Patents Assigned to Tonen Sekiyukagaku
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Patent number: 5252385Abstract: An elastomer film of a thermoplastic elastomer composition comprising 30-70 weight % of an ethylene-propylene-diene copolymer and 70-30 weight % of an ethylene-vinyl acetate copolymer having a vinyl acetate content of 5-30 weight % and a melt index of 0.2-25 g/10 minutes, the elastomer film having a thickness of 10-60 .mu.m, and a draw ratio expressed by a heat shrinkage ratio at 50.degree. C. which is 5-35% in an MD direction and 5-25% in a TD direction, the ratio of the draw ratio in an MD direction to the draw ratio in a TD direction being 3 or less, is produced by an air-cooled inflation method.Type: GrantFiled: November 30, 1992Date of Patent: October 12, 1993Assignee: Tonen Sekiyukagaku Kabushiki KaishaInventors: Seiji Kagawa, Hideaki Toda, Yoshihiro Uotome
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Patent number: 5218036Abstract: Shrinkable film and articles prepared therefrom which shrink more than 5% when heated to a temperature of 50.degree. C. are disclosed. The shrinkable film is prepared by stretching a polymer film of EPDM or EPM and EVA and talc more than 1.5 times in at least one direction at specified temperatures.Type: GrantFiled: December 24, 1990Date of Patent: June 8, 1993Assignee: Tonen Sekiyukagaku K.K.Inventors: Seiji Kagawa, Hideaki Toda, Yoshinaga Murakami
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Patent number: 5216054Abstract: A polymer composition comprising resin components comprising (a) 5-95 weight % of a polyamide resin, and (b) 5-95 weight % of polyolefin + unsaturated carboxylic acid-modified polyolefin, and (c) additives comprising the following compounds in amounts per 100 parts by weight of the total composition: (1) 0.1-2 parts by weight of a substituted hydrazine: (2) 0.05-2 parts by weight of a hindered phenol compound; (3) 0.05-0.5 parts by weight of a phosphite or phosphonite; and (4) 0.15-1 parts by weight of a thiodipropionate.Type: GrantFiled: February 27, 1992Date of Patent: June 1, 1993Assignee: Tonen Sekiyukagaku Kabushiki KaishaInventors: Kunio Iwanami, Kissho Kitano, Yukihiko Yagi, Takashi Mikami
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Patent number: 5185203Abstract: Disclosed are a heat-sealable crosslinked oriented polyethylene film having low-temperature heat sealabilitiy which enables high-speed bag making, improved in antiblocking property and excellent in clarity and moistureproofness, comprising a crosslinked, biaxially oriented high density polyethylene film in which the degree of crosslinking inwardly decreases across the thickness of the film, and a heat sealing layer placed thereon, the heat sealing layer being composed of a tackifier and an ethylene-vinyl acetate copolymer containing an antiblocking agent or composed of 1,2-polybutadiene containing an antiblocking agent, preferably further comprising a heat sealing layer free from an antiblocking agent placed between the biaxially oriented film and the heat sealing layer containing the antiblocking agent, and a process for the production of the same.Type: GrantFiled: November 14, 1989Date of Patent: February 9, 1993Assignee: Tonen Sekiyukagaku K.K.Inventors: Yasushi Itaba, Minoru Izawa, Keichiro Saito, Takayoshi Kondo
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Patent number: 5153060Abstract: A resin composition comprising polyarylene sulfide, polyvinylidene fluoride and optionally ultrafine particles and a method of adhering a polyarylene sulfide article and a polyvinylidene fluoride article by using a resin composition comprising polyarylene sulfide, polyvinylidene fluoride and optionally ultrafine particles as an adhesive comprises the steps of melting portions of the polyarylene sulfide article and the polyvinylidene fluoride article to be adhered and the adhesive at a temperature between a melting point of the polyarylene sulfide and 400.degree. C.; bringing the portions to be adhered into contact with each other via the adhesive in a molten state; and cooling the adhered portions in a contact state.Type: GrantFiled: April 11, 1991Date of Patent: October 6, 1992Assignee: Tonen Sekiyukagaku Kabushiki KaishaInventors: Shunji Onishi, Yoshinori Ichikawa, Junji Takeuchi
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Patent number: 5123688Abstract: A high shock-absorbing automobile bumper with a smooth outer surface which may be manufactured by loading a preformed surface skin member into a blow mold, and then blowing a parison in the mold so that the blow parison is bonded to the surface skin member. The result is a hollow cushioning body firmly bonded to the surface skin member.Type: GrantFiled: April 23, 1991Date of Patent: June 23, 1992Assignee: Tonen Sekiyukagaku K.K.Inventors: Yutaka Takado, Masayuki Yamazaki, Takashi Mikami, Tetsuo Tomiyama
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Patent number: 5106909Abstract: A modified polyolefin-polyester graft copolymer includes (a) 10-90 parts by weight of a polyester having an intrinsic viscosity [.eta.] of 0.30-1.20 and an end carboxyl group content of 15-200 milliequivalent/kg, and (b) 90-10 parts by weight of a modified polyolefin having 0.2-5 mol % of an epoxy group or carboxyl group content and a weight-average molecular weight of 8,000-140,000.A thermoplastic resin composition includes (a) 5-95 weight % of an aromatic polycarbonate, (b) 95-5 weight % of a polyolefin, and (c) 1-30 parts by weight, per 100 parts by weight of (a)+(b), of the graft copolymer.Type: GrantFiled: October 13, 1989Date of Patent: April 21, 1992Assignee: Tonen Sekiyukagaku Kabushiki KaishaInventors: Tadahi Sezume, Shigeru Sato, Masahiro Oosawa, Yasuhiko Haraguchi, Takashi Mikami, Takeyoshi Nishio, Toshio Yokoi, Takao Nomura, Nobuya Kawamura
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Patent number: 5106893Abstract: A fiber-reinforced polymer composition containing resin components including (a) 30-90 weight % of a polyamide resin, and (b) 10-70 weight % of polyolefin+unsaturated carboxylic acid-modified polyolefin, based on the resin components; and, per 100 parts by weight of the total components, (c) 5-50 parts by weight of glass fibers, and (d) additives including the following set of additives: 0.1-1 parts by weight of N,N'-hexamethylene-bis (3,5-di-tert-butyl-4-hydroxy-hydrocinnamide); 0.1-1 parts by weight of triethylene glycol-bis [3-(3-tert-butyl-5-methyl-4-hydroxyphenyl) propionate]; and 0.1-1 parts by weight of pentaerythrityl-tetrakis [3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate]. An alternative set of additives are 0.1-2 parts by weight of N,N'-bis [3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionyl] hydrazine; 0.05-0.5 parts by weight of pentaerythrityl-tetrakis [3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate]; 0.05-0.5 parts by weight of distearyl-pentaerythritol diphosphite; and 0.Type: GrantFiled: February 7, 1991Date of Patent: April 21, 1992Assignees: Tonen Sekiyukagaku Kabushiki Kaisha, Nippondenso Co., Ltd.Inventors: Kunio Iwanami, Kissho Kitano, Kiyotada Narukawa, Masato Sakuma, Takashi Mikami, Masami Esaki, Koji Egashira, Hiroyuki Wakabayashi, Fumio Kato
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Patent number: 5106564Abstract: Fiber-reinforced polymer compositions containing resin components including (a) 30-90 weight % of polyamide resins, and (b) 10-70 weight % of polyolefins+unsaturated carboxylic acid-modified polyolefins, based on the resin components; and (c) 5-50 parts by weight of glass fibers per 100 parts by weight of the total compositions, a molar ratio of end amino groups in the polyamide resins to carboxyl groups in the modified polyolefins being 10-1000. The compositions have a morphology in which polyolefin domains having an average size of 0.5-5 .mu.m are uniformly dispersed in polyamide matrix phases.Type: GrantFiled: January 4, 1991Date of Patent: April 21, 1992Assignees: Tonen Sekiyukagaku Kabushiki Kaisha, Nippondenso Co., Ltd.Inventors: Kunio Iwanami, Kissho Kitano, Kiyotada Narukawa, Kenichi Aoki, Yukihiko Yagi, Masato Sakuma, Takashi Mikami, Masami Esaki, Fumio Kato, Koji Egashira, Hiroyuki Wakabayashi
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Patent number: 5091463Abstract: A resin composition comprising polyarylene sulfide, polyvinylidene fluoride and optionally ultrafine particles. A method of adhering a polyarylene sulfide article and a polyvinylidene fluoride article by using a resin composition comprising polyarylene sulfide, polyvinylidene fluoride and optionally ultrafine particles as an adhesive comprises the steps of melting portions of the polyarylene sulfide article and the polyvinylidene fluoride article to be adhered and the adhesive at a temperature between a melting point of the polyarylene sulfide and 400.degree. C.; bringing the portions to be adhered into contact with each other via the adhesive in a molten state; and cooling the adhered portions in a contact state.Type: GrantFiled: October 23, 1989Date of Patent: February 25, 1992Assignee: Tonen Sekiyukagaku Kabushhiki KaishaInventors: Shunji Onishi, Yoshinori Ichikawa, Junji Takeuchi
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Patent number: 5075152Abstract: Disclosed are a polyethylene composite film used for displaying materials, balloons and various packaging materials, which is excellent in moistureproofness, clarity, bending properties and pinhole resistance, comprising an oriented polyethylene film in which the degree of crosslinking inwardly decreases across the thickness of the oriented polyethylene film on which printing is performed and a film laminated on the printed surface; and a label suitably used for a polyethylene bottle comprising the above oriented polyethylene film on which printing is performed and an adhesive layer formed on the printed surface.Type: GrantFiled: May 2, 1991Date of Patent: December 24, 1991Assignee: Tonen Sekiyukagaku K.K.Inventors: Haruo Tsukuda, Joichi Tabuchi
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Patent number: 5057252Abstract: A method of forming a heat-resistant product, produced from a polymer composition comprising 40-70 weight % of a thermoplastic elastomer containing a repeating unit derived from ethylene and a repeating unit derived from propylene and 60-30 weight % of an ethylene-vinyl acetate copolymer containing 7.5 weight % or more of a vinyl acetate repeating unit, which comprises blending the polymer composition at a temperature of 160.degree. C. or less, molding it at a temperature of 180.degree. C. or less, and then cross-linking the resulting molded product by irradiating it with an electron beam or by heating to produce a foamed product which has good shape memory characteristics.Type: GrantFiled: July 2, 1990Date of Patent: October 15, 1991Assignee: Tonen Sekiyukagaku Kabushiki KaishaInventors: Seiji Kagawa, Hideaki Toda, Shinichiro Nomura
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Patent number: 5045620Abstract: Disclosed are oriented polyethylene films having specific elongation and strength, which are excellent in linear tearability and clear tearability, suitably used for packaging and produced by longitudinally stretching a polyethylene resin sheet in which the degree of crosslinking inwardly decreases across the thickness thereof at a draw ratio of at least 5 times at a temperature of not higher than the melting point of a polyethylene resin forming the polyethylene resin sheet, and laterally stretching said sheet 4 to 8 times at a temperature ranging from above the melting point of the polyethylene resin up to 10.degree. C. higher than the melting point thereof.Type: GrantFiled: September 7, 1989Date of Patent: September 3, 1991Assignee: Tonen Sekiyukagaku K.K.Inventors: Yasushi Itaba, Yutaka Yoshifuji, Takayoshi Kondo, Ichiro Sakamoto
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Patent number: 5021504Abstract: A thermoplastic resin composition having well-balanced properties which comprises 95-5 weight % of polycarbonate, 5-95 weight % of polyolefin and a particular combination of additional components selected from a styrene-ethylene.propylene copolymer, a styrene-ethylene. butyrene-styrene block copolymer, an AES resin, a styrene-olefin block copolymer, an unsaturated carboxylic acid-modified polyolefin, polybutylene terephthalate, a styrene-maleic anhydride copolymer, an oxazoline ring-containing styrene copolymer a saponified olefin-vinyl ester copolymer and an epoxy group-containing styrene copolymer.Type: GrantFiled: September 19, 1988Date of Patent: June 4, 1991Assignees: Tonen Sekiyukagaku Kabushiki Kaisha, Toyota Jidosha Kabushiki KaishaInventors: Yuuji Fujita, Tadashi Sezume, Kitsusho Kitano, Kiyotada Narukawa, Takashi Mikami, Tetsuya Kawamura, Shigeru Sato, Takeyoshi Nishio, Toshio Yokoi, Takao Nomura
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Patent number: 5013789Abstract: A process for producing a thermoplastic resin composition which comprises preparing a component composed of 1 to 49 parts by weight of modified polyolefin (A) obtained by adding an unsaturated carboxylic acid or a derivative thereof to a polyolefin, 1 to 98 parts by weight of polyolefin (B), and 1 to 98 parts by weight of polyamide (C) [provided that (A)+(B)+(C)=100 parts by weight], mixing the component or its molten component with a metal compound (D) in an amount of 0.5 to 5 times the molar quantity of the acid added to the modified polyolefin (A), and subsequently melt-mixing the mixture. The thermoplastic resin composition prepared by this process is preferably used for providing products improved in both surface luster and mechanical strengths.Type: GrantFiled: December 16, 1988Date of Patent: May 7, 1991Assignee: Tonen SekiyukagakuInventors: Masato Sakuma, Yuji Fujita, Kissho Kitano, Yukihiko Yagi, Masao Sakaizawa, Noburo Yamamoto
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Patent number: 4990550Abstract: Fiber-reinforced polymer compositions containing resin components including (a) 30-90 weight % of polyamide resins, and (b) 10-70 weight % of polyolefins+unsaturated carboxylic acid-modified polyolefins, based on the resin components; and (c) 5-50 parts by weight of glass fibers per 100 parts by weight of the total compositions, a molar ratio of end amino groups in the polyamide resins to carboxyl groups in the modified polyolefins being 10-1000. The compositions have a morphology in which polyolefin domains having an average size of 0.5-5 .mu.m are uniformly dispersed in polyamide matrix phases.Type: GrantFiled: March 20, 1989Date of Patent: February 5, 1991Assignees: Tonen Sekiyukagaku Kabushiki Kaisha, Nippondenso Co., Ltd.Inventors: Kunio Iwanami, Kissho Kitano, Kiyotada Narukawa, Kenichi Aoki, Yukihiko Yagi, Masato Sakuma, Takashi Mikami, Masami Esaki, Fumio Kato, Koji Egashira, Hiroyuki Wakabayashi
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Patent number: 4960823Abstract: A resin composition for bumpers including:(a) 50-65 parts by weight of a propylene-ethylene block copolymer including:(i) 60-75 weight % of a propylene-ethylene block copolymer having an ethylene content of 4-20 weight % and a melt flow rate of 9-30 g/10 min (230.degree. C., 2.16 kg load), and(ii) 40-25 weight % of a propylene-ethylene block copolymer having an ethylene content of 4-20 weight % and a melt flow rate of 40-80 g/10 min (230.degree. C., 2.16 kg load);(b) 40-25 parts by weight of an ethylene-propylene copolymer rubber and/or an ethylene-propylene-diene terpolymer rubber each having an ethylene content of 50-80 weight % and a Mooney viscosity ML.sub.1+4 (100.degree. C.) of 80 or less; and(c) 10-15 parts by weight of high-density polyethylene having a melt index of 1-20 g/10 min (190.degree. C., 2.16 kg load),(a)+(b)+(c) being 100 parts by weight.Type: GrantFiled: February 12, 1990Date of Patent: October 2, 1990Assignee: Tonen Sekiyukagaku Kabushiki KaishaInventors: Masato Komatsu, Masaaki Isoi, Isao Baba, Takashi Mikami
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Patent number: 4945127Abstract: A heat-resistant formed product produced from a polymer composition comprising 40-70 weight % of a thermoplastic elastomer containing a repeating unit derived from ethylene and a repeating unit derived from propylene and 60-30 weight % of an ethylene-vinyl acetate copolymer containing 7.5 weight % or more of a vinyl acetate repeating unit, by blending the polymer composition at a temperature of 160.degree. C. or less, molding it at a temperature of 180.degree. C. or less, and then cross-linking the resulting molded product by irradiating electron beam or heating. The formed product also has good shape memory characteristics.Type: GrantFiled: December 23, 1988Date of Patent: July 31, 1990Assignee: Tonen Sekiyukagaku Kabushiki KaishaInventors: Seiji Kagawa, Hideaki Toda, Shinichiro Nomura
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Patent number: 4940270Abstract: An automoblile bumper comprising a blow-molded hollow body (5) of synthetic resin located between a surface skin (1) and a reinforcement (2), the hollow body (5) having recesses (7) formed by longitudinally extending ribs (6a) and (6a) on either the front or rear side, or on both sides, whereby the bumper uniformly absorbs impact energy when it is hit and thus reduces shocks transmitted to a car body.Type: GrantFiled: February 27, 1989Date of Patent: July 10, 1990Assignee: Tonen Sekiyukagaku K.K.Inventors: Masayuki Yamazaki, Yutaka Takado, Takashi Mikami
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Patent number: 4906683Abstract: Partially crosslinked thermoplastic elastomer which is produced as follows:(A) propylene (10-90 weight part), (B) halogenated butyl rubber (90-10 weight part, (A)+(B)=100 weight part), (C) olefinic rubber (10-120 weight part) and (D) mineral oil softening agent (5-120 weight part) are heated in the presence of (E) metal oxide and/or metal chloride. To the composition based on (A)-(E) (100 weight part), (F) polyolefin (300-1900 weight part) and (G) styrenic rubber (50-1100 weight part) are blended. The composition has particularly good moldability, compatibility, low temperature impact strength, and gloss, and can be used for large scale molding.Type: GrantFiled: November 2, 1987Date of Patent: March 6, 1990Assignee: Tonen Sekiyukagaku K.K.Inventors: Masato Komatsu, Isao Baba, Noboru Yamamoto