Patents Assigned to Towa Chemical Industry Co., Ltd.
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Publication number: 20080097085Abstract: [Object] It is intended to provide a crystalline maltitol powder less prone to consolidation, which is free from the formation of a lump during delivery or storage thereof, does not require pulverization or re-classification in use, is easy to handle in transfer, package opening, addition or mixing to another food material, and so on, and allows for automated transportation and so on. [Means for Solving the Object] The crystalline maltitol powder less prone to consolidation is obtained by charging crystalline or powdery maltitol into a shelf type dryer, a tunnel-type dryer, a cylindrical container, or the like and subjecting the equipment or container to a treatment wherein an air having a temperature of 30 to 33° C. and a relative humidity of 5% is allowed to flow into the equipment or container from one side thereof and withdrawn out of the other side thereof at a space velocity of 11 to 12 for consecutive 24 hours.Type: ApplicationFiled: August 19, 2005Publication date: April 24, 2008Applicant: Towa Chemical Industry Co., Ltd.Inventors: Chihaya Sano, Takashi Noguchi, Tohru Nemoto, Koshiro Shimazu
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Patent number: 6995107Abstract: To obtain a Raney catalyst for fixed bed permitting a continuous use with a high initial activity and to produce a high purity sugar-alcohol at a low cost using the same. For this object, sugar-alcohol is produced by: using the powder type Raney catalyst made by using for the hydrogenation under the hydrogen pressure a lump form Raney catalyst made by (i) the first step for melting nickel and aluminum, (ii) the second step for obtaining quenched lump alloy by quenching droplets of said melted mixture and (iii) the third step for classifying and activating said quenched lump alloy as it is or once it is broken, collecting said lump form Raney catalyst, crushing into powder and reactivating, and hydrogenating sugars under the hydrogen pressure.Type: GrantFiled: November 29, 2004Date of Patent: February 7, 2006Assignees: Towa Chemical Industry Co., Ltd., Nikko Rica CorporationInventors: Koshiro Shimazu, Yoshiaki Tateno, Mitsuo Magara, Naoki Okamoto, Takao Ohshima, Minoru Nagasawa, Hideki Sakamura
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Patent number: 6994889Abstract: The present invention provides hard coating preparation having a hard coating layer, unbreakable, made from sugar/sugar alcohols and oxidized starch and/or acid treated starch, with low waste of coating liquid when forming the coating layer. The hard coating preparation has the hard coating layer containing any one of sugar/sugar alcohols selected from the group of maltitol, xylitol, erythritol, mannitol, lactitol, PALATINIT (registered trade mark), trehalose, sucrose, and oxidized starch and/or acid treated starch.Type: GrantFiled: January 31, 2003Date of Patent: February 7, 2006Assignee: Towa Chemical Industry Co., Ltd.Inventors: Megumi Satomi, Shinya Oda, Shiho Sogawa, Tsuyoshi Ito
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Publication number: 20050153837Abstract: To obtain a Raney catalyst for fixed bed permitting a continuous use with a high initial activity and to produce a high purity sugar-alcohol at a low cost using the same. For this object, sugar-alcohol is produced by: using the powder type Raney catalyst made by using for the hydrogenation under the hydrogen pressure a lump form Raney catalyst made by (i) the first step for melting nickel and aluminum, (ii) the second step for obtaining quenched lump alloy by quenching droplets of said melted mixture and (iii) the third step for classifying and activating said quenched lump alloy as it is or once it is broken, collecting said lump form Raney catalyst, crushing into powder and reactivating, and hydrogenating sugars under the hydrogen pressure.Type: ApplicationFiled: November 29, 2004Publication date: July 14, 2005Applicants: Towa Chemical Industry Co., Ltd., Nikko Rica CorporationInventors: Koshiro Shimazu, Yoshiaki Tateno, Mitsuo Magara, Naoki Okamoto, Takao Ohshima, Minoru Nagasawa, Hideki Sakamura
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Patent number: 6838107Abstract: This relates to foodstuffs containing maltitol. More particularly, this invention relates to improved fat-containing foodstuffs, wherein the improvement includes the partial or total replacement of the fat by a taste effective amount of maltitol.Type: GrantFiled: October 1, 1991Date of Patent: January 4, 2005Assignee: Towa Chemical Industry Co., Ltd.Inventors: Abraham I. Bakal, Shiochi Nanbu, Toshiaki Muraoka
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Patent number: 6414201Abstract: To obtain a Raney catalyst for fixed bed permitting a continuous use with a high initial activity and to produce a high purity sugar-alcohol at a low cost using the same. For this object, sugar-alcohol is produced by: using the powder type Raney catalyst made by using for the hydrogenation under the hydrogen pressure a lump form Raney catalyst made by (i) the first step for melting nickel and aluminum, (ii) the second step for obtaining quenched lump alloy by quenching droplets of said melted mixture and (iii) the third step for classifying and activating said quenched lump alloy as it is or once it is broken, collecting said lump form Raney catalyst, crushing into powder and reactivating, and hydrogenating sugars under the hydrogen pressure.Type: GrantFiled: November 4, 1996Date of Patent: July 2, 2002Assignees: Towa Chemical Industry Co., Ltd., Nikko Rica CorporationInventors: Koshiro Shimazu, Yoshiaki Tateno, Mitsuo Magara, Naoki Okamoto, Takao Ohshima, Minoru Nagasawa, Hideki Sakamura
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Patent number: 5932015Abstract: Provides an economical method for manufacturing high-value added crystalline maltitol and crystalline mixture solid containing this by means of a process wherein a syrup with a maltose content of 40 to 75% by weight in the solid component is subjected to catalytic hydrogenation, the sugar alcohol syrup is then subjected to chromatographic separation to produce a maltitol-containing syrup fraction with a high maltitol content in the solid component, and the maltitol-containing syrup fraction is then subjected to chromatographic separation.Type: GrantFiled: July 3, 1997Date of Patent: August 3, 1999Assignee: Towa Chemical Industry Co., Ltd.Inventors: Susumu Yoneda, Yoshiaki Tateno, Mitsuo Magara, Naoki Okamoto
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Patent number: 5873943Abstract: To provide an economically advantageous process for manufacturing crystalline maltitol and crystalline mixture solid containing crystalline maltitol. The process of this invention uses the syrup having a maltose purity of 81 to 90% as the starting material. The syrup is hydrogenated under the existence of catalyst, and then subjected to a chromatographic separation by using cation-exchange resin, resulting in an aqueous solution of maltitol having a maltitol purity of 94 to 99.9%. The aqueous solution, is further crystallized in the presence of a seed crystal, subjected to a separation, cooled and kneaded so as to manufacture both crystalline maltitol and crystalline mixture solid containing crystalline maltitol at the same time.Type: GrantFiled: May 2, 1996Date of Patent: February 23, 1999Assignee: Towa Chemical Industry Co., Ltd.Inventors: Mitsuo Magara, Koichi Kataura, Yoshiaki Tateno, Yoshimasa Onuki, Yuji Osada, Fumito Yamazaki, Kazuaki Kato
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Patent number: 5583215Abstract: The crystalline mixture solid containing maltitol of the present invention has a crushed and relatively tight crystal structure which can be observed at 1,000 magnifications by a scanning electron microscope, an apparent specific gravity in the range of 0.650-0.750, an oil absorptivity of the powdered crystalline mixture solid containing maltitol having a particle size from 50 mesh to 20 mesh in the range of 7.0%-17%, in other words, is relatively heavy in apparent specific gravity and low in oil absorptivity, and the crystalline mixture solid containing maltitol is prepared by continuously supplying an aqueous solution of maltitol to an extruder provided with elongated cooling and kneading zones, cooling and kneading it in the presence of seed crystals to form a maltitol magma, and continuously extruded from a nozzle.Type: GrantFiled: July 26, 1994Date of Patent: December 10, 1996Assignee: Towa Chemical Industry Co., Ltd.Inventors: Shigeru Kawashima, Mitsuo Magara, Yoshibumi Ishii, Kazuaki Kato
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Patent number: 5462864Abstract: This invention allows high-purity maltose to be manufactured both simply and economically by sequentially going through the steps of liquefaction of starch, saccharification of the resulting liquefied substance by combining with general-purpose enzymes and further saccharification with an enzyme which hydrolyzes oligosaccharides of trisaccharide or more, and also allows the economical and favorable manufacturing of maltitol, the reduced product of the above maltose, by going through an additional reduction step.Type: GrantFiled: May 18, 1992Date of Patent: October 31, 1995Assignee: Towa Chemical Industry Co., Ltd.Inventors: Masahiro Niimi, Yukari Hariu, Koichi Kataura, Yoshibumi Ishii, Kazuaki Kato
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Patent number: 5430184Abstract: An economic hydrogenation process is provided which significantly suppresses palladium catalyzer activity loss, for obtaining very high purity 1,4-CHDA through a simple operation. The process includes bringing the solution containing the hydrogenation reaction product of interest into contact with steam. The resultant products may include resins having excellent weather resistance or physical properties or high purity medical drugs. The process for preparing 1,4-cyclohexandicarboxylic acid is characterized by two consecutive steps. The first step includes the hydrogenation of a solution containing terephthalic acid in the presence of a palladium catalyzer in an acid resistant vessel or in a vessel layered with acid resistant material for preparing 1,4-cyclohexandicarboxylic acid. The second step includes contacting the solution containing 1,4-cyclohexandicarboxylic acid obtained in the first step with the steam, and extracting impurities moved to the steam.Type: GrantFiled: December 17, 1993Date of Patent: July 4, 1995Assignee: Towa Chemical Industry Co., Ltd.Inventors: Yoshiaki Tateno, Chihaya Sano, Kotone Tanaka, Mitsuo Magara, Naoki Okamoto, Kazuaki Kato
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Patent number: 5354856Abstract: The crystalline mixture solid containing maltitol of the present invention has a crushed and relatively tight crystal structure which can be observed at 1,000 magnifications by a scanning electron microscope, an apparent specific gravity in the range of 0.650-0.750, an oil absorptivity of the powdered crystalline mixture solid containing maltitol having a particle size from 50 mesh to 20 mesh in the range of 7.0%-17%, in other words, is relatively heavy in apparent specific gravity and low in oil absorptivity, and the crystalline mixture solid containing maltitol is prepared by continuously supplying an aqueous solution of maltitol to an extruder provided with elongated cooling and kneading zones, cooling and kneading it in the presence of seed crystals to form a maltitol magma, and continuously extruded from a nozzle.Type: GrantFiled: February 24, 1992Date of Patent: October 11, 1994Assignee: Towa Chemical Industry Co., Ltd.Inventors: Shigeru Kawashima, Mitsuo Magara, Yoshibumi Ishii, Kazuaki Kato
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Patent number: 5160546Abstract: The present invention is to solve a variety of problems relative to conventional lactitol crystals and relates to a trihydrate crystal of lactitol having a molecular formula C.sub.12 H.sub.24 O.sub.11.3H.sub.2 O and a melting point of 52.degree.-56.degree. C., a crystalline mixture solid containing it and a process for producing them.Type: GrantFiled: January 2, 1991Date of Patent: November 3, 1992Assignee: Towa Chemical Industry Co., Ltd.Inventors: Shigeru Kawashima, Hiroshi Ide, Kazuaki Kato, Mitsuo Magara, Yoshibumi Ishii
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Patent number: 5141859Abstract: This invention allows high-purity maltose to be manufactured both simply and economically by sequentially going through the steps of liquefaction of starch, saccharification of the resulting liquefied substance by combining with general-purpose enzymes and further saccharification with an enzyme which hydrolyzes oligosaccharides of trisaccharide or more, and also allows the economical and favorable manufacturing of maltitol, the reduced product of the above maltose, by going through an additional reduction step.Type: GrantFiled: October 24, 1989Date of Patent: August 25, 1992Assignee: Towa Chemical Industry Co., Ltd.Inventors: Masahiro Niimi, Yukari Hariu, Koichi Kataura, Yoshibumi Ishii, Kazuaki Kato
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Patent number: 5112273Abstract: The present invention is a process and an apparatus for efficiently separating fine bones from fish flakes wherein fish flakes are dispersed after dehydration or dehydrated after dispersion, and separated using a sieve with a plate with slits formed thereon.Type: GrantFiled: July 27, 1990Date of Patent: May 12, 1992Assignee: Towa Chemical Industry Co. Ltd.Inventor: Kyosuke Nishiya
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Patent number: 5028444Abstract: The present invention relates to quality-improving agents for Frozen SURIMI which is used as a raw material of fish pastes, and also relates to a process for preparing Frozen SURIMI which comprises using such quality-improving agents. The quality-improving agents for addition to Frozen SURIMI comprise, as an effective ingredient, a mixture of sodium bicarbonate, calcium citrate and calcium lactate.Type: GrantFiled: November 22, 1989Date of Patent: July 2, 1991Assignee: Towa Chemical Industry Co., Ltd.Inventors: Yasuhiro Yamamoto, Takeshi Okubo, Shizuo Hatayama, Mayuko Naito, Takashi Ebisu
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Patent number: 4999090Abstract: A process of preparing industrially trans-1,4-cyclohexanedimethanol of high purity by distilling a mixture of cis- and trans-1,4-cyclohexanedimethanol in the presence of alkali, or by heating a mixture of cis- and trans-1,4-cyclohexanedimethanol in the presence of alkali and then distilling the heated mixture, and a process of preparing powdered trans-1,4-cyclohexanedimethanol by pulverizing the distillate obtained above.Type: GrantFiled: July 5, 1989Date of Patent: March 12, 1991Assignee: Towa Chemical Industry Co., Ltd.Inventors: Yoshiaki Tateno, Susumu Yoneda, Naoki Okamoto, Yoshibumi Ishii, Kazuaki Kato
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Patent number: 4999058Abstract: The present invention is to solve a variety of problems relative to conventional lactitol crystals and relates to a trihydrate crystal of lactitol having a molecular formula C.sub.12 H.sub.24 O.sub.11 .multidot.3H.sub.2 O and a melting point of 52.degree.-56.degree. C., a crystalline mixture solid containing it and a process for producing them.Type: GrantFiled: January 24, 1990Date of Patent: March 12, 1991Assignee: Towa Chemical Industry Co., Ltd.Inventors: Shigeru Kawashima, Hiroshi Ide, Kazuaki Kato, Mitsuo Magara, Yoshibumi Ishii
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Patent number: 4758283Abstract: This invention relates to a process for readily and efficiently preparing L-rhamnose with the use of a marine alga belonging to the family Monostromaceae, Ulvales.According to the process of the present invention, rhamnan sulfate is extracted from a marine alga belonging to the family Monostromaceae such as Monostroma nitidium Wittrock and the obtained extract is hydrolyzed by adding acid(s) thereto followed by heating or treating thereof with a cation exchange resin followed by heating to thereby give a solution containing free L-rhamnose.Since the solution thus obtained contains a large amount of salts, the removal of these salts is significantly important in the preparation of L-rhamnose. In the present invention, an effective process therefor is combined with a conventional method by using an ion exchange resin to thereby establish an efficient desalting process.Type: GrantFiled: December 22, 1986Date of Patent: July 19, 1988Assignee: Towa Chemical Industry Co. Ltd.Inventors: Motohiro Takemura, Mochihiro Iljima, Yoshiaki Tateno, Naoki Okamoto, Masaaki Fuse