Abstract: A novel thermosetting resin composition comprising at least one [(2,3-epoxypropoxy)alkyl]trialkoxysilane and at least one selected from polymers, prepolymers, copolymers and coprepolymers of epoxy-group-containing vinyl monomers, which may further contain at least one selected from polymers, prepolymers, copolymers and coprepolymers of vinyl monomers containing no epoxy group, is disclosed. This composition is cured by heating with addition of a ring-opening polymerization catalyst and remarkably improves surface hardness, abrasion resistance, weathering resistance, chemical resistances, heat resistances, etc. of acrylic resins and many other plastic materials without imparing the inherent transparency and other optical properties of these materials when it is applied on the surface of them and cured.
Type:
Grant
Filed:
December 23, 1975
Date of Patent:
September 20, 1977
Assignees:
Japan Atomic Energy Research Institute, Tokyo Optical Company, Ltd.
Abstract: Soft contact lenses comprising a copolymer comprising at least one monomer of the general formula, ##EQU1## wherein X is H or CH.sub.3 and n is 2 or 3, at least one monomer of the general formula, ##EQU2## wherein X is H or CH.sub.3 and m is an integer of 4 to 13, and optionally at least one polymerizable monomer other than the monomers of the above-mentioned two groups are disclosed. These contact lenses are soft and flexible in the non-swollen state and are tougher and less susceptible to microbiological contamination than the hitherto known soft contact lenses. Also a novel process for preparation of these soft contact lenses is disclosed, which comprises cast-polymerizing a mixture of the above-mentioned monomers, cooling the resulting copolymer to a low temperature at which it stands rigid, and shaping the copolymer body into the lens form in the cooled rigid state.
Type:
Grant
Filed:
December 6, 1974
Date of Patent:
September 28, 1976
Assignees:
Japan Atomic Energy Research Institute, Tokyo Optical Company Ltd. (Kabushiki Kaisha Tokyo Megane)
Abstract: Transparent resin composites comprising a substrate of a transparent plastic material coated with a cured film of at least one [(2,3-epoxypropoxy)alkyl]trialkoxysilane or of at least one [(2,3-epoxypropoxy)alkyl]trialkoxysilane and at least one transparent polymer compatible with said silane are provided. The resin composites have excellent abrasion resistance, surface hardness, heat resistance, chemical resistance, weathering resistance, etc. well retaining the transparency and other optical characteristics of the substrate resin. These resin composites can be used as transparent plastic panels, lenses, etc.
Type:
Grant
Filed:
August 6, 1974
Date of Patent:
May 4, 1976
Assignees:
Japan Atomic Energy Research Institute, Tokyo Optical Company, Ltd.