Patents Assigned to TOTAL RESEARCH & TECHNOLOGY
-
Patent number: 11993559Abstract: The invention relates to a process for treating an alcoholic feedstock, comprising: a) a stage of preheating of said alcoholic feedstock to a temperature of between 70° C. and 200° C.; b) a stage of pretreatment on an acidic solid, operating at a temperature of between 70° C. and 200° C., to produce a pretreated alcoholic feedstock; c) a stage of partial vaporization to produce a vaporized stream and a liquid stream; and d) a stage of purification of the liquid stream resulting from stage c), to give a stream rich in water, a stream rich in monoalcohol and a stream rich in impurities.Type: GrantFiled: November 27, 2019Date of Patent: May 28, 2024Assignees: TOTAL RESEARCH & TECHNOLOGY FELUY, IFP Energies NouveliesInventors: Nicolas Aribert, Ludovic Chahen, Arnaud Lanoue, Vincent Coupard, Nikolai Nesterenko
-
Patent number: 11952444Abstract: The present invention relates to a polyethylene resin prepared using a continuous process having and at least one metallocene catalyst composition: a molecular weight distribution Mw/Mn lower than 6.5; a molecular weight distribution Mw/Mn of at least 3.5; a melt index ranging from an HLMI of at least 1.20 g/10 min to an MI2 of at most 6.0 g/10 min wherein MI2 is determined according to ISO 1133:1997 at a temperature of 190° C. and under a load of 2.16 kg, and HLMI is determined according to ISO 1133:1997, at a temperature of 190° C. and under a load of 21.6 kg; melt index ratio HLMI/MI2 below or equal to 30; and a melt strength of X in Newtons, as determined by Göttfert Rheotens Melt Strength Apparatus, 190° C., as described in the Experimental section, satisfying the following equations (1) and/or (2) X is greater than ?0.026 ln(MI2)+0.0498??(1) X is greater than ?0.026 ln(HLMI)+0.1334??(2) with Mw being the weight-average molecular weight and Mn being the number-average molecular weight.Type: GrantFiled: October 14, 2019Date of Patent: April 9, 2024Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Virginie Cirriez, Alexandre Welle, Aurélien Vantomme, Pierre Bernard
-
Patent number: 11919980Abstract: The present invention relates to a catalyst composition comprising: catalyst component A comprising a bridged metallocene compound with two tetrahydroindenyl groups, each group being unsubstituted or substituted; catalyst component B comprising a bridged metallocene compound with a substituted or unsubstituted cyclopentadienyl group and a substituted or unsubstituted fluorenyl group; an optional activator; an optional support; and an optional co-catalyst. The present invention also relates to a polymerization process using said composition. The invention further relates to olefin polymers at least partially catalyzed by said catalyst composition and articles comprising said olefin polymers.Type: GrantFiled: August 2, 2018Date of Patent: March 5, 2024Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Virginie Cirriez, Alexandre Welle, Aurélien Vantomme
-
Patent number: 11634565Abstract: Described herein are caps or closures made from a resin composition having at least one polyethylene having a density of at least 0.940 g/cm3 when measured following the ISO 1183-2 method at 23° C.; erucamide; and at least 700 ppm based on the total weight of the resin composition of at least one ultraviolet absorber selected from the hydroxyphenylbenzotriazole class. A process for the production of such caps or closures is also described herein.Type: GrantFiled: August 25, 2017Date of Patent: April 25, 2023Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventor: David Ribour
-
Patent number: 11618721Abstract: A method for isomerising dehydration in the presence of a specific catalyst, to produce at least one alkene, carried out on a feedstock containing a non-linear primary monoalcohol, where the catalyst includes a zeolite having a series of 8MR channels and a binder having certain pore volume, which catalyst is multilobe-shaped and has characteristics including certain average mesopore volume Vm, and mesopores having a certain diameter, an average certain macropore volume VM, the macropores having a certain diameter, and certain average micropore volume V?, the micropores having a certain diameter, and the catalyst has a certain exposed geometric area.Type: GrantFiled: April 4, 2019Date of Patent: April 4, 2023Assignees: IFP Energies Nouvelles, TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Sylvie Maury, Vincent Coupard, Delphine Bazer-Bachi, Joseph Lopez, Nikolai Nesterenko, Guillaume Duplan, Colin Dupont
-
Patent number: 11358911Abstract: A process for dehydrating an ethanol feedstock to give ethylene, includes: a) a vaporization stage; b) a heating stage; c) a dehydration stage in a multitubular reactor comprising tubes having a length of between 2 and 4 m, said tubes comprising a, preferably zeolitic, dehydration catalyst, the feedstock having an inlet temperature of greater than 400° C. and less than 550° C. and an inlet pressure of between 0.8 and 1.8 MPa, the heat transfer fluid having an inlet temperature of greater than 430° C. and less than 550° C. and a mass flow rate such that the ratio of the mass flow rates of the heat transfer fluid relative to the feedstock is greater than or equal to 10; d) separation into an effluent comprising ethylene and an aqueous effluent; e) purification of the aqueous effluent and separation of a stream of purified water and a stream of unconverted ethanol.Type: GrantFiled: November 27, 2019Date of Patent: June 14, 2022Assignees: IFP Energies nouvelles, TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Kirill Drobyshev, Vincent Coupard, Nikolai Nesterenko, Jean-Christophe Gabelle
-
Publication number: 20220064088Abstract: The invention relates to a process for treating an alcoholic feedstock, comprising: a) a stage of preheating of said alcoholic feedstock to a temperature of between 70° C. and 200° C.; b) a stage of pretreatment on an acidic solid, operating at a temperature of between 70° C. and 200° C., to produce a pretreated alcoholic feedstock; c) a stage of partial vaporization to produce a vaporized stream and a liquid stream; and d) a stage of purification of the liquid stream resulting from stage c), to give a stream rich in water, a stream rich in monoalcohol and a stream rich in impurities.Type: ApplicationFiled: November 27, 2019Publication date: March 3, 2022Applicants: TOTAL RESEARCH & TECHNOLOGY FELUY, IFP Energies NouvellesInventors: Nicolas ARIBERT, Ludovic CHAHEN, Arnaud LANOUE, Vincent COUPARD, Nikolai NESTERENKO
-
Publication number: 20220041525Abstract: A process for dehydrating an ethanol feedstock to give ethylene, includes: a) a vaporization stage; b) a heating stage; c) a dehydration stage in a multitubular reactor comprising tubes having a length of between 2 and 4 m, said tubes comprising a, preferably zeolitic, dehydration catalyst, the feedstock having an inlet temperature of greater than 400° C. and less than 550° C. and an inlet pressure of between 0.8 and 1.8 MPa, the heat transfer fluid having an inlet temperature of greater than 430° C. and less than 550° C. and a mass flow rate such that the ratio of the mass flow rates of the heat transfer fluid relative to the feedstock is greater than or equal to 10; d) separation into an effluent comprising ethylene and an aqueous effluent; e) purification of the aqueous effluent and separation of a stream of purified water and a stream of unconverted ethanol.Type: ApplicationFiled: November 27, 2019Publication date: February 10, 2022Applicants: IFP Energies nouvelles, TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Kirill DROBYSHEV, Vincent COUPARD, Nikolai NESTERENKO, Jean-Christophe GABELLE
-
Patent number: 11230511Abstract: A process for the isomerizing dehydration of a feedstock including a primary monoalcohol, alone or as a mixture, of formula R—CH2—OH, wherein R is a nonlinear alkyl radical of general formula CnH2n+1 where n is an integer between 3 and 20, the process taking place in the gas phase at a weighted average temperature between 275° C. and 400° C., at a pressure between 0.3 MPa and 1 MPa and at a WWH (weight per weight per hour) between 5 and 10 h?1, in the presence of a catalyst containing at least one silicic binder and at least one zeolite having at least one series of channels, the opening of which is defined by a ring of 8 oxygen atoms (8MR), process wherein vaporized feedstock entering the reactor has a weight content of water of from 4% to 35%.Type: GrantFiled: November 6, 2017Date of Patent: January 25, 2022Assignees: TOTAL RESEARCH & TECHNOLOGY FELUY, IFP Energies NouvellesInventors: Sylvie Maury, Vincent Coupard, Thibault Heinz, Guillaume Duplan, Joseph Lopez, Nikolai Nesterenko
-
Patent number: 11118039Abstract: The invention relates to a conductive article made from a composite material comprising: from 50 to 99 wt % of a first polyethylene resin as based on the total weight of said composite material, wherein the first polyethylene resin has a melt index MI2 of at most 0.45 g/10 min as determined according to ISO 1133 (190° C.—2.16 kg), and a density ranging from 0.920 g/cm3 to 0.980 g/cm3 as determined according to ISO 1183 at a temperature of 23° C.; and from 0.2 to 10 wt % of carbon particles as based on the total weight of said composite material as determined according to ISO 11358 selected from nanographene, carbon nanotubes or any combination thereof; wherein the composite material further comprises from 0.10 to 0.48 wt % of polyethylene glycol as based on the total weight of the composite material, and in that said polyethylene glycol is selected to have a weight average molecular weight Mw of at most 20,000 g/mol.Type: GrantFiled: October 4, 2018Date of Patent: September 14, 2021Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Dimitri Rousseaux, Olivier Lhost, Nabil Mellouky, Pascal Navez
-
Patent number: 10995168Abstract: The present invention relates to a process for the preparation of ethylene polymers using a number of reactors arranged in series comprising the steps in which a) ethylene, a diluent, a catalyst, a co-catalyst and optionally comonomers and hydrogen are introduced into a first reactor, b) polymerization of ethylene and optionally comonomers is carried out in the reaction mixture of said first reactor to make ethylene polymers, c) reaction mixture is discharged from said first reactor, d) said reaction mixture and fresh ethylene and optionally comonomers and hydrogen are introduced into the consecutive reactor to make additional ethylene polymers, e) said reaction mixture is discharged from said consecutive reactor and introduced into the further consecutive reactor, if any, with fresh ethylene and optionally comonomers and hydrogen to make additional ethylene polymers, steps c) and d) are repeated until the last reactor of the series, f) reaction mixture is discharged from last reactor of the series and ethylType: GrantFiled: March 4, 2019Date of Patent: May 4, 2021Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Mieke Dams, Daniel Siraux
-
Patent number: 10961172Abstract: A process for purifying an olefinic feedstock containing olefins with 4 carbon atoms and impurities including isobutanal, ethanol and acetone, the process including a pre-treatment containing at least one step of eliminating the ethanol and the water present in the olefinic feedstock and a step of simultaneously eliminating the isobutanal and the acetone, by passing the feedstock from the pre-treatment over at least one fixed bed of at least one adsorbent containing at least one material with a zeolite framework, the material with a zeolite framework being chosen from zeolites, AIPOs, SAPOs and mixtures thereof; the step of simultaneously eliminating the isobutanal and the acetone being carried out at a temperature of between 0 and 200° C., at a pressure of 0.1 to 10 MPa and with an hourly space velocity of the feedstock over the fixed bed of 0.1 to 10 h?1.Type: GrantFiled: November 30, 2018Date of Patent: March 30, 2021Assignees: IFP Energies nouvelles, TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Karin Barthelet, Emmanuelle Bracco, Vincent Coupard, Nikolai Nesterenko
-
Publication number: 20210078919Abstract: A method for isomeris ng dehydration in the presence of a specific catalyst, to produce at least one alkene, carried out on a feedstock containing a non-linear primary monoalcohol, where the catalyst includes a zeolite having a series of 8MR channels and a binder having certain pore volume, which catalyst is multilobe-shaped and has characteristics including certain average mesopore volume Vm, and mesopores having a certain diameter, an average certain macropore volume VM, the macropores having a certain diameter, and certain average micropore volume V?, the micropores having a certain diameter, and the catalyst has a certain exposed geometric area.Type: ApplicationFiled: April 4, 2019Publication date: March 18, 2021Applicants: IFP Energies nouvelles, TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Sylvie MAURY, Vincent COUPARD, Delphine BAZER-BACHI, Joseph LOPEZ, Nikolai NESTERENKO, Guillaume DUPLAN, Colin DUPONT
-
Publication number: 20210078918Abstract: The invention relates to a process for dehydrating alcohols to olefins, comprising a reaction step and a catalyst selectivation step.Type: ApplicationFiled: July 10, 2018Publication date: March 18, 2021Applicants: TOTAL RESEARCH & TECHNOLOGY FELUY, IFP Energies NouvellesInventors: Nicolas ARIBERT, Vincent COUPARD, Nikolai NESTERENKO, Christophe THILLE, Julie MOUNIER
-
Catalyst compositions comprising small size molecular sieves crystals deposited on a porous material
Patent number: 10894246Abstract: Catalyst compositions comprising an inorganic porous material with pore diameters of at least 2 nm and of crystals of molecular sieve, characterized in that the crystals of molecular sieve have an average diameter, measured by scanning electron microscopy, not bigger than 50 nm, and in that the catalyst composition presents a concentration of acid sites ranges from 50 to 1200 ?mol/g measured by TPD NH3 adsorption; and the XRD pattern of said catalyst composition is the same as the X ray diffraction pattern of said inorganic porous material.Type: GrantFiled: February 6, 2019Date of Patent: January 19, 2021Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Kok-Giap Haw, Jean-Michel Goupil, Jean-Pierre Gilson, Valentin Valtchev, Nikolai Nesterenko, Delphine Minoux, Jean-Pierre Dath -
Publication number: 20200385324Abstract: A process for purifying an olefinic feedstock containing olefins with 4 carbon atoms and impurities including isobutanal, ethanol and acetone, the process including a pre-treatment containing at least one step of eliminating the ethanol and the water present in the olefinic feedstock and a step of simultaneously eliminating the isobutanal and the acetone, by passing the feedstock from the pre-treatment over at least one fixed bed of at least one adsorbent containing at least one material with a zeolite framework, the material with a zeolite framework being chosen from zeolites, AIPOs, SAPOs and mixtures thereof; the step of simultaneously eliminating the isobutanal and the acetone being carried out at a temperature of between 0 and 200° C., at a pressure of 0.1 to 10 MPa and with an hourly space velocity of the feedstock over the fixed bed of 0.1 to 10 h?1.Type: ApplicationFiled: November 30, 2018Publication date: December 10, 2020Applicants: IFP Energies nouvelles, TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Karin BARTHELET, Emmanuelle BRACCO, Vincent COUPARD, Nikolai NESTERENKO
-
Patent number: 10858333Abstract: The present invention relates to a process for synthesizing lactide, comprising the steps of: adding thermal energy to at least one solvent; providing one or more components to at least one reactor, the one or more components comprising lactic acid and the at least one solvent; converting at least part of the lactic acid into lactide and water; and recovering at least part of the lactide; wherein the step of adding thermal energy to the at least one solvent is performed prior to the step of adding the at least one solvent to the at least one reactor; wherein the at least one solvent is provided in the at least one reactor independently from the lactic acid by a separate entry into the at least one reactor; and, wherein the step of converting at least part of the lactic acid into lactide and water is performed in one step.Type: GrantFiled: June 20, 2017Date of Patent: December 8, 2020Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Mahdi Yazdanpanah, Jamal Chaouki, Pieter Van Wouwe, Bert Sels
-
Patent number: 10851028Abstract: The invention relates to a process for dehydration of a mono-alcohol, or of a mixture of at least two mono-alcohols, having at least 2 carbon atoms and at most 7 carbon atoms into olefins having the same number of carbons, wherein the process uses a catalyst composition that comprises a modified crystalline aluminosilicate has an acidity between 350 and 500 ?mol/g that comprises, and further wherein the catalyst composition is obtained by a process comprising the steps of providing a crystalline aluminosilicate having a Si/Al framework molar ratio greater than 10; and steaming said crystalline aluminosilicate, or said shaped and/or calcined crystalline aluminosilicate at a temperature ranging from 100° C. to 380° C.; and under a gas phase atmosphere, without liquid, containing from 5 wt % to 100 wt % of steam; at a pressure ranging from 2 to 200 bars; at a partial pressure of H2O from 2 bars to 200 bars; and said steaming being performed during at least 30 min and up to 144 h.Type: GrantFiled: September 6, 2017Date of Patent: December 1, 2020Assignees: TOTAL RESEARCH & TECHNOLOGY FELUY, IFP ENERGIES NOUVELLESInventors: Nikolai Nesterenko, Colin Dupont, Vincent Coupard, Sylvie Maury, Thibault Heinz
-
Patent number: 10851078Abstract: The present invention relates to a process for synthesizing lactide, comprising the steps of: adding thermal energy to at least one of one or more components; providing the one or more components to at least one reactor, the one or more components comprising lactic acid and at least one solvent; converting at least part of the lactic acid into lactide and water; recovering at least part of the lactide; recovering at least part of the at least one solvent; recovering at least part of the thermal energy, wherein at least part of the recovered thermal energy is recovered from the recovered solvent; and adding the recovered thermal energy to at least one of the one or more components.Type: GrantFiled: June 20, 2017Date of Patent: December 1, 2020Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Mahdi Yazdanpanah, Jamal Chaouki, Pieter Van Wouwe, Bert Sels
-
Patent number: 10730970Abstract: The present invention relates to a process for determining a set of one or more operating conditions of an olefin polymerization reactor for the synthesis of a polyolefin in slurry condition, comprising the steps of: a1) introducing a polyolefin into a volume of at least one diluent, said diluent being agitated by a powered agitator at a first temperature T1; b1) monitoring the power consumed by the agitator as a function of the concentration, for at least three concentrations C1, C2, and Cn, which are different from each other; c1) repeating steps a1) and b1) at two or more subsequent temperatures T2 and Tn, which are different from each other and from T1; d1) determining from the power consumed by the agitator as a function of concentration, said set of one or more stable operating conditions for the synthesis of the polyolefin in the olefin polymerization reactor.Type: GrantFiled: December 15, 2016Date of Patent: August 4, 2020Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventor: Alvaro Fernandez