Abstract: A process for the alkylation of an aromatic substrate can include providing an alkylation reaction zone containing an alkylation catalyst, and introducing a feedstock including an aromatic substrate and an alkylating agent into an inlet of the alkylation reaction zone and into contact with the alkylation catalyst. The alkylation reaction zone can be operated at temperature and pressure conditions to cause alkylation of the aromatic substrate in the presence of the alkylation catalyst to produce an alkylation product including a mixture of the aromatic substrate and monoalkylated and polyalkylated aromatic components. The alkylation product can be withdrawn from the alkylation reaction zone. Nitrogen containing compounds in the aromatic substrate, alkylating agent, or both can be monitored in a range 15 wppb to 35 wppm by dry colorimetry. The process can include transalkylation of polyalkylated aromatic components in a transalkylation reaction zone containing a transalkylation catalyst.
Abstract: A method for testing asset management software applications includes: interfacing a user computing device with a computing server, the server being configured to execute an asset management application program; displaying, on the user computing device, a user interface configured to enable a user to perform functions associated with the asset management application program; recording a plurality of user input actions using the interface; generating a program script configured to, upon execution by the computing server, automate performance of each of the recorded plurality of user input actions; executing at least one instance of the generated program script; and measuring one or more performance metrics associated with performance of the computing server during execution of the at least one instance of the generated program script.
Type:
Application
Filed:
February 23, 2015
Publication date:
August 27, 2015
Applicant:
TOTAL RESOURCE MANAGEMENT, INC.
Inventors:
Albert M. JOHNSON, JR., Andrew Joseph MAHEN, Jordan Pressler ORTIZ
Abstract: A method to mitigate the consequences of a vapor cloud explosion due to an accidental release of a flammable gas in an open area, comprising: defining an hazardous area wherein an accidental release of flammable gas is likely to happen; receiving a signal from a detector device able to detect the presence of the flammable gas within the hazardous area, upon reception of a signal indicating the presence of the flammable gas within the hazardous area, generating a control signal to activate a release of a flame acceleration suppression product in the hazardous area, at a rate that is determined as a function of the volume of said hazardous area.
Type:
Application
Filed:
November 12, 2013
Publication date:
August 27, 2015
Applicant:
TOTAL RAFFINAGE CHIMIE
Inventors:
Christophe Gueret, Dirk Roosendans, Leopold Hoorelbeke, Gilles Helschger
Abstract: The present invention is a process to make isoprene comprising: a) providing a reaction zone comprising an acidic aqueous solution, b) introducing, continuously or intermittently, in said reaction zone a mixture comprising (i) isobutanol and optionally (ii) t-butanol or an iso-butene precursor which is not isobutanol and not t-butanol or iso-butene or any combination of two or three of these (ii) components, an aqueous solution of formaldehyde, c) operating said reaction zone at conditions effective to dehydrate isobutanol and optionally (ii) t-butanol and optionally the iso-butene precursor to iso-butene and produce isoprene by reaction of formaldehyde and iso-butene while distilling away a mixture comprising produced isoprene, water, unreacted starting materials and other low boiling point components from this reaction zone to the outside of the reaction zone. In another embodiment isobutanol provides 10% or more of the iso-butene for the isoprene synthesis.
Abstract: The invention relates to a process for the preparation of a particulate polyethylene product in a loop reactor, wherein the polymerization catalyst applied in the polymerization process comprises a particulate metallocene-alumoxane catalyst immobilized on a porous silica support; and whereby said metallocene-alumoxane catalyst is heterogeneously distributed on said porous silica support.
Abstract: The invention relates to a catalyst metering device with a valve formed of an iron-based alloy steel hardened to a Rockwell hardness C of at least 60. The device can be used for metering of a catalyst for an ethylene polymerization reaction. The invention further relates to ethylene polymerization wherein the catalyst is metered in a catalyst metering device with a iron-based alloy steel hardened valve, as well as to a ethylene polymerization reactor comprising such a catalyst metering device.
Abstract: Provided is a method of preparation of a spherical support for an olefin polymerization catalyst. Specifically, provided is a method of preparation of a support which can be used in preparation of an olefin polymerization catalyst, wherein, MgX(I) (X=halogen atom) is prepared by reacting a reaction initiator, nitrogen halide, and magnesium metal, and then magnesium metal and alcohol are reacted in the presence of the MgX, thereby resulting a smooth-surfaced spherical dialkoxy magnesium support having a uniform particle size distribution.
Type:
Grant
Filed:
September 11, 2008
Date of Patent:
August 18, 2015
Assignee:
SAMSUNG TOTAL PETROCHEMICALS CO., LTD.
Inventors:
Eun-Il Kim, Young-Joo Lee, Hoe-Chul Jung, Joon-Ryeo Park
Abstract: The object of the invention is a process for treating bituminous feedstocks wherein the energy required to separate the organic and mineral fractions of said bituminous feedstocks in a treatment unit powered by hot water is provided by chemical looping combustion (CLC).
Abstract: The present invention relates to a method for initiating an ethylene polymerization reaction in an ethylene polymerization loop reactor. More particularly, the invention relates to the timing upon which hydrogen is introduced into the ethylene polymerization loop reactor. The catalysts used in the ethylene polymerization reaction according to present invention are preferably metallocene catalysts.
Abstract: A process for preparing a multimodal polyethylene product with at least two different polyethylene resins can include producing a first polyethylene resin in the presence of a Ziegler-Natta catalyst in a reactor. The Ziegler-Natta catalyst used for the production of the first polyethylene resin has an average particle size (D50) of at most 15 ?m. The HLMI of the first polyethylene resin is between 0.01 and 5 g/10 min. The process can include separately producing a second polyethylene resin in the presence of a Ziegler-Natta catalyst in a reactor. The MI2 of the second polyethylene resin is between 1 and 150 g/10 min. The process can include physically blending together the first and second polyethylene resins to produce a multimodal polyethylene product. The physical blending can be performed in a device for continuously melting and blending the first and second polyethylene resins.
Abstract: The subject of the disclosure concerns C8 or higher, linear or branched fatty chain (meth)acrylic polymers possibly containing at least one ethylene unsaturation, having a weight average molecular weight Mw of less than 20,000 g/mole, free of sulphur-containing, metallic and halogenated compounds and with a residual monomer content measured by GPC of no more than 10% by weight, preferably no more than 7% by weight. A further subject of the disclosure is the synthesis method and the uses of these polymers.
Type:
Grant
Filed:
March 25, 2010
Date of Patent:
August 11, 2015
Assignee:
TOTAL RAFFINAGE MARKETING
Inventors:
Nelly Dolmazon, José Santiago, Yvan Storet, Frédéric Tort
Abstract: A lubricating composition includes one or more base oils, at least one dimercaptothiadiazole derivative, at least one ethylene and alpha-olefin copolymer and at least one amine thiophosphate. The composition can be used for lubricating transmissions such as gearboxes and axles, preferably the manual gearboxes of motor vehicles and enable a reduction in the fuel consumption of vehicles, in particular of motor vehicles, due to the combination of the ethylene and alpha-olefin copolymer, dimercaptothiadiazole derivative and amine thiophosphate which decreases the coefficient of friction of the lubricating composition.
Type:
Application
Filed:
December 14, 2012
Publication date:
August 6, 2015
Applicant:
TOTAL MARKETING SERVICES
Inventors:
Alain Bouffet, Alder Da Costa D'ambros, Richard Vernay, Gérard Thomesse
Abstract: The disclosure relates to a method for extracting hydrocarbons from a tank including providing a facility having an injection well including at least one tube for steam injection, a production well including at least one hydrocarbon extraction tube, a set of measuring sensors, at least one hydrocarbon extracting pump in the production well, an automaton for controlling and monitoring the running of the facility; rejecting the steam into the injection well; extracting the hydrocarbons with the pump of the production well; and controlling speed of the pump depending on the difference between the measured temperature at the pump input and the evaporation temperature calculated on the basis of the measured pressure at the input of the pump. The method enables an increase in hydrocarbon production.
Type:
Grant
Filed:
April 22, 2010
Date of Patent:
July 28, 2015
Assignee:
TOTAL S.A.
Inventors:
Félix Ndinemenu, Pierre Lemetayer, Emmanuel Toguem Nguete
Abstract: The present invention discloses new catalyst systems based on complexes of divalent metals supported by chelating phenoxy ligands for immortal ring-opening polymerisation of cyclic esters and cyclic carbonates.
Type:
Grant
Filed:
April 29, 2010
Date of Patent:
July 28, 2015
Assignees:
TOTAL RESEARCH & TECHNOLOGY FELUY, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS)
Inventors:
Jean-François Carpentier, Yann Sarazin, Valentin Poirier, Marion Helou
Abstract: The present invention relates to a method for optimizing the sequential use of at least two ethylene polymerization catalysts to an ethylene polymerization loop reactor, comprising: transferring to a mixing vessel a first ethylene polymerization catalyst and a first diluent, thereby providing a first catalyst slurry, transferring said first catalyst slurry from said mixing vessel to an ethylene polymerization loop reactor at a concentration suitable for polymerizing ethylene, increasing the ratio of said diluent to said first ethylene polymerization catalyst in said first catalyst slurry, stopping the supply of said first catalyst slurry to said mixing vessel, stopping the supply of said first catalyst slurry to said ethylene polymerization loop reactor, stopping the supply of ethylene to said ethylene polymerization loop reactor, removing said first catalyst slurry from said ethylene polymerization loop reactor, emptying said mixing vessel, optionally rinsing said mixing vessel with fresh diluent, transfe
Abstract: A process for dehydration of an ethanol feedstock into ethylene, comprising the vaporization of said ethanol feedstock in a mixture with at least a portion of the recycled purified water stream from heat exchange with the effluent that is obtained from the last reactor.
Type:
Grant
Filed:
July 20, 2012
Date of Patent:
July 21, 2015
Assignees:
TOTAL PETROCHEMICALS RESEARCH FELUY, IFP ENERGIES NOUVELLES
Inventors:
Vincent Coupard, Natacha Touchais, Stephanie Fleurier, Helena Gonzalez Penas, Walter Vermeiren, Delphine Minoux, Philip De Smedt, Cindy Adam
Abstract: A process for conversion of isobutanol to make propylene can include dehydrating the isobutanol to produce butenes. The process can include cracking the butenes to produce propylene.
Type:
Grant
Filed:
July 8, 2011
Date of Patent:
July 14, 2015
Assignee:
TOTAL RESEARCH & TECHNOLOGY FELUY
Inventors:
Cindy Adam, Delphine Minoux, Nikolai Nesterenko, Sander Van Donk, Jean-Pierre Dath
Abstract: A process for dehydration of an ethanol feedstock into ethylene, comprising the vaporization of said dilute hydrated ethanol feedstock in an exchanger, with heat exchange with the effluent that is obtained from a last reactor, with said mixture being introduced into said vaporization stage at a pressure that is lower than the pressure of the effluent that is obtained from the last reactor, the compression of the mixture that is vaporized in a compressor, the introduction of the vaporized and compressed mixture, into at least one adiabatic reactor that contains at least one dehydration catalyst.
Type:
Grant
Filed:
October 5, 2012
Date of Patent:
July 14, 2015
Assignees:
TOTAL RESEARCH & TECHNOLOGY FELUY, IFP ENERGIES NOUVELLES
Inventors:
Vincent Coupard, Natacha Touchais, Stephanie Fleurier, Helena Gonzalez Penas, Philip De Smedt, Walter Vermeiren, Cindy Adam, Delphine Minoux
Abstract: The invention concerns a catalyst containing a support comprising at least one binder and at least one zeolite having at least one series of channels the opening of which is defined by a ring containing 12 oxygen atoms, said catalyst comprising phosphorus, at least one C1-C4 dialkyl succinate, acetic acid and a hydrodehydrogenating function comprising at least one element from group VI B and at least one element from group VIII, the Raman spectrum of the catalyst comprising bands at 990 and/or 974 cm-1, characteristic of at least one Keggin heteropolyanion, the characteristic bands of said succinate and the characteristic principal band of acetic acid at 896 cm-1. The invention also concerns the process for preparing the catalyst and its use in hydroconversion.
Type:
Grant
Filed:
December 21, 2012
Date of Patent:
July 14, 2015
Assignees:
TOTAL RAFFINAGE MARKETING, IFP ENERGIES NOUVELLES
Inventors:
Laurent Simon, Bertrand Guichard, Gregory Lapisardi, Hugues Dulot, Valentina De Grandi, Delphine Minoux, Jean Pierre Dath