, Masato Komatsu, Kazuo Sei
  • Patent number: 4409282
    Abstract: A bulky nonwoven fabric comprises fine fibers forming thin intertwined layers extending between one surface of the fabric and the other surface, that is, the layered fibers run in the direction of thickness of the fabric. The nonwoven fabric of thermoplastic resin is prepared by a melt-blowing process utilizing a drum collector and cooperating nip-roll. If desired the fiber and gas stream may be contacted with fine liquid drops.
    Type: Grant
    Filed: July 22, 1982
    Date of Patent: October 11, 1983
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Shigeo Fujii, Tokuzo Ikeda, Takashi Mikami, Shuji Okano
  • Patent number: 4402863
    Abstract: According to this invention, there is provided a magnesium-containing solid, obtained by contacting the reaction product of (1):a magnesium-containing solid, obtained by contacting the reaction product of:(a) metallic magnesium;(b) a halogenated hydrocarbon of the general formula RX in which R stands for an alkyl, aryl or cycloalkyl group having 1 to 20 carbon atoms, and X stands for a halogen atom; and(c) an alkoxy compound of the general formula X'.sub.m C(OR').sub.4-m in which X' stands for a hydrogenor halogen atoms, or an alkyl, aryl or a cycloalkyl group having 1 to 10 carbon atoms, R' stands for an alkyl, aryl or cycloalkyl group having 1 to 20 carbon atoms and m is 0, 1 or 2, with (2) an organic aluminum compound.The magnesium-containing solid is employed as a carrier for a transition metal halide. The supported transition metal halide in combination with an aluminum alkyl cocatalyst such as aluminum triethyl is usefully employed for the polymerization of olefins.
    Type: Grant
    Filed: November 10, 1981
    Date of Patent: September 6, 1983
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Makoto Miyazaki, Takeshi Nomura, Chihiro Imai, Makoto Yoda
  • Patent number: 4401799
    Abstract: A titanium trichloride catalytic complex is produced by reducing titanium tetrachloride with an organo-metal compound and then treating the resulting reduced solids product with a chlorinated saturated aliphatic hydrocarbon having three to eight carbon atoms in the presence of a complexing agent. The resulting titanium trichloride complex composition, when employed as a co-catalyst with an organo-metal compound for Ziegler-type catalysts in polymerization of .alpha.-olefins, results in uniform polymer grains with unexpectedly high polymerization activity and high stereoregular polymer yielding ratios.
    Type: Grant
    Filed: July 20, 1979
    Date of Patent: August 30, 1983
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Hiroshi Ueno, Eiji Sezaki, Naomi Inaba, Tokuo Makishima, Koh Watanabe, Shozo Wada
  • Patent number: 4397788
    Abstract: This invention relates to rhodium compounds having the general formula:HRh(CO)(XR.sub.3).sub.n (YR'.sub.3).sub.3-nwherein X is phosphorus, arsenic or antimony; Y is arsenic or antimony when X is phosphorus, Y is phosphorus or antimony when X is arsenic, or Y is phosphorus, arsenic or antimony when X is antimony; R and R' are aryl groups; and n is an integer of 1 or 2. Further, it relates to a process for the preparation of aldehydes by the hydroformylation of olefins in the presence of a rhodium catalyst, and more particularly for the production of aldehydes by the reaction of olefins such as propylene with carbon monoxide and hydrogen in the presence of HRh(CO)PPh.sub.3).sub.2 (AsPh.sub.3)/excess PPh.sub.3 and AsPh.sub.3 or HRh(CO)(PPh.sub.3)(AsPh.sub.3).sub.2 /excess PPh.sub.3 and AsPh.sub.3.
    Type: Grant
    Filed: February 25, 1981
    Date of Patent: August 9, 1983
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Tadamori Sakakibara, Yoshihisa Matsushima, Yukio Nagashima, Nobukazu Okamoto, Katsumi Kaneko, Yohio Ishii, Shozo Wada
  • Patent number: 4390671
    Abstract: A supported titanium catalyst component is produced by cogrinding an organo aluminum catalyst component with a supported titanium (IV) halide on a magnesium halide. The resulting supported titanium halide catalyst component, when employed with an organo aluminum catalyst component to form a catalyst system is highly useful for the stereoregular polymerization of .alpha.-olefins as well as the copolymerization of .alpha.-olefins.
    Type: Grant
    Filed: September 26, 1980
    Date of Patent: June 28, 1983
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Masafumi Imai, Hiroshi Ueno, Naomi Inaba, Makoto Yoda, Shozo Wada
  • Patent number: 4375446
    Abstract: A process for producing a thermoplastic nonwoven fabric having a uniform thickness and optionally napped fibers according to a melt blowing method, which comprises blowing a fiber stream consisting of melt blown fibers and a gas at a high speed onto a plate within a valley-like fiber-collecting zone formed by two plates having a large number of pores, to form a uniform nonwoven fabric without scattering fibers.
    Type: Grant
    Filed: December 21, 1979
    Date of Patent: March 1, 1983
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Shigeo Fujii, Tokuzo Ikeda, Takashi Mikami, Shuji Okano
  • Patent number: 4370257
    Abstract: A process for producing a magnesium containing support for titanium comprising contacting magnesium metal, a halogenated hydrocarbon and a compound represented by the formula X'.sub.m C(OR').sub.4-m wherein X' is a hydrogen atom, a halogen atom or a C.sub.1 -C.sub.10 alkyl, aryl, cycloalkyl or halogenated alkyl, aryl, cycloalkyl group, R' is a C.sub.1 -C.sub.20 alkyl, aryl or cycloalkyl group and m is 0, 1 or 2 to form a magnesium-containing solid represented by the formula R'OMgX and thereafter contacting the magnesium-containing solid with a Lewis base or a compound which can form an ester such as benzoyl chloride and a titanium compound such as titanium tetrachloride. The obtained magnesium supported titanium composition is useful as a catalyst component in combination with a co-catalyst organoaluminum compound for the polymerization of olefins.
    Type: Grant
    Filed: August 11, 1980
    Date of Patent: January 25, 1983
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Masafumi Imai, Hiroshi Ueno, Naomi Inaba, Makoto Yoda, Shozo Wada
  • Patent number: 4358626
    Abstract: Secondary alcohols are produced by the hydration of a n-olefin substantially free from an isoolefin in the presence as catalyst of an acidic cation exchange resin such as a sulfonated styrene-divinylbenzene copolymer and in the presence of an oxy acid or lactone thereof such as .gamma.-valerolactone. The process is especially useful for hydrating a n-butene feed or a feed consisting essentially of n-butenes and butane to produce secondary butyl alcohol.
    Type: Grant
    Filed: August 6, 1981
    Date of Patent: November 9, 1982
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Yoshiharu Okumura, Tadamori Sakakibara, Katsumi Kaneko
  • Patent number: 4358621
    Abstract: Described is an olefin hydroformylation process for producing aldehydes utilizing a Pt Group IV-A organometallic catalyst mixture such as (PPh.sub.3).sub.2 PtPh-SnPh.sub.2 Cl/SnCl.sub.2. High yields of aldehydes are produced in high selectivity for the normal isomer, especially when using propylene as the olefin.
    Type: Grant
    Filed: May 26, 1981
    Date of Patent: November 9, 1982
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Tadamori Sakakibara, Yoshihisa Matsushima, Katsumi Kaneko
  • Patent number: 4354961
    Abstract: A method of preparing a catalyst for the diacyloxylation of conjugated dienes such as butadiene by reaction with a carboxylic acid such as acetic acid and oxygen, which comprises separately and successively impregnating a carrier, for example carbon, with a solution of a Group VIII noble metal in a mixture of a mineral acid and an organic solvent, then with a solution of a Group IVA, VA or VIA element or compound thereof in an organic solvent.
    Type: Grant
    Filed: November 21, 1980
    Date of Patent: October 19, 1982
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Setsuo Kamiyama, Kouji Shiozawa, Eiichiro Nishikawa, Katsumi Kaneko
  • Patent number: 4354003
    Abstract: An improved dewaxing aid for solvent dewaxing process comprising a mixture of (A) an .alpha.-olefin polymer having an average molecular weight of from about 10,000 to 1,000,000 and a wide molecular weight distribution exceeding the range of from about 10,000 to 1,000,000 but falling within the range of from about 2,000 to 3,000,000 wherein the .alpha.-olefin polymer is a homopolymer made up of a C.sub.10 to C.sub.25 alpha-olefin monomer or is a copolymer made up of a monomer mixture comprising more than 50 wt. % of at least 2 C.sub.10 to C.sub.25 alpha-olefin monomers and a melt index greater than 1.8 g/10 min. and (B) an olefin vinyl acetate copolymer having a vinyl acetate content of from about 15 to 40 wt. % and an average molecular weight of from about 50,000 to 1,000,000 and a melt index greater than 2 g/10 min. The .alpha.
    Type: Grant
    Filed: September 28, 1981
    Date of Patent: October 12, 1982
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Takashi Onodera, Kikuji Komine, Fumis Ohashi, Tsutomu Naito
  • Patent number: 4348507
    Abstract: A supported titanium catalyst is produced by cogrinding, in combination, a magnesium halide, tetravalent titanium halide, organic acid ester, and an organic halogen compound. The resulting supported titanium catalyst, when employed as a titanium component with an organo aluminum catalyst component for the catalyst system in a process for stereoregular polymerization of .alpha.-olefins, produces high polymerization activity and unexpectedly high stereoregular polymer yielding ratios.
    Type: Grant
    Filed: July 28, 1980
    Date of Patent: September 7, 1982
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Hiroshi Ueno, Masafumi Imai, Naomi Inaba, Makoto Yoda, Shozo Wada
  • Patent number: 4339619
    Abstract: In a solvent dewaxing process wherein a waxy hydrocarbon oil is mixed with a dewaxing aid and dewaxing solvent and chilled to form a slurry comprising solid particles of wax and a mixture of dewaxed oil and solvent, the improvement which comprises using a polymeric dewaxing aid comprising a condensation product of naphthalene and chlorinated wax having an average molecular weight ranging from about 20,000 to 500,000 and a molecular weight distribution exceeding the range of from about 10,000 to 1,000,000.
    Type: Grant
    Filed: August 21, 1980
    Date of Patent: July 13, 1982
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Takashi Onodera, Kikuji Komine, Fumio Ohashi, Tsutomo Naito
  • Patent number: 4338228
    Abstract: A polyolefin composition comprising a modified polyolefin obtained by adding an unsaturated carboxylic acid or an anhydride thereof to a polyolefin or mixtures of said modified polyolefin and an unmodified polyolefin, an inorganic filler, one or more nucleating agents or a combination thereof with one or more heat deterioration inhibitors, said polyolefin composition evidencing reduced deterioration by heat or reduction of its mechanical strength during a molding operation.
    Type: Grant
    Filed: October 7, 1980
    Date of Patent: July 6, 1982
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Hiroshi Inoue, Masaaki Isoi, Makoto Yoda, Masato Komatsu
  • Patent number: 4335015
    Abstract: A supported titanium catalyst, adaptable for use in the polymerization of alpha-olefins, is produced by treating a supported titanium-containing solid obtained by co-pulverization of a magnesium halide, a tetravalent titanium halide which may also comprise an electron donor compound and/or a halogen compound with an organohalogen compound. The component is thereafter treated with an organoaluminum compound and an electron donor compound. The resulting supported titanium catalyst, one employed as a titanium component with an organoaluminum catalyst component results in a catalyst system useful for the polymerization of alpha-olefins and particularly alpha-olefins.
    Type: Grant
    Filed: June 23, 1980
    Date of Patent: June 15, 1982
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Masafumi Imai, Hiroshi Ueno, Naomi Inaba
  • Patent number: 4327231
    Abstract: Tertiary alcohols are produced by the hydration of an isoolefin in the presence as catalyst of an acidic cation exchange resin such as a sulfonated styrene-divinylbenzene copolymer, and a polyhydric neo-type alcohol such as neopentyl glycol. The process is useful for separating isobutylene from a hydrocarbon mixture containing its isomers via preparation of the alcohol, separation from the unreacted hydrocarbons and dehydration of the tertiary butyl alcohol to isobutylene.
    Type: Grant
    Filed: March 3, 1980
    Date of Patent: April 27, 1982
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Yoshiharu Okumura, Hiroshi Furukawa, Katsumi Kaneko