Patents Assigned to Tougas Oilfield Solutions GmbH
  • Patent number: 11718781
    Abstract: A method for the preparation of a scale inhibitor and a method of inhibiting the formation of scale uses a water soluble polymeric gelling agent, in particular synthetic polymer, which has been degraded and reduced in its molecular weight.
    Type: Grant
    Filed: June 5, 2018
    Date of Patent: August 8, 2023
    Assignee: TouGas Oilfield Solutions GmbH
    Inventors: Fatima Dugonjic-Bilic, Benjamin Gerlach, Jasmin Meurer, Marita Neuber
  • Patent number: 10961438
    Abstract: A method to reduce the viscosity of viscosified treatment fluids is disclosed herein. The method includes a water soluble polymer as viscosifying agent, preferably a synthetic water soluble polymer, optionally a crosslinker for the water soluble polymer, a breaker system containing an organic peroxide, mixing the viscosified treatment fluid and the breaker composition and allowing the viscosified treatment fluid and the breaker composition to interact whereby the viscosity of the viscosified treatment is reduced. The application of the process in the production of oil and gas is also discussed.
    Type: Grant
    Filed: November 18, 2015
    Date of Patent: March 30, 2021
    Assignee: TouGas Oilfield Solutions GmbH
    Inventors: Fatima Dugonjic-Bilic, Jasmin Meurer, Marita Neuber
  • Patent number: 10934479
    Abstract: A method to reduce the viscosity of viscosified treatment fluids is disclosed herein. The method includes a water soluble polymer, a breaker system containing at least one aliphatic azo-compound, mixing the viscosified treatment fluid and the breaker composition and allowing the viscosified treatment fluid and the breaker composition to interact whereby the viscosity of the viscosified treatment is reduced. The application of the process in the production of oil and gas and to the treatment fluids is also discussed.
    Type: Grant
    Filed: November 18, 2015
    Date of Patent: March 2, 2021
    Assignee: TouGas Oilfield Solutions, GmbH
    Inventors: Fatima Dugonjic-Bilic, Jasmin Meurer, Marita Neuber
  • Patent number: 10399902
    Abstract: The present invention relates to a method to reduce the water loss in slurries and solutions used in oil field or gas field operations, for example for drilling, cementing and completion operations by adding a copolymer having a high molecular weight characterized by a K value of at least 300, said copolymer comprising structural units derived from monomers having sulfonic acid or derivative thereof, phosphonic acid or derivative thereof and acrylamide functionality.
    Type: Grant
    Filed: February 24, 2015
    Date of Patent: September 3, 2019
    Assignee: TouGas Oilfield Solutions GmbH
    Inventors: Fatima Dugonjic-Bilic, Jasmin Meurer nee Buhler, Marita Neuber
  • Patent number: 9688908
    Abstract: The invention relates to a temperature-stable hydrogel comprising electrolytic water and a copolymer cross-linked to multivalent metal ions. The invention is characterized in that the copolymer contains at least structural units which are derived at up to 0.005-20% by weight from an ethylenically unsaturated phosphonic acid and alkali metal salts thereof and/or ammonia salts, up to 5-40% by weight from an ethylenically unsaturated sulfuric acid and alkali metal salts thereof and/or ammonia salts and up to 5-94.995% by weight from an amide of an ethylenically unsaturated carboxylic acid selected from the group of acrylamide, methacrylamide and/or C1-C4 alkyl derivatives, wherein the percentages are based on the total mass of the monomers used during copolymerization, and that the multivalent metal ions for cross-linking of the copolymers belong to the groups IIIA, IVB, VB, VIIIB and/or VIIIB of the periodic system of elements.
    Type: Grant
    Filed: May 22, 2014
    Date of Patent: June 27, 2017
    Assignee: TOUGAS OILFIELD SOLUTIONS GMBH
    Inventors: Fatima Dugonjic-Bilic, Carolin Usener, Marita Neuber, Margarethe Pfahls, Marion Wissel
  • Publication number: 20170029692
    Abstract: A method for synthesize hydrogels, that may be used in fracturing operations, with increased viscosity from a solution containing water, a copolymer and a dissolved salt of an alkaline metal, an earth alkaline metal and/or an organic amine by addition of a zirconium compound as a crosslinker which comprises: i) providing a copolymer containing structural units of formula I, structural units of formula II, and structural units of formula Ill ii) preparing an aqueous solution by adding the copolymer prepared in step i) to a solution comprising water and the dissolved salt, iii) forming a network of a hydrogel by addition of at least one zirconium-compound to the aqueous solution prepared in step ii), and iv) selecting the amount of the dissolved salt in the hydrogel to range from 0.15 and 10 weight %.
    Type: Application
    Filed: January 30, 2014
    Publication date: February 2, 2017
    Applicant: TouGas Oilfield Solutions GmbH
    Inventors: Fatima Dugonjic-Bilic, Jasmin Meurer nee Buhler, Carolin Usener, Marita Neuber
  • Publication number: 20160122627
    Abstract: The invention relates to a temperature-stable hydrogel comprising electrolytic water and a copolymer cross-linked to multivalent metal ions. The invention is characterized in that the copolymer contains at least structural units which are derived at up to 0.005-20% by weight from an ethylenically unsaturated phosphonic acid and alkali metal salts thereof and/or ammonia salts, up to 5-40% by weight from an ethylenically unsaturated sulfuric acid and alkali metal salts thereof and/or ammonia salts and up to 5-94.995% by weight from an amide of an ethylenically unsaturated carboxylic acid selected from the group of acrylamide, methacrylamide and/or C1-C4 alkyl derivatives, wherein the percentages are based on the total mass of the monomers used during copolymerization, and that the multivalent metal ions for cross-linking of the copolymers belong to the groups IIIA, IVB, VB, VIIIB and/or VIIIB of the periodic system of elements.
    Type: Application
    Filed: May 22, 2014
    Publication date: May 5, 2016
    Applicant: TOUGAS OILFIELD SOLUTIONS GMBH
    Inventors: Fatima Dugonjic-Bilic, Carolin Usener, Marita Neuber, Margarethe Pfahls, Marion Wissel
  • Publication number: 20160075935
    Abstract: An electrolyte-containing aqueous polymer solution is described with a salt content of 5% to 35% by weight with respect to the total weight of the polymer solution, containing at least one dissolved synthetic copolymer which contains structural units which are derived from (i) at least one amide of an ethylenically unsaturated carbonic acid and from (ii) at least one ethylenically unsaturated sulphonic acid or their alkali metal salts and/or ammonium salts, and containing at least one non-ionic surfactant selected from the group formed by alkoxylated fatty alcohols, alkoxylated alkylphenols and/or alkoxylated fatty acids, with the proviso that the mean degree of alkoxylation of said surfactants is 8-10. The aqueous polymer solution is used for the tertiary recovery of crude petroleum and is characterized by very good filtration behaviour, in particular in the presence of saline water.
    Type: Application
    Filed: May 2, 2014
    Publication date: March 17, 2016
    Applicant: TOUGAS OILFIELD SOLUTIONS GMBH
    Inventors: Carolin Usener, Manfred Krattenmacher, Fatima Dugonjic-Bilic, Marita Neuber
  • Patent number: 8962715
    Abstract: Disclosed are stabilized aqueous polymer compositions containing A) a stabilizing amount of a least a sulfur dye or containing a stabilizing amount of a sulfur dye with a compound comprising a heterocyclic system containing nitrogen and sulphur as ring heteroatoms and B) at least one polymer comprising groups which are capable of complex formation with ions. The aqueous polymer compositions are stabilized against thermal or other degradation processes of the polymer by addition of component A) to allow their use even under harsh conditions.
    Type: Grant
    Filed: September 16, 2009
    Date of Patent: February 24, 2015
    Assignee: Tougas Oilfield Solutions GmbH
    Inventors: Friedrich Engelhardt, Werner Spielmann, Christian Bremer, Anja Obermüller, Joachim Christian