Patents Assigned to Toho Beslon Co., Ltd.
  • Patent number: 4753777
    Abstract: A method for producing carbon fibers in a vertical carbonizing furnace and an apparatus for producing carbon fibers using such a method are disclosed. The furnace includes a heating chamber for carbonizing fibers, the furnace including,(i) a fiber inlet at the upper end of the chamber(ii) an air tight sealed fiber outlet at the lower end of the furnace,(iii) an inert gas inlet provided on the wall of the chamber and above the fiber outlet,(iv) at least one inert gas injection portion, formed on the wall of the chamber, each capable of forming a curtain of inert gas across the heating chamber, each injection portion being provided between the gas inlet and the fiber inlet,(v) at least one outlet each being provided below each inert gas injection portion, and(vi) a heating member capable of controlling the temperature in the heating chamber in such a manner that the temperature gradually increases from the upper end toward a lower end of the heating chamber.
    Type: Grant
    Filed: June 12, 1985
    Date of Patent: June 28, 1988
    Assignee: Toho Beslon Co., Ltd.
    Inventors: Osamu Yoshinari, Makoto Sugiyama, Hideki Nakai
  • Patent number: 4696742
    Abstract: Active carbon fibers derived from acrylic fibers and having a BET specific surface area (SA) of 800 to 2,000 m.sup.2 /g, a pore volume (Vp) to (SA) ratio, i.e., (Vp)/(SA), of from 5.times.10.sup.-4 to 14.5.times.10.sup.-4, and a methylene blue adsorption rate constant of not less than 5.times.10.sup.-1 sec.sup.-1, and a filter adsorption unit for water purification using said active carbon fibers; the unit is useful to remove compounds having a wide range of molecular weights from an aqueous liquid.
    Type: Grant
    Filed: January 6, 1986
    Date of Patent: September 29, 1987
    Assignee: Toho Beslon Co., Ltd.
    Inventor: Kenji Shimazaki
  • Patent number: 4677818
    Abstract: A composite rope obtained by a process comprising(1) impregnating a fiber core of a reinforcing fiber bundle with a thermosetting resin,(2) coating the outer periphery of the resin-impregnated fiber core with fibers, and(3) curing the thermosetting resin with heat.
    Type: Grant
    Filed: July 11, 1985
    Date of Patent: July 7, 1987
    Assignees: Toho Beslon Co., Ltd., Tokyo Rope Manufacturing Co., Ltd.
    Inventors: Kenji Honda, deceased, Tadaaki Sawafuji
  • Patent number: 4671950
    Abstract: A carbonaceous fiber having a carbon content of from 70 to 90%, a high tensile strength and a high modulus of elasticity, which is produced by a method which comprises preoxidizing an acrylic fiber in an oxidizing atmosphere at a temperature of from 10.degree. to 60.degree. C. below the decomposition point of said fiber, to prepare a preoxidized fiber having a degree of orientation of not less than 78% at an angle of X-ray diffraction (2.theta.) of 25.degree. and a specific gravity of from 1.30 to 1.40, pyrolyzing the preoxidized fiber in an inert gas atmosphere by passing the fiber firstly through a lower temperature zone having a temperature of not higher than 750.degree. C. and then through a higher temperature zone having a temperature of from 750.degree. to 950.degree. C., during the pyrolysis controlling the tension of the fiber so that the change of the fiber length during pyrolyzing is from +16% to -8.8% based on the length of the preoxidized fiber.
    Type: Grant
    Filed: November 14, 1985
    Date of Patent: June 9, 1987
    Assignee: Toho Beslon Co., Ltd.
    Inventors: Hiroyasu Ogawa, Tetsuro Shigei, Hiroshi Sugeno, Kazuhiro Ichimaru
  • Patent number: 4659623
    Abstract: Acrylic fibers suitable for producing preoxidized fibers free from coalescence which have a fluorine-containing surface active agent or further have at least one phosphoric surface active agent selected from the group consisting of compounds represented by the following formulae (I), (II) and (III): ##STR1## (wherein all the symbols are defined in the appended claims).
    Type: Grant
    Filed: May 14, 1984
    Date of Patent: April 21, 1987
    Assignee: Toho Beslon Co., Ltd.
    Inventors: Osamu Yoshinari, Yoshifumi Kawakatsu, Hayashi Takahashi, Hideaki Fukuizumi
  • Patent number: 4576929
    Abstract: Active carbon fibers derived from acrylic fibers and having a BET specific surface area (SA) of 800 to 2,000 m.sup.2 /g, a pore volume (Vp) to (SA) ratio, i.e., (Vp)/(SA), of from 5.times.10.sup.-4 to 14.5.times.10.sup.-4, and a methylene blue adsorption rate constant of not less than 5.times.10.sup.-1 sec.sup.-1, and a filter adsorption unit for water purification using said active carbon fibers; the unit is useful to remove compounds having a wide range of molecular weights from an aqueous liquid.
    Type: Grant
    Filed: December 18, 1984
    Date of Patent: March 18, 1986
    Assignee: Toho Beslon Co., Ltd.
    Inventor: Kenji Shimazaki
  • Patent number: 4543241
    Abstract: A method for producing carbon fibers in a vertical carbonizing furnace and an apparatus for producing carbon fibers using such a method are disclosed. The furnace includes a heating chamber for carbonizing fibers, the furnace including,(i) a fiber inlet at the upper end of the chamber(ii) an air tight sealed fiber outlet at the lower end of the furnace,(iii) an inert gas inlet provided on the wall of the chamber and above the fiber outlet,(iv) at least one inert gas injection portion, formed on the wall of the chamber, each capable of forming a curtain of inert gas across the heating chamber, each injection portion being provided between the gas inlet and the fiber inlet,(v) at least one outlet each being provided below each inert gas injection portion, and(vi) a heating member capable of controlling the temperature in the heating chamber in such a manner that the temperature gradually increases from the upper end toward a lower end of the heating chamber.
    Type: Grant
    Filed: April 18, 1983
    Date of Patent: September 24, 1985
    Assignee: Toho Beslon Co., Ltd.
    Inventors: Osamu Yoshinari, Makoto Sugiyama, Hideki Nakai
  • Patent number: 4522801
    Abstract: High-performance carbon fiber or graphite fiber can be produced by treating the preoxidized fiber or carbon fiber strand with an aqueous solution containing at least one member of polyethylene oxide having a molecular weight greater than 100,000, methyl cellulose, ethyl cellulose, and hydroxyethyl cellulose, and drying the treated fiber strand at a temperature lower than 250.degree. C. prior to carbonization or graphitization.
    Type: Grant
    Filed: October 11, 1983
    Date of Patent: June 11, 1985
    Assignee: Toho Beslon Co., Ltd.
    Inventors: Osamu Yoshinari, Yoshifumi Kawakatsu, Hideaki Fukuizumi
  • Patent number: 4520623
    Abstract: An activated carbon fiber spun yarn having excellent workability and adsorptive property is disclosed. The activated carbon fiber spun yarn comprising activated carbon fibers having a specific surface area of 500 to 1,500 m.sup.2 /g, a ductility of at least 0.5%, and a tensile strength of at least 10 kg/mm.sup.2 and derived from acrylonitrile-based fibers. The spun yarn has a twist coefficient of 30 to 60.
    Type: Grant
    Filed: July 18, 1983
    Date of Patent: June 4, 1985
    Assignee: Toho Beslon Co., Ltd.
    Inventors: Hiroyasu Ogawa, Kazuo Izumi, Kenji Shimazaki
  • Patent number: 4508851
    Abstract: Fibrous activated carbon having a pH not more than 5 which is suitable for recovering halogenated hydrocarbon solvents is disclosed. The fibrous activated carbon is obtained by acid treating raw fibrous activated carbon.
    Type: Grant
    Filed: June 21, 1983
    Date of Patent: April 2, 1985
    Assignee: Toho Beslon Co., Ltd.
    Inventors: Kazuo Izumi, Kenji Shimazaki, Kenji Seki
  • Patent number: 4482660
    Abstract: A prepreg for making a composite is disclosed. The prepreg comprising reinforcing fibers impregnated with a resin composition comprising (A) an epoxy resin, (B) a reaction product of an epoxy resin and a butadiene-acrylonitrile copolymer having carboxyl groups on at least both terminals of the molecular chain of the copolymer, and (C) 4,4'-diaminodiphenylsulfone as a curing agent. A composite produced by curing this prepreg is high in both tensile elongation and heat resistance and is used with advantage as primary and secondary structural materials in aircraft.
    Type: Grant
    Filed: January 14, 1983
    Date of Patent: November 13, 1984
    Assignee: Toho Beslon Co., Ltd.
    Inventors: Tsuyoshi Minamisawa, Masato Andoh
  • Patent number: 4474906
    Abstract: A carbon fiber coated with 0.3 to 10 wt. % of a polyurethane resin is disclosed. Also disclosed is a carbon fiber reinforced thermoplastic resin composition consisting preferably of 3 to 60 wt. % of such carbon fiber and 97 to 40 wt. % of a thermoplastic matrix resin. Said carbon fiber has increased gathering properties and adhesion strength to facilitate the mixing with the thermoplastic matrix resin and provides a resin molding having improved mechanical properties, especially increased impact strength.
    Type: Grant
    Filed: January 20, 1983
    Date of Patent: October 2, 1984
    Assignees: Toho Beslon Co., Ltd., Teijin Chemicals Ltd.
    Inventors: Katsumi Nakama, Hiroaki Yamashita, Hirotsugu Kuroda, Mikio Kashimoto
  • Patent number: 4460650
    Abstract: Acrylonitrile fibers suitable for production of preoxidized fibers, fibrous active carbon and carbon fibers, which have thereon a water-soluble basic aluminum salt of the formula:Al.sub.2 (OH).sub.l (A).sub.m (B).sub.n (C).sub.p (Cl).sub.q (I)where(1) A, B and C stand for mutually different acid residues;(2) l and q are both an integer or decimal fraction larger than 0;(3) m, n and p are 0 or an integer or decimal fraction and make a total which is not zero;(4) l+mEm+nEn+pEp+q=6 (Em, En and Ep are the valence numbers of A, B and C, respectively); ##EQU1## in an amount of 0.005 to 5.0% by weight of aluminum element based on the fiber having the salt.
    Type: Grant
    Filed: December 23, 1982
    Date of Patent: July 17, 1984
    Assignee: Toho Beslon Co., Ltd.
    Inventors: Hiroyasu Ogawa, Kazuo Izumi, Kenzi Shimazaki
  • Patent number: 4443507
    Abstract: A heat-moldable laminate comprising at least one thermoplastic resin layer, at least one fiber reinforced cured thermosetting resin layer, and at least one slippage layer interposed therebetween and bonding the resin layers, said slippage layer comprising a thermoplastic resin and said slippage layer being capable of being molten at lower temperatures than the moldable temperature of the thermoplastic resin layer, and a process for molding the heat-moldable laminate to produce a molded article having excellent strength and rigidity is disclosed.
    Type: Grant
    Filed: August 30, 1982
    Date of Patent: April 17, 1984
    Assignee: Toho Beslon Co., Ltd.
    Inventors: Kozo Yamada, Takayuki Tanaka
  • Patent number: 4443726
    Abstract: A brush, for use for example as an electrical pick-up, includes a brush portion composed of a bundle of metal coated carbon fibers arranged substantially in parallel. A base portion includes a region where the metal coated fibers have been bonded by diffusion via a hot pressing method, and at least one metallic piece bonded to the fiber bundle by diffusion by the same process. The brush of the invention has excellent durability and a conductivity.
    Type: Grant
    Filed: May 10, 1982
    Date of Patent: April 17, 1984
    Assignees: Toho Beslon Co., Ltd., Japan Marine Machinery Development Assoc., Sumitomo Heavy Industries, Ltd.
    Inventors: Shigeru Ikegami, Takashi Ohsaki
  • Patent number: 4438738
    Abstract: A rocker arm made from a carbon-fiber reinforced resin is disclosed wherein various axes are defined with particularity such as the central axis of the hole through which the rocker shaft is inserted (Z-axis), a line parallel to the edge of the valve side (Y-axis) and the line that is parallel to the cam side (Y'axis). The bisect of the angle at which the Y-axis crosses the Y'axis is the X-axis. Further, cos.sup.2 .beta. of the carbon fibers present in the Y- or Y'axis side with respect to the X-Z axis is defined in detail where .beta. is a defined angle of orientation as is cos.sup.2 .alpha. which is defined in the specification.The rocker arm is produced by filling a rocker arm mold with a carbon fiber-containing synthetic resin such that cos.sup.2 .beta. of the carbon fibers meets a defined value to such an extent that the cos.sup.2 .alpha. meets a defind value. The rocker arm is lighter and stronger than conventional rocker arms.
    Type: Grant
    Filed: November 26, 1982
    Date of Patent: March 27, 1984
    Assignees: Toho Beslon Co., Ltd., Toyota Jidosha Kabushiki Kaisha
    Inventors: Hiroyuki Kosuda, Yasuo Kogo, Yasuhiro Mishima, Masahiro Nakagawa
  • Patent number: 4366085
    Abstract: A fibrous activated carbon with a metal chelate compound supported thereon which is suitable for removal of toxic substances in gas. This activated carbon is obtained by attaching a solution or dispersion of the metal chelate compound onto the fibrous activated carbon followed by drying. Contacting the activated carbon with a toxic substance-containing gas provides very efficient removal of the toxic substance from the gas.
    Type: Grant
    Filed: November 14, 1980
    Date of Patent: December 28, 1982
    Assignee: Toho Beslon Co., Ltd.
    Inventors: Shigeru Ikegami, Yoshihumi Kawakatsu, Minoru Hirai, Kazuo Izumi
  • Patent number: 4362646
    Abstract: A fibrous activated carbon having high adsorptivity and excellent mechanical properties is produced by preoxidizing an acrylonitrile-based fiber containing a specific amount of an iron compound at a specific initial heat-treatment temperature and then activating.
    Type: Grant
    Filed: September 29, 1980
    Date of Patent: December 7, 1982
    Assignee: Toho Beslon Co., Ltd.
    Inventors: Shigeru Ikegami, Minoru Hirai, Kazuo Izumi
  • Patent number: 4347279
    Abstract: A carbon fiber, a process for production thereof, and composite materials prepared therewith are described, wherein the carbon fiber has a single yarn diameter of from 2 to 6 microns and showing a strand knot strength of 7 kilograms or more when formed into a strand of 0.4.+-.0.01 gram per meter, which comprises subjecting a 0.1 to 0.6 denier acrylonitrile-based fiber having a strength of 6 grams per denier or more to a preoxidation treatment wherein the acrylonitrile-based fiber is treated under such tension as to provide a shrinkage of at least 3% until the equilibrium water content reaches 5%, and (b) a second preoxidation treatment wherein the acrylonitrile-based fiber is treated under such tension as to provide a shrinkage of at least 1%, said preoxidation treatment is conducted in an oxidizing atmosphere having a temperature of from 240.degree. C. to 300.degree. C. while maintaining the relation between the preoxidation treatment time (t) (minutes) and average preoxidation treatment temperature (T) (.
    Type: Grant
    Filed: August 21, 1981
    Date of Patent: August 31, 1982
    Assignee: Toho Beslon Co., Ltd.
    Inventors: Yasuo Saji, Kozo Tanaka, Takashi Yamauchi
  • Patent number: 4339021
    Abstract: A friction material comprising a carbon fiber reinforced carbon with an oxidation temperature of at least 800.degree. C. and a crystallinity index of matrix carbon of from 2.3 to 5.0, a process for the production of the same, and a friction element comprising the same.
    Type: Grant
    Filed: July 18, 1980
    Date of Patent: July 13, 1982
    Assignee: Toho Beslon Co., Ltd.
    Inventors: Hiroyuki Kosuda, Kenji Niijima