Abstract: The present invention discloses a method for preparing an activating support and its use to activate metallocene or post-metallocene catalyst component for use in the oligomerization and polymerization of ethylene and alpha-olefins.
Type:
Grant
Filed:
July 16, 2008
Date of Patent:
March 12, 2013
Assignees:
Total Petrochemicals Research Feluy Seneffe, Centre National de la Recherche Scientifique
Inventors:
Abdelkrim El Kadib, Karine Molvinger, Daniel Brunel, Floran Prades, Sabine Sirol
Abstract: The present invention is a process for making an olefin product from an oxygen-containing organic feedstock comprising: providing a mixture of said oxygen-containing feedstock, an hydrocarbon and optionally an inert diluent, contacting said mixture in a reaction zone having an inner surface (the MTO reactor) with a zeolitic catalyst at conditions effective to convert at least a part of the oxygen-containing organic feedstock to olefin products (the MTO reactor effluent), recovering a reactor effluent comprising light olefins, a heavy hydrocarbon fraction and undesired by-products, wherein: at least a part of the inner surface is passivated such that the undesired by-products are reduced by comparison with a non passivated inner surface and for one or more sulphur compound is co-injected with the said oxygen-containing feedstock and the hydrocarbon and said sulphur compound is capable to reduce the undesired by-products by comparison with a non injection of sulphur compound.
Type:
Application
Filed:
July 3, 2009
Publication date:
August 4, 2011
Applicant:
TOTAL PETROCHEMICALS RESEARCH FELUY Seneffe
Inventors:
Giacomo Grasso, Nikolai Nesterenko, Sander Van Donk, Jean-Pierre Dath, Eric Duchesne