Abstract: Apparatuses, methods and uses thereof, for sampling fluids and volatile components in such fluids, from a high pressure pipe, are provided. The apparatus can include dual floating pistons moveably disposed in two cylinders. The lower portion of the first cylinder can be fluidly connected to the upper portion of the second cylinder. In operation, fluids can enter the upper portion of the first cylinder, controlled by flow limiting means. Once the first cylinder is filled with sample, the pressure on the sample can equalize to the pressure set in the lower portion of the second cylinder. The sample can be exposed to gas to liberate the volatile components of the sample into a vapour phase. The sample, or vapour phase, can then be discharged from the first cylinder to an analyzing device. The apparatus, method and use of the present disclosure can reduce the risk of plugging of the system.