Abstract: There is disclosed a compositionally graded sintered alloy which comprises: 1 to 40% by weight of a iron group metal; 0.1 to 10% by weight of at least one type of a specific metal element selected from the group consisting of Cr, Au, Ge, Cu; Sn, Al, Ga, Ag, In, Mn and Pb; a hard phase containing, as a main component, at least one compound selected from the group consisting of a carbide, a nitride and a mutual solid solution of a metal(s) which belongs to Group 4 (Ti, Zr, Hf), 5 (V, Nb, Ta) or 6 (Cr, Mo, W) of the Periodic Table; and inevitable impurities, wherein the content of the specific metal element gradually increases from a surface of the sintered alloy toward an inner portion thereof, and a ratio of the average concentration of the specific metal element in a region which is at least 1 mm inside from the surface of the sintered alloy, to the average concentration of the specific metal element in a region between the surface and the position which is 0.

Abstract: There are disclosed a coated cutting tool which comprises a base material of a hard alloy comprising a hard phase of tungsten carbide and at least one material selected from a carbide, nitride and carbonitride of a metal selected from the Group 4, 5 and 6 of the Periodic Table and a mutual solid solution thereof and a binder phase of at least one element selected from Fe, Ni and Co, and a hard coating film formed on the surface of the base material by a CVD method, wherein the hard coating film has a columnar crystal layer comprising at least one material selected from a carbide, nitride and carbonitride of titanium, the columnar crystal layer contains large-sized particles and small-sized particles, and the ratio of the amounts of the large particles to the small particles is 3 to 50; and a method for producing the same which comprises forming the hard coating film by at least one coating film of a carbide, carbonitride and carbonitroxide of titanium using a hydrocarbon gas containing ethane as a carbon elem

Abstract: There is disclosed a compositionally graded sintered alloy which comprises: 1 to 40% by weight of a iron group metal; 0.1 to 10% by weight of at least one type of a specific metal element selected from the group consisting of Cr, Au, Ge, Cu; Sn, Al, Ga, Ag, In, Mn and Pb; a hard phase containing, as a main component, at least one compound selected from the group consisting of a carbide, a nitride and a mutual solid solution of a metal(s) which belongs to Group 4 (Ti, Zr, Hf), 5 (V, Nb, Ta) or 6 (Cr, Mo, W) of the Periodic Table; and inevitable impurities, wherein the content of the specific metal element gradually increases from a surface of the sintered alloy toward an inner portion thereof, and a ratio of the average concentration of the specific metal element in a region which is at least 1 mm inside from the surface of the sintered alloy, to the average concentration of the specific metal element in a region between the surface and the position which is 0.

Abstract: There is disclosed a hard alloy which comprises 5 to 50% by volume of a metallic binder phase comprising at least one element selected from cobalt, nickel and iron as a main component, 0 to 40% by volume of a cubic crystal compound comprising at least one compound selected from a carbide, nitride and mutual solid solution of a metal of Group IVB, VB or VIB of the Periodic Table, and the reminder being hexagonal tungsten carbide and inevitable impurities,

Abstract: A coated cemented carbide excellent in peel strength includes a cemented carbide substrate comprising a hard phase containing tungsten carbide and a binder phase, and a hard film being provided on a surface of the substrate with a single layer or two or more laminated layers, wherein (1) at least part of the surface of the substrate is subjected to machining, and (2)(i) substantially no crack is present in particles of the hard phase existing at an interface of the surface of the substrate subjected to machining and the hard film and/or (2)(ii) peak intensities of crystal surfaces satisfy hs(001)wc/hs(101)wc≧1.1×hi(001)wc/hi(101)wc wherein hs(001)wc and hs(101)wc each represent a peak intensity of (001) crystal face and that of (101) crystal face at the surface of the substrate subjected to machining processing, respectively, and hi(001)wc and hi(101)wc each represent a peak intensity of (001) crystal face and that of (101) crystal face in the substrate, respectively.

Abstract: There are disclosed a coated cutting tool which comprises a base material of a hard alloy comprising a hard phase of tungsten carbide and at least one material selected from a carbide, nitride and carbonitride of a metal selected from the Group 4, 5 and 6 of the Periodic Table and a mutual solid solution thereof and a binder phase of at least one element selected from Fe, Ni and Co, and a hard coating film formed on the surface of the base material by a CVD method, wherein the hard coating film has a columnar crystal layer comprising at least one material selected from a carbide, nitride and carbonitride of titanium, the columnar crystal layer contains large-sized particles and small-sized particles, and the ratio of the amounts of the large particles to the small particles is 3 to 50; and a method for producing the same which comprises forming the hard coating film by at least one coating film of a carbide, carbonitride and carbonitroxide of titanium using a hydrocarbon gas containing ethane as a carbon elem

Abstract: There are disclosed a coated cutting tool which comprises a base material of a hard alloy comprising a hard phase of tungsten carbide and at least one material selected from a carbide, nitride and carbonitride of a metal selected from the Group 4, 5 and 6 of the Periodic Table and a mutual solid solution thereof and a binder phase of at least one element selected from Fe, Ni and Co, and a hard coating film formed on the surface of the base material by a CVD method, wherein the hard coating film has a columnar crystal layer comprising at least one material selected from a carbide, nitride and carbonitride of titanium, the columnar crystal layer contains large-sized particles and small-sized particles, and the ratio of the amounts of the large particles to the small particles is 3 to 50; and a method for producing the same which comprises forming the hard coating film by at least one coating film of a carbide, carbonitride and carbonitroxide of titanium using a hydrocarbon gas containing ethane as a carbon elem

Abstract: The present invention is to provide a highly adhesive surface-coated cemented carbide which comprises a cemented carbide base material and a hard film formed on a surface of the base material, characterized in that both of the hard film at a proximate portion of an interface between the hard film and the cemented carbide base material and the cemented carbide at a proximate portion of an interface contain at least one diffusive element selected from chromium, molybdenum, manganese, copper, silicon and an iron group metal and a method for producing the same by uniformly coating at least part of a surface of the base material with a metal, an alloy, or a compound comprising at least one diffusive element selected from iron group metals, chromium, molybdenum, manganese, copper, and silicon followed by coating the surface with the hard film.

Abstract: There are disclosed a surface coated sintered alloy member having a hard film coated on a base material of a sintered alloy of a cemented carbide or cermet, wherein the hard film comprises at least one Ti-containing layer which comprises at least one material selected from the group consisting of TiC, TiN, TiCN, TiCO, TiNO, TiCNO, a composite nitride, carbonitride, nitroxide, carboxide or carbonitroxide each containing Ti and Al, and the uppermost Ti-containing layer has a maximum surface roughness Rmax of 0.6 &mgr;m or less and an average surface roughness Ra of 0.2 &mgr;m or less in the reference length of 5 &mgr;m under conditions without being subjected to machining; and a surface coated sintered alloy member further comprising an aluminum oxide layer formed on the surface of the Ti-containing layer.

Abstract: There are disclosed a coated cemented carbide excellent in peel strength which comprises a cemented carbide base metal comprising a hard phase containing tungsten carbide and a binder phase, and a hard film being provided on a surface of the base metal with a single layer or two or more laminated layers, wherein (1) at least part of the surface of the base metal is subjected to machining, and (2) (i) substantially no crack is present in particles of the hard phase existing at an interface of the surface of the base metal subjected to machining and the hard film and/or (2) (ii) peak intensities of crystal surfaces satisfy

Abstract: There is disclosed a laminated coated-material for cutting tool which comprises a laminated coated-sintered alloy in which on the surface of a substrate comprising a hard alloy or a cermet at least two layers containing an inner layer comprising aluminum oxide and positioned at the substrate side, and an outermost layer having a decorative color and positioned at the far most side of the substrate, and the outermost layer is so coated that it is peeled off by mechanical stress.

Abstract: There are disclosed a coated cutting tool which comprises a base material of a hard alloy comprising a hard phase of tungsten carbide and at least one material selected from a carbide, nitride and carbonitride of a metal selected from the Group 4, 5 and 6 of the Periodic Table and a mutual solid solution thereof and a binder phase of at least one element selected from Fe, Ni and Co, and a hard coating film formed on the surface of the base material by a CVD method, wherein the hard coating film has a columnar crystal layer comprising at least one material selected from a carbide, nitride and carbonitride of titanium, the columnar crystal layer contains large-sized particles and small-sized particles, and the ratio of the amounts of the large particles to the small particles is 3 to 50; and a method for producing the same which comprises forming the hard coating film by at least one coating film of a carbide, carbonitride and carbonitroxide of titanium using a hydrocarbon gas containing ethane as a carbon elem

Abstract: Disclosed is an aluminum oxide coated tool member which comprises a substrate, an intermediate layer containing elements of Al, Ti, O and C provided on the substrate and an outer layer adjacent to the intermediate layer, wherein the outer layer comprises Al2O3, and the intermediate layer comprises at least one layer selected from the group consisting of a single-phase layer of a composite carboxide containing Ti and Al, and a complex-phase layer in which at least two selected from the group consisting of TiC, TiN, Ti(C,N), Ti(C,O), Ti(N,O), Ti(C,N,O), Al2O3, AlN, Al(O,N), Al(O,C), Al(O,N,C), a composite nitride containing Ti and Al, a composite oxide containing Ti and Al, a composite carboxide containing Ti and Al, a composite nitroxide containing Ti and Al, and a composite carbonitroxide containing Ti and Al are dispersed.

Abstract: Disclosed are a plate-crystalline tungsten carbide-containing hard alloy which comprises 4 to 40% by volume of a binder phase containing at least one of iron group metals selected from Co, Ni and Fe as a main component; and the balance of a hard phase comprising tungsten carbide alone, or tungsten carbide and 50% by volume or less of a compound with a cubic structure selected from at least one of carbide and nitride of the 4a (Ti, Zr and Hf), 5a (V, Nb and Ta) or 6a (Cr, Mo and W) group element of the periodic table and mutual solid solutions thereof, and inevitable impurities,wherein when peak intensities at a (001) face and a (101) face in X-ray diffraction using K.alpha. rays with Cu being a target are represented by h(001) and h(101), respectively, the tungsten carbide satisfies h(001)/h(101) .gtoreq.0.50, a composition for forming a plate-crystalline tungsten carbide, and a process for preparing the plate-crystalline tungsten carbide-containing hard alloy.

Abstract: Disclosed are a plate-crystalline tungsten carbide-containing hard alloy which comprises 4 to 40% by volume of a binder phase containing at least one of iron group metals selected from Co, Ni and Fe as a main component; and the balance of a hard phase comprising tungsten carbide alone, or tungsten carbide and 50% by volume or less of a compound with a cubic structure selected from at least one of carbide and nitride of the 4a (Ti, Zr and Hf), 5a (V, Nb and Ta) or 6a (Cr, Mo and W) group element of the periodic table and mutual solid solutions thereof, and inevitable impurities,wherein when peak intensities at a (001) face and a (101) face in X-ray diffraction using K.alpha. rays with Cu being a target are represented by h(001) and h(101), respectively, the tungsten carbide satisfies h(001)/h(101).gtoreq.0.50, a composition for forming a plate-crystalline tungsten carbide, and a process for preparing the plate-crystalline tungsten carbide-containing hard alloy.

Abstract: A drill comprising, a central cutting edge tip which is arranged on an axial portion of a distal end of a spindle body, and a peripheral cutting edge tip which is arranged on an outer peripheral portion of the distal end of the spindle body, each of the tips including a tip body, the central cutting edge tip being arranged so that its longitudinal direction is parallel with a radius direction of the spindle body, a long-side cutting edge and a long-side corner cutting edge adjacent to an axial side of the long-side cutting edge being formed as an end cutting edge, and the short-side corner cutting edge adjacent to the long-side corner cutting edge being arranged so as to go beyond the axis of the spindle body, the peripheral cutting edge tip being arranged so that its longitudinal direction is parallel with a radius direction of the spindle body, the short-side cutting edge and the short-side corner cutting edge adjacent to an outer peripheral side of the short-side cutting edge being 9 formed as an end cutti

Abstract: A metal oxide resistor for suppressing variations in resistivity in use in an atmosphere at a high temperature or humidity. Such a metal oxide resistor includes a sintered body in which carbon particles having an average grain size of 1 .mu.m or less exist in the grain boundaries of metal oxide particles in an amount of 0.05 to 3 wt %, and electrodes formed on at least two opposing surfaces of the sintered body.

Abstract: Disclosed are a hard sintered alloy having fine pores which comprises a sintered alloy comprising 2 to 30% by volume of a dispersed phase of at least one of oxide, carbide and sulfide of Ca, Sr or Ba and mutual solid solutions of these, and the balance of a binder phase comprising at least one metal of Co, Ni and Fe or an alloy containing said metal as a main component and a hard phase of at least one of carbide, nitride and boride of the 4a (Ti, Zr, Hf), 5a (V, Nb, Ta) or 6a (Cr, Mo, W) group metal of the periodic table and mutual solid solutions of these, with a volume ratio of said binder phase to said hard phase being 2:98 to 95:5, wherein fine pores are formed by removing said dispersed phase from a surface portion of said sintered alloy, and a process for preparing the same.

Abstract: The object of the present invention is to provide a stoichiometric B1-type tantalum nitride and a sintered body thereof.A B1-type tantalum nitride and a sintered body thereof, wherein a stoichiometric B1-type tantalum nitride is produced typically according to the method of impact compression, having the properties (a) that the X ray diffraction substantially shows a pattern ascribed to the stoichiometric B1-type tantalum nitride alone but not others, (b) that the measured value of the lattice spacing D (h, k, l) has a deviation of 0.00013 nm or less from the corresponding value calculated based on the B1 structure, (c) that the lattice constant is 0.4335.about.0.4338 nm, (d) that the electron diffraction image substantially shows the spots particular to the stoichiometric B1-type tantalum nitride alone but not others and (e) the value of Z in TaN.sub.z is within a range of 0.96-1.01.

Abstract: A reamer includes a shank portion and a reamer head fixed to the shank portion. A cutting blade is mounted on the reamer head to project axially forwardly from the front end of the reamer head. A bearing guide pad is mounted on the reamer head circumferentially spaced from the cutting blade downstream with respect to the rotating direction of the reamer, and a sizing guide pad is mounted on the reamer head substantially diametrically opposed to the cutting blade. The axial lengths (L2) of the guide surfaces of the bearing guide pad and the sizing guide pad are both not larger than the axial length (L1) of the circle land of the cutting blade, the axial length (L1) of the cutting blade is not larger than the diameter (D) of the reamer, and the width (W2) of the sizing guide pad is not larger than the width (W1) of the bearing guide pad. The axial lengths (L2) of the guide surfaces of the guide pads are preferably 5 mm to 15 mm where the diameter of the reamer is 5 mm to 100 mm.