Abstract: The present invention relates to the biosynthesis of ?-olefins. In particular, the invention provides methods for the production of medium-chain ?-olefins, more particularly C11 ?-olefins, using a polypeptide with decarboxylase activity on free fatty acids with 8 to 14 carbons, in particular on C8-C12 free fatty acids, more particularly on C12 free fatty acids, or a genetically engineered host cell expressing or overexpressing said polypeptide.

Abstract: The invention relates to a device (10) for safe access to a confined space, comprising: a rectilinear support strut (12), two arms (14, 16) each fixed rigidly to an end (12a) of the strut, at right angles thereto and in opposite directions. A first arm (14) comprises at least one anchoring element (18), the second arm (16) being provided with at least two pulleys (20, 22) whose axis of rotation is at right angles to the plane defined by the strut and the arms. The anchoring element (18) and the two pulleys (20, 22) are arranged so as to allow the passage of a cordage of the anchoring element to the pulleys without interfering with the strut and the first and second arms. The strut (12) has at least one fixing member intended to cooperate with an opening (84) of the confined space in order to ensure the fixing thereof.

Abstract: A process for selective partial hydrogenation of conjugated diene compounds includes at least one, preferably terminal, diene function and at least one additional carbon-carbon double bond, the process including reacting the conjugated diene compounds with hydrogen in the presence of an iridium-NHC based catalyst. The disclosure also relates to a reaction mixture that can be obtained at the end of the process. The disclosure also relates to the use of the reaction mixture.

Abstract: The disclosure relates to a process for obtaining alpha-olefins by heterogeneous catalytic ethenolysis of optionally-functionalized unsaturated, in particular mono-unsaturated, olefins. The disclosure also relates to new supported catalysts that can be used in the process and to a method for preparing the supported catalysts.

Abstract: A method to mitigate the consequences of a vapor cloud explosion due to an accidental release of a flammable gas in an open area, comprising: defining an hazardous area wherein an accidental release of flammable gas is likely to happen; receiving a signal from a detector device able to detect the presence of the flammable gas within the hazardous area, upon reception of a signal indicating the presence of the flammable gas within the hazardous area, generating a control signal to activate a release of a flame acceleration suppression product in the hazardous area, at a rate that is determined as a function of the volume of said hazardous area.

Abstract: The invention relates to a method and to a device for chemical looping combustion CLC of a solid hydrocarbon feed wherein it is proposed to inject the solid hydrocarbon feed so as to limit any occurrence of sticking of the feed to the walls of the injection device. The solid feed is fed into a conveying zone operating under fluidized bed conditions and opening into a combustion reactor. A fluidization gas is injected into this conveying zone while controlling the flow of gas in such a way that the superficial velocity of the gas in the conveying zone is higher than the terminal velocity of the solid hydrocarbon feed particles and the terminal velocity of solid particles present in the combustion reactor, and while controlling the fluidization gas temperature in such a way that the temperature in the conveying zone is less than or equal to 500° C.

Abstract: The invention relates to a process and to a unit for chemical looping oxidation-reduction combustion of a hydrocarbon feed, wherein heat exchanges are controlled through a level variation of a dense fluidized bed of active mass particles in an external heat exchanger (E1, E2), positioned on a transport line carrying particles circulating between a reduction zone (210) and an oxidation zone (200) for the particles in the chemical loop. The bed level variation is allowed through controlled application of a pressure drop on a fluidization gas outlet in the heat exchanger, said pressure drop being compensated by the level variation of an active mass particle bed in a reservoir zone provided on the particle circuit in the chemical loop.

Abstract: The invention relates to a metal element (12) for anchoring an anti-erosion coating that is intended to be fastened alone in an isolated manner to a metal wall or assembled with other identical anchoring elements. The anchoring element (12) has an edge (12a) for fastening to said metal wall and an anchoring body firmly attached to the fastening edge (12a) and having an upper edge (12b) that is away from the fastening edge and intended to be covered by a composite material of concrete type. A section of this upper edge (12b), which is not intended to be juxtaposed and assembled with an upper edge of an identical anchoring element, is provided with a delimiting tab (16) in order to delimit a height of composite material that must cover the upper edge (12b) of said anchoring element, said delimiting tab (16) having a delimiting edge (18) that is a predetermined distance away from a plane defined by the upper edge (12b) of the anchoring element.

Abstract: The invention relates to a process for purifying synthesis gas, comprising at least one stage for separating the crude synthesis gas to be treated into at least two effluents, namely a first part and a complementary part, in which the said first part is subjected to a carbon monoxide conversion stage with steam and the said complementary part is subjected to a COS and HCN catalytic hydrolysis stage, the two gas flows, namely the first part and complementary part, are then each treated separately in two stages intended to remove acid gases such as CO2 and H2S, by washing with aqueous solutions of specific amines, before a recombination stage of the two treated effluents.

Abstract: The invention relates to an orifice chamber designed to expand a gas, in particular intended for a fluid catalytic cracking unit, said orifice chamber comprising the following elements: a chamber having an axis (X), an inlet duct that opens into the chamber, an outlet duct located on the opposite side from the inlet duct following said axis (X), and a plurality of internal plates positioned crosswise to the axis (X) inside the chamber at a distance from one another along the axis (X), each internal plate being provided with a plurality of through-orifices, characterized in that at least the plurality of internal plates is made of a ceramic material.

Abstract: The invention relates to a termination device of a tubular reactor comprising at least one separation element adapted for the separation of solid particles and gaseous effluents and at least one coupling element that is part of an end of said tubular reactor, said separation element being connected to said coupling element, characterized in that each element of the termination device is made of ceramic material. The invention also relates to a tubular reactor, having a vertical or substantially vertical axis, of a fluid catalytic cracking unit equipped with a termination device according to the invention and to a corresponding fluid catalytic cracking unit.

Abstract: An injection element (10) for a gas injection system (1) inside a regenerator of a fluid catalytic cracking unit, said injection element defining a flow passage (12) and being arranged so as to be able to be fastened to a support (11) so that said flow passage opens on one side into a cavity and on the other side into a fluidized catalyst bed, characterized in that said injection element is made of ceramic material.

Abstract: A process for the selective partial hydrogenation of conjugated diene compounds includes at least one, preferably terminal, diene function and at least one additional carbon-carbon double bond, the process including reacting the conjugated diene compounds with hydrogen in the presence of a nickel-NHC based catalyst. The disclosure also relates to a reaction mixture that can be obtained at the end of the process and to a catalyst that can be used in the process. The disclosure also relates to the use of the reaction mixture.

Abstract: The invention relates to a metal element (12) for anchoring an anti-erosion coating that is intended to be fastened alone in an isolated manner to a metal wall or assembled with other identical anchoring elements. The anchoring element (12) has an edge (12a) for fastening to said metal wall and an anchoring body firmly attached to the fastening edge (12a) and having an upper edge (12b) that is away from the fastening edge and intended to be covered by a composite material of concrete type. A section of this upper edge (12b), which is not intended to be juxtaposed and assembled with an upper edge of an identical anchoring element, is provided with a delimiting tab (16) in order to delimit a height of composite material that must cover the upper edge (12b) of said anchoring element, said delimiting tab (16) having a delimiting edge (18) that is a predetermined distance away from a plane defined by the upper edge (12b) of the anchoring element.

Abstract: The invention concerns a CLC process, and its installation, producing high purity dinitrogen, comprising: (a) the combustion of a hydrocarbon feed by reduction of a redox active mass brought into contact with the feed, (b) a first step for oxidation of the reduced active mass (25) obtained from step (a) in contact with a fraction of a depleted air stream (21b), in order to produce a high purity stream of dinitrogen (28) and a stream of partially re-oxidized active mass (26); (c) a second step for oxidation of the stream of active mass (26) in contact with air (20) in order to produce a stream of depleted air and a stream of re-oxidized active mass (24) for use in step (a); (d) dividing the stream of depleted air obtained at the end of step (c) in order to form the fraction of depleted air used in step (b) and a fraction complementary to the depleted air extracted from the CLC.

Abstract: An assembly for loading a refinery and/or petrochemical reactor (100) with solid particles, comprising a dispensing device (110) for loading the reactor with solid particles in a relatively uniform manner, a system (200) for supplying the dispensing device, comprising a flexible sleeve (140) connected to a solid particle tank (130) and to the dispensing device, and a control system (300) comprising a blocking device (310) for blocking the particles flowing in the flexible sleeve, adjacent to a portion (141) of the flexible sleeve and capable, when activated, of moving the walls of the flexible sleeve in such a way as to reduce a cross section of said sleeve at said portion, and an actuating device (350) for actuating the blocking device located at a distance from the blocking device.

Abstract: The present invention relates to the biosynthesis of ?-olefins. In particular, the invention provides methods for the production of medium-chain ?-olefins, more particularly C11 ?-olefins, using a polypeptide with decarboxylase activity on free fatty acids with 8 to 14 carbons, in particular on C8-C12 free fatty acids, more particularly on C12 free fatty acids, or a genetically engineered host cell expressing or overexpressing said polypeptide.

Abstract: The invention relates to a cyclone (10) for mechanical separation of particles in suspension in a gas, in particular intended for a fluid catalytic cracking unit, said cyclone comprising the following elements: a separation chamber (101), an inlet duct (102) that opens into the chamber (101), a gas outlet duct (103) located in the upper portion of the chamber (101) and a particle outlet duct (104) located in the lower portion of the chamber (101), characterized in that each element of the cyclone is made of a ceramic material. The invention also relates to a fluid catalytic cracking unit equipped with at least one cyclone made of ceramic material.

Abstract: The present invention pertains to novel core-shell particles comprising a core of iron oxide and a shell of cobalt oxide, characterized in that they are spherical with a number average diameter, as measured by TEM, of between 1 and 20 nm. This invention is also directed to their uses in the manufacture of a catalyst, and to the method for preparing these particles, by precipitating cobalt oxide onto magnetite or hematite particles which are themselves precipitated from Fe(III) and optionally Fe(II) salts.

Abstract: A method for managing the charging of a space with solid particles, comprising: modelling an expected charging profile over a charging duration, during the charging, receiving, from at least one sensor, measured values of a parameter indicative of the height of a bed of solid particles charged into the space, determining filtered values of the parameter indicative of the height from the measured values received and from the modelled charging profile, and transmitting the filtered values to control the charging with solid particles.