Patents Assigned to Toray Silicone Co., Ltd.
  • Patent number: 7030259
    Abstract: A process for preparing a silicone compound, the process comprising reacting (A) a silicon compound having silicon-bonded alkoxy groups or silicon-bonded aryloxy groups and (B) a disiloxane in the presence of (C) a carboxylic acid, (D) an acid catalyst, and (E) a carboxylic anhydride, and a process for preparing a silicone compound, the process comprising reacting (F) a silicon compound having silicon-bonded acyloxy groups and (B) a disiloxane compound in the presence of (D) an acid catalyst, (E) a carboxylic anhydride, and (G) an alcohol.
    Type: Grant
    Filed: January 27, 2003
    Date of Patent: April 18, 2006
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Tadashi Okawa, Makoto Yoshitake, Tomohiro Iimura, Satoshi Onodera
  • Patent number: 7019069
    Abstract: Resinous composition comprising: (A) 100 weight parts of (R2SiO2/2)w(RSiO3/2)x(SiO4/2)y(O1/2R1)z wherein R is selected from the group consisting of monovalent hydrocarbon groups having 1 to 10 carbon atoms, R1 is selected from the group consisting of the hydrogen atom and saturated hydrocarbon groups having from 1 to 6 carbon atoms, w is a number from 0 to 0.2, x is a number from 0.4 to 0.9, y is a number from 0.1 to 0.6, z is a number from 0.1 to 0.5, and (w+x+y)=1; (B) 20 to 150 weight parts of an alcohol-based solvent; (C) 100 to 1000 weight parts of a solvent selected from the group consisting of hydrocarbon-based solvents and polydimethylsiloxanes described by the formula Me3SiO(Me2SiO)nSiMe3, wherein Me is the methyl group and n has a value of 0 or 1; (D) 1 to 100 weight parts of a coupling agent selected from the group consisting of alkoxysilanes and silane coupling agents; (E) 0.1 to 20 weight parts of a condensation catalyst, and (F) 0.
    Type: Grant
    Filed: February 12, 2001
    Date of Patent: March 28, 2006
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Hideki Kobayashi, Mari Tateishi, Toru Masatomi
  • Patent number: 6881807
    Abstract: A silicone gel composition is characterized by excellent storage stability in a non-cured state and by high adhesion to a substrate and long-term stability of consistency at elevated temperatures after curing. The silicone gel composition comprises: a polyorganosiloxane (A), which consists of polyorganosiloxane (A-1) that contains R(CH3)2SiO2/2 units, RsiO3/2 units R(CH3)2SiO1/2 units, and polydiorganosiloxane (A-2) that contains R(CH3)2SiO2/2 units and R(CH3)2SiO1/2 units, and R(CH3) which contains in one molecule two silicon-bonded hydrogen atoms; an addition-reaction platinum catalyst (C); an organosilicon compound (D) selected from silane of the general formula (R1O)nSiR24-n or a partially hydrolyzed condensate thereof; and an organic titanium compound (E).
    Type: Grant
    Filed: April 15, 2002
    Date of Patent: April 19, 2005
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Masayoshi Terada, Hiroji Enami
  • Patent number: 6797772
    Abstract: A composition comprises the product obtained by homogeneously blending: (A) 100 parts by weight of a polyorganosiloxane containing at least two alkenyl radicals per molecule, (B) an organohydrogensiloxane containing at least two silicon-bonded hydrogen atoms per molecule in a quantity sufficient to provide from 0.5 to 3 silicon-bonded hydrogen atoms per alkenyl radical of (A), (C) from 50-2000 parts by weight of silver particles pre-treated with an organosilicon compound selected from the group consisting of (i) alkoxy group(s)-containing silanes and (ii) organosiloxanes, (D) a platinum catalyst, (E) up to 20 weight percent based on the weight of (A) of an organosilicon compound containing at least one silicon-bonded alkoxy group per molecule, and (F) from 0.001 to 5 parts by weight per 100 parts by weight of (A) of a cure inhibitor.
    Type: Grant
    Filed: January 18, 2002
    Date of Patent: September 28, 2004
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Kazumi Nakayoshi, Katsutoshi Mine, Rikako Tazawa
  • Patent number: 6787057
    Abstract: A viscous liquid vibration damping composition containing (A) 30-95 weight percent of a viscous liquid, and (B) 5-70 weight percent of at least two solid powders having different average particle diameters, where the difference between the respective average particle diameters of the two solid powders is at least 10 &mgr;m. These viscous liquid vibration damping compositions are superior in vibration damping properties, and possess a stable vibration damping characteristic that is not significantly affected by temperature changes.
    Type: Grant
    Filed: May 1, 2001
    Date of Patent: September 7, 2004
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Mari Tateishi, Shoji Akamatsu
  • Patent number: 6777486
    Abstract: A vibration damping silicone composition with excellent long term storage stability and vibration damping ability contains as components (A) a silicone oil, (B) hollow particles of an organic resin having an inorganic material powder supported on its surfaces, and (C) a solid inorganic material powder.
    Type: Grant
    Filed: June 26, 2001
    Date of Patent: August 17, 2004
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Hideki Kobayashi, Masayuki Hayashi
  • Patent number: 6764718
    Abstract: A method for forming an electrically insulating thin film coating the surface of an electronic device with an electrically insulating thin-film-forming resin composition and crosslinking the composition by a method selected from the group consisting of heating and irradiation with high-energy rays.
    Type: Grant
    Filed: December 9, 2002
    Date of Patent: July 20, 2004
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Takashi Nakamura, Kiyotaka Sawa, Akihiko Kobayashi, Katsutoshi Mine
  • Patent number: 6761947
    Abstract: A silicone-based adhesive sheet prepared by a process comprising (i) curing a silicone composition to form a substantially cured product while the composition lies between backing materials, wherein at least one of the backing materials has a surface comprising oxygen atoms and/or sulfur atoms in contact with the silicone composition and the backing materials are releasable from the cured product, and (ii) separating the cured product from the backing materials. A method of manufacturing a silicone-based adhesive sheet comprising (i) curing a silicone composition to form a cured product while the composition lies between backing materials, wherein at least one of the backing materials has a surface comprising oxygen atoms and/or sulfur atoms in contact with the silicone composition and the backing materials are releasable from the cured product, and (ii) separating the cured product from the backing materials.
    Type: Grant
    Filed: January 17, 2003
    Date of Patent: July 13, 2004
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Kimio Yamakawa, Minoru Isshiki, Yoshiko Otani, Katsutoshi Mine
  • Patent number: 6750550
    Abstract: An adhesive composition for bonding semiconductor chips to their chip mounting components comprising a curable polymer composition comprising from 1 to 900 weight-ppm spherical filler having an average particle size of from 10 to 100 &mgr;m and a major axis-to-minor axis ratio of from 1 to 1.5. Also, semiconductor devices in which a semiconductor chip therein is bonded to its chip mounting component by the aforesaid adhesive composition.
    Type: Grant
    Filed: June 20, 2000
    Date of Patent: June 15, 2004
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Kimio Yamakawa, Minoru Isshiki, Katsutoshi Mine
  • Patent number: 6720083
    Abstract: An adhesive composition for bonding of semiconductor chips to their chip mounting components comprising a curable polymer composition that comprises a spherical filler having an average particle size from greater than 100 to 1,000 &mgr;m and an aspect ratio of 1 to 1.5. Semiconductor devices according to this invention are characterized in that a semiconductor chip therein is bonded to the mounting component for said chip by the aforementioned adhesive.
    Type: Grant
    Filed: March 20, 2002
    Date of Patent: April 13, 2004
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Kimio Yamakawa, Minoru Isshiki, Katsutoshi Mine
  • Patent number: 6710124
    Abstract: Water base coating material compositions form coating films of superior flat finish properties. They contain silicone particles with at least two kinds of different average particle size. According to the method of making the composition, a water base coating material composition can be formed by adding an aqueous suspension of silicone particles to a water base coating material composition where the aqueous suspension contains at least two kinds of silicone particles with different average particle size.
    Type: Grant
    Filed: August 27, 2001
    Date of Patent: March 23, 2004
    Assignee: Dow Corning Toray Silicone, Co. Ltd.
    Inventors: Yoshitsugu Morita, Kazuo Kobayashi, Ken Tanaka
  • Patent number: 6706798
    Abstract: A water repellent silicone coating agent composition comprising (A) a diorganopolysiloxane having a viscosity of 20 to 20,000 mPa·s at 25° C. in which the terminal ends of the molecular chain are blocked by silanol groups or silicon-bonded hydrolyzable groups, (B) a cross-linking agent represented by general formula RaSiX4-a, in which R is a monovalent hydrocarbon group comprising 1 to 10 carbon atoms, X is a hydrolyzable group, and subscript a is an integer of 0 to 2, (C) a condensation reaction catalyst, (D) a hydrophobic surface treated dry process silica having a carbon content of 3.7 to 5% by weight and a bulk density of 40 to 99 g/L, or a hydrophobic surface treated dry process silica having a carbon content of 2.7 to 5% by weight and a bulk density of 100 to 300 g/L, (E) an organic functional silane coupling agent-based adhesion-imparting agent, (F) an organic solvent, and optionally (G) a non-reactive silicone fluid.
    Type: Grant
    Filed: November 29, 2001
    Date of Patent: March 16, 2004
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Hideki Kobayashi, Motoshi Sasaki
  • Patent number: 6699925
    Abstract: A flame-retardant thermoplastic resin composition comprising (A) 100 weight parts of a thermoplastic resin, (B) 10 to 300 weight parts of particulate metal hydroxide; (C) 0.01 to 50 weight parts of a branched polyorganosiloxane having alkoxy groups and described by average unit formula R1a(R2O)bSiO(4−a−b)/2, where R1 and R2 are monovalent hydrocarbon groups selected from the group consisting of alkyl, alkenyl, and aryl groups, a is 0 or a positive number; b is a positive number; and a+b is a number from 0.75 to 2.5; (D) 0.01 to 50 weight parts of a branched polyorganosiloxane having silanol groups and described by average unit formula R3a(HO)bSiO(4−a−b)/2, where R3 is a monovalent hydrocarbon group selected from the group consisting of alkyl, alkenyl, and aryl groups, a is 0 or a positive number, b is a positive number, and a+b is a number from 0.75 to 2.5; and (E) 0.01 to 10 weight parts of a condensation reaction promoting catalyst.
    Type: Grant
    Filed: August 23, 2001
    Date of Patent: March 2, 2004
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Hidekatsu Hatanaka, Koji Nakanishi, Haruhiko Furukawa, Koji Shiromoto, Hiroshi Ueki, Yoshitsugu Morita
  • Patent number: 6627705
    Abstract: A vibration damping silicone composition of superior vibration damping properties and superior long-term storage stability contains (A) a silicone oil, and (B) a silicone resin powder. Component (B) is a solid at room temperature, and has a volatile component content of not more than one percent by weight, after being heated for two hours at 200° C.
    Type: Grant
    Filed: July 26, 2001
    Date of Patent: September 30, 2003
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Hideki Kobayashi, Masayuki Hayashi
  • Patent number: 6621173
    Abstract: A semiconductor device having a semiconductor chip; a semiconductor chip attachment element facing the semiconductor chip, at least one interconnect on the surface of the semiconductor chip attachment element; and at least one member consisting of a metal or metal alloy that electrically connects the semiconductor chip with the interconnects; wherein the semiconductor chip is bonded to the semiconductor chip attachment element by an adhesive and at least a portion of at least one member that electrically connects the semiconductor chip with at least one interconnect is sealed or imbedded with a sealant/filling agent, and the complex modulus of at least one of the adhesive and the sealant/filling agent is not greater than 1×108 Pa at −65° C. and a shear frequency of 10 Hz.
    Type: Grant
    Filed: January 14, 2000
    Date of Patent: September 16, 2003
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Kimio Yamakawa, Minoru Isshiki, Yoshiko Otani, Katsutoshi Mine
  • Patent number: 6605231
    Abstract: A vibration damping silicone composition having excellent vibration damping ability and good storage stability contains (A) a silicone oil, (B) calcium carbonate powder, (C) a solid inorganic material powder other than powder (B) having a mean particle size of 20-200 &mgr;m, and (D) a fatty acid or fatty acid derivative.
    Type: Grant
    Filed: June 26, 2001
    Date of Patent: August 12, 2003
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Hideki Kobayashi, Masayuki Hayashi
  • Patent number: 6602949
    Abstract: Stable vinyl copolymer emulsions are capable of forming strongly water repellent and highly water resistant films and coatings, and can be used as paint or coating additives. They are highly compatible with paint and coating compositions. The vinyl copolymer emulsions are produced by emulsion polymerizing (A) 50-99.9 weight percent of a vinyl monomer, (B) 0.1-50 weight percent of a branched organosilicon compound bearing a radically polymerizable organic group, where the sum of components (A) and (B) is 100 weight percent, and (C) a radically polymerizable surfactant used at 0.1-20 weight parts per 100 weight parts of the total amount of components (A) and (B).
    Type: Grant
    Filed: December 13, 2001
    Date of Patent: August 5, 2003
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Haruhiko Furukawa, Takayuki Aso, Yoshitsugu Morita
  • Patent number: 6590032
    Abstract: A thermoplastic resin composition comprising (A) 100 weight parts thermoplastic resin, (B) 0.1 to 100 weight parts of a mixture of (b-1) thermoplastic resin and (b-2) polyorganosiloxane that has a viscosity at 25° C. of at least 1,000,000 mPa·s, and (C) 0.1 to 100 weight parts polyorganosiloxane-bonded thermoplastic resin in which (c-1) thermoplastic resin and (c-2) polyorganosiloxane are chemically bonded to each other.
    Type: Grant
    Filed: April 10, 2001
    Date of Patent: July 8, 2003
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Haruhiko Furukawa, Koji Shiromoto, Hiroshi Ueki, Yoshitsugu Morita
  • Patent number: 6569931
    Abstract: A thermoplastic elastomer composition, method of preparation, and article prepared therefrom. The thermoplastic elastomer composition comprising (A) a thermoplastic elastomer, (B) a thermoplastic resin which has Rockwell hardness (R scale) exceeding 80 at 25° C., (C) a polydiorganosiloxane which has a Williams plasticity exceeding 100 at 25° C.; and (D) an inorganic filler.
    Type: Grant
    Filed: May 3, 2001
    Date of Patent: May 27, 2003
    Assignees: Dow Corning Corporation, Dow Corning Toray Silicone Co., Ltd.
    Inventors: Haruhiko Furukawa, Yoshitsugu Morita, Kevin Edward Lupton, David Joseph Romenesko
  • Patent number: 6569536
    Abstract: A thermoconductive liquid silicone rubber composition is provided for fixing rolls. The composition is capable of producing silicone rubber of superior thermal conductivity and small compression set after curing. The thermoconductive liquid silicone rubber composition contains (A) a diorganopolysiloxane with at least two silicon bonded alkenyl groups per molecule, (B) an alumina powder with an average particle size not more than 10 &mgr;m and an ignition loss of not more than 0.15 weight percent, (C) an organohydrogenpolysiloxane having at least two silicon bonded hydrogen atoms per molecule, and (D) a platinum catalyst. Fluororesin coated fixing rolls can be fabricated by providing a fluororesin layer on the peripheral surface of a roll shaft, with the silicone rubber layer interposed between it and the surface.
    Type: Grant
    Filed: July 24, 2001
    Date of Patent: May 27, 2003
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Yuichi Tsuji, Hiroaki Yoshida, Yutaka Oka