Patents Assigned to Towa Chemical Industry Co., Ltd.
  • Publication number: 20080097085
    Abstract: [Object] It is intended to provide a crystalline maltitol powder less prone to consolidation, which is free from the formation of a lump during delivery or storage thereof, does not require pulverization or re-classification in use, is easy to handle in transfer, package opening, addition or mixing to another food material, and so on, and allows for automated transportation and so on. [Means for Solving the Object] The crystalline maltitol powder less prone to consolidation is obtained by charging crystalline or powdery maltitol into a shelf type dryer, a tunnel-type dryer, a cylindrical container, or the like and subjecting the equipment or container to a treatment wherein an air having a temperature of 30 to 33° C. and a relative humidity of 5% is allowed to flow into the equipment or container from one side thereof and withdrawn out of the other side thereof at a space velocity of 11 to 12 for consecutive 24 hours.
    Type: Application
    Filed: August 19, 2005
    Publication date: April 24, 2008
    Applicant: Towa Chemical Industry Co., Ltd.
    Inventors: Chihaya Sano, Takashi Noguchi, Tohru Nemoto, Koshiro Shimazu
  • Patent number: 6995107
    Abstract: To obtain a Raney catalyst for fixed bed permitting a continuous use with a high initial activity and to produce a high purity sugar-alcohol at a low cost using the same. For this object, sugar-alcohol is produced by: using the powder type Raney catalyst made by using for the hydrogenation under the hydrogen pressure a lump form Raney catalyst made by (i) the first step for melting nickel and aluminum, (ii) the second step for obtaining quenched lump alloy by quenching droplets of said melted mixture and (iii) the third step for classifying and activating said quenched lump alloy as it is or once it is broken, collecting said lump form Raney catalyst, crushing into powder and reactivating, and hydrogenating sugars under the hydrogen pressure.
    Type: Grant
    Filed: November 29, 2004
    Date of Patent: February 7, 2006
    Assignees: Towa Chemical Industry Co., Ltd., Nikko Rica Corporation
    Inventors: Koshiro Shimazu, Yoshiaki Tateno, Mitsuo Magara, Naoki Okamoto, Takao Ohshima, Minoru Nagasawa, Hideki Sakamura
  • Patent number: 6994889
    Abstract: The present invention provides hard coating preparation having a hard coating layer, unbreakable, made from sugar/sugar alcohols and oxidized starch and/or acid treated starch, with low waste of coating liquid when forming the coating layer. The hard coating preparation has the hard coating layer containing any one of sugar/sugar alcohols selected from the group of maltitol, xylitol, erythritol, mannitol, lactitol, PALATINIT (registered trade mark), trehalose, sucrose, and oxidized starch and/or acid treated starch.
    Type: Grant
    Filed: January 31, 2003
    Date of Patent: February 7, 2006
    Assignee: Towa Chemical Industry Co., Ltd.
    Inventors: Megumi Satomi, Shinya Oda, Shiho Sogawa, Tsuyoshi Ito
  • Publication number: 20050153837
    Abstract: To obtain a Raney catalyst for fixed bed permitting a continuous use with a high initial activity and to produce a high purity sugar-alcohol at a low cost using the same. For this object, sugar-alcohol is produced by: using the powder type Raney catalyst made by using for the hydrogenation under the hydrogen pressure a lump form Raney catalyst made by (i) the first step for melting nickel and aluminum, (ii) the second step for obtaining quenched lump alloy by quenching droplets of said melted mixture and (iii) the third step for classifying and activating said quenched lump alloy as it is or once it is broken, collecting said lump form Raney catalyst, crushing into powder and reactivating, and hydrogenating sugars under the hydrogen pressure.
    Type: Application
    Filed: November 29, 2004
    Publication date: July 14, 2005
    Applicants: Towa Chemical Industry Co., Ltd., Nikko Rica Corporation
    Inventors: Koshiro Shimazu, Yoshiaki Tateno, Mitsuo Magara, Naoki Okamoto, Takao Ohshima, Minoru Nagasawa, Hideki Sakamura
  • Patent number: 6838107
    Abstract: This relates to foodstuffs containing maltitol. More particularly, this invention relates to improved fat-containing foodstuffs, wherein the improvement includes the partial or total replacement of the fat by a taste effective amount of maltitol.
    Type: Grant
    Filed: October 1, 1991
    Date of Patent: January 4, 2005
    Assignee: Towa Chemical Industry Co., Ltd.
    Inventors: Abraham I. Bakal, Shiochi Nanbu, Toshiaki Muraoka
  • Patent number: 6414201
    Abstract: To obtain a Raney catalyst for fixed bed permitting a continuous use with a high initial activity and to produce a high purity sugar-alcohol at a low cost using the same. For this object, sugar-alcohol is produced by: using the powder type Raney catalyst made by using for the hydrogenation under the hydrogen pressure a lump form Raney catalyst made by (i) the first step for melting nickel and aluminum, (ii) the second step for obtaining quenched lump alloy by quenching droplets of said melted mixture and (iii) the third step for classifying and activating said quenched lump alloy as it is or once it is broken, collecting said lump form Raney catalyst, crushing into powder and reactivating, and hydrogenating sugars under the hydrogen pressure.
    Type: Grant
    Filed: November 4, 1996
    Date of Patent: July 2, 2002
    Assignees: Towa Chemical Industry Co., Ltd., Nikko Rica Corporation
    Inventors: Koshiro Shimazu, Yoshiaki Tateno, Mitsuo Magara, Naoki Okamoto, Takao Ohshima, Minoru Nagasawa, Hideki Sakamura
  • Patent number: 5932015
    Abstract: Provides an economical method for manufacturing high-value added crystalline maltitol and crystalline mixture solid containing this by means of a process wherein a syrup with a maltose content of 40 to 75% by weight in the solid component is subjected to catalytic hydrogenation, the sugar alcohol syrup is then subjected to chromatographic separation to produce a maltitol-containing syrup fraction with a high maltitol content in the solid component, and the maltitol-containing syrup fraction is then subjected to chromatographic separation.
    Type: Grant
    Filed: July 3, 1997
    Date of Patent: August 3, 1999
    Assignee: Towa Chemical Industry Co., Ltd.
    Inventors: Susumu Yoneda, Yoshiaki Tateno, Mitsuo Magara, Naoki Okamoto
  • Patent number: 5873943
    Abstract: To provide an economically advantageous process for manufacturing crystalline maltitol and crystalline mixture solid containing crystalline maltitol. The process of this invention uses the syrup having a maltose purity of 81 to 90% as the starting material. The syrup is hydrogenated under the existence of catalyst, and then subjected to a chromatographic separation by using cation-exchange resin, resulting in an aqueous solution of maltitol having a maltitol purity of 94 to 99.9%. The aqueous solution, is further crystallized in the presence of a seed crystal, subjected to a separation, cooled and kneaded so as to manufacture both crystalline maltitol and crystalline mixture solid containing crystalline maltitol at the same time.
    Type: Grant
    Filed: May 2, 1996
    Date of Patent: February 23, 1999
    Assignee: Towa Chemical Industry Co., Ltd.
    Inventors: Mitsuo Magara, Koichi Kataura, Yoshiaki Tateno, Yoshimasa Onuki, Yuji Osada, Fumito Yamazaki, Kazuaki Kato
  • Patent number: 5583215
    Abstract: The crystalline mixture solid containing maltitol of the present invention has a crushed and relatively tight crystal structure which can be observed at 1,000 magnifications by a scanning electron microscope, an apparent specific gravity in the range of 0.650-0.750, an oil absorptivity of the powdered crystalline mixture solid containing maltitol having a particle size from 50 mesh to 20 mesh in the range of 7.0%-17%, in other words, is relatively heavy in apparent specific gravity and low in oil absorptivity, and the crystalline mixture solid containing maltitol is prepared by continuously supplying an aqueous solution of maltitol to an extruder provided with elongated cooling and kneading zones, cooling and kneading it in the presence of seed crystals to form a maltitol magma, and continuously extruded from a nozzle.
    Type: Grant
    Filed: July 26, 1994
    Date of Patent: December 10, 1996
    Assignee: Towa Chemical Industry Co., Ltd.
    Inventors: Shigeru Kawashima, Mitsuo Magara, Yoshibumi Ishii, Kazuaki Kato
  • Patent number: 5462864
    Abstract: This invention allows high-purity maltose to be manufactured both simply and economically by sequentially going through the steps of liquefaction of starch, saccharification of the resulting liquefied substance by combining with general-purpose enzymes and further saccharification with an enzyme which hydrolyzes oligosaccharides of trisaccharide or more, and also allows the economical and favorable manufacturing of maltitol, the reduced product of the above maltose, by going through an additional reduction step.
    Type: Grant
    Filed: May 18, 1992
    Date of Patent: October 31, 1995
    Assignee: Towa Chemical Industry Co., Ltd.
    Inventors: Masahiro Niimi, Yukari Hariu, Koichi Kataura, Yoshibumi Ishii, Kazuaki Kato
  • Patent number: 5430184
    Abstract: An economic hydrogenation process is provided which significantly suppresses palladium catalyzer activity loss, for obtaining very high purity 1,4-CHDA through a simple operation. The process includes bringing the solution containing the hydrogenation reaction product of interest into contact with steam. The resultant products may include resins having excellent weather resistance or physical properties or high purity medical drugs. The process for preparing 1,4-cyclohexandicarboxylic acid is characterized by two consecutive steps. The first step includes the hydrogenation of a solution containing terephthalic acid in the presence of a palladium catalyzer in an acid resistant vessel or in a vessel layered with acid resistant material for preparing 1,4-cyclohexandicarboxylic acid. The second step includes contacting the solution containing 1,4-cyclohexandicarboxylic acid obtained in the first step with the steam, and extracting impurities moved to the steam.
    Type: Grant
    Filed: December 17, 1993
    Date of Patent: July 4, 1995
    Assignee: Towa Chemical Industry Co., Ltd.
    Inventors: Yoshiaki Tateno, Chihaya Sano, Kotone Tanaka, Mitsuo Magara, Naoki Okamoto, Kazuaki Kato
  • Patent number: 5354856
    Abstract: The crystalline mixture solid containing maltitol of the present invention has a crushed and relatively tight crystal structure which can be observed at 1,000 magnifications by a scanning electron microscope, an apparent specific gravity in the range of 0.650-0.750, an oil absorptivity of the powdered crystalline mixture solid containing maltitol having a particle size from 50 mesh to 20 mesh in the range of 7.0%-17%, in other words, is relatively heavy in apparent specific gravity and low in oil absorptivity, and the crystalline mixture solid containing maltitol is prepared by continuously supplying an aqueous solution of maltitol to an extruder provided with elongated cooling and kneading zones, cooling and kneading it in the presence of seed crystals to form a maltitol magma, and continuously extruded from a nozzle.
    Type: Grant
    Filed: February 24, 1992
    Date of Patent: October 11, 1994
    Assignee: Towa Chemical Industry Co., Ltd.
    Inventors: Shigeru Kawashima, Mitsuo Magara, Yoshibumi Ishii, Kazuaki Kato
  • Patent number: 5160546
    Abstract: The present invention is to solve a variety of problems relative to conventional lactitol crystals and relates to a trihydrate crystal of lactitol having a molecular formula C.sub.12 H.sub.24 O.sub.11.3H.sub.2 O and a melting point of 52.degree.-56.degree. C., a crystalline mixture solid containing it and a process for producing them.
    Type: Grant
    Filed: January 2, 1991
    Date of Patent: November 3, 1992
    Assignee: Towa Chemical Industry Co., Ltd.
    Inventors: Shigeru Kawashima, Hiroshi Ide, Kazuaki Kato, Mitsuo Magara, Yoshibumi Ishii
  • Patent number: 5141859
    Abstract: This invention allows high-purity maltose to be manufactured both simply and economically by sequentially going through the steps of liquefaction of starch, saccharification of the resulting liquefied substance by combining with general-purpose enzymes and further saccharification with an enzyme which hydrolyzes oligosaccharides of trisaccharide or more, and also allows the economical and favorable manufacturing of maltitol, the reduced product of the above maltose, by going through an additional reduction step.
    Type: Grant
    Filed: October 24, 1989
    Date of Patent: August 25, 1992
    Assignee: Towa Chemical Industry Co., Ltd.
    Inventors: Masahiro Niimi, Yukari Hariu, Koichi Kataura, Yoshibumi Ishii, Kazuaki Kato
  • Patent number: 5112273
    Abstract: The present invention is a process and an apparatus for efficiently separating fine bones from fish flakes wherein fish flakes are dispersed after dehydration or dehydrated after dispersion, and separated using a sieve with a plate with slits formed thereon.
    Type: Grant
    Filed: July 27, 1990
    Date of Patent: May 12, 1992
    Assignee: Towa Chemical Industry Co. Ltd.
    Inventor: Kyosuke Nishiya
  • Patent number: 5028444
    Abstract: The present invention relates to quality-improving agents for Frozen SURIMI which is used as a raw material of fish pastes, and also relates to a process for preparing Frozen SURIMI which comprises using such quality-improving agents. The quality-improving agents for addition to Frozen SURIMI comprise, as an effective ingredient, a mixture of sodium bicarbonate, calcium citrate and calcium lactate.
    Type: Grant
    Filed: November 22, 1989
    Date of Patent: July 2, 1991
    Assignee: Towa Chemical Industry Co., Ltd.
    Inventors: Yasuhiro Yamamoto, Takeshi Okubo, Shizuo Hatayama, Mayuko Naito, Takashi Ebisu
  • Patent number: 4999090
    Abstract: A process of preparing industrially trans-1,4-cyclohexanedimethanol of high purity by distilling a mixture of cis- and trans-1,4-cyclohexanedimethanol in the presence of alkali, or by heating a mixture of cis- and trans-1,4-cyclohexanedimethanol in the presence of alkali and then distilling the heated mixture, and a process of preparing powdered trans-1,4-cyclohexanedimethanol by pulverizing the distillate obtained above.
    Type: Grant
    Filed: July 5, 1989
    Date of Patent: March 12, 1991
    Assignee: Towa Chemical Industry Co., Ltd.
    Inventors: Yoshiaki Tateno, Susumu Yoneda, Naoki Okamoto, Yoshibumi Ishii, Kazuaki Kato
  • Patent number: 4999058
    Abstract: The present invention is to solve a variety of problems relative to conventional lactitol crystals and relates to a trihydrate crystal of lactitol having a molecular formula C.sub.12 H.sub.24 O.sub.11 .multidot.3H.sub.2 O and a melting point of 52.degree.-56.degree. C., a crystalline mixture solid containing it and a process for producing them.
    Type: Grant
    Filed: January 24, 1990
    Date of Patent: March 12, 1991
    Assignee: Towa Chemical Industry Co., Ltd.
    Inventors: Shigeru Kawashima, Hiroshi Ide, Kazuaki Kato, Mitsuo Magara, Yoshibumi Ishii
  • Patent number: 4758283
    Abstract: This invention relates to a process for readily and efficiently preparing L-rhamnose with the use of a marine alga belonging to the family Monostromaceae, Ulvales.According to the process of the present invention, rhamnan sulfate is extracted from a marine alga belonging to the family Monostromaceae such as Monostroma nitidium Wittrock and the obtained extract is hydrolyzed by adding acid(s) thereto followed by heating or treating thereof with a cation exchange resin followed by heating to thereby give a solution containing free L-rhamnose.Since the solution thus obtained contains a large amount of salts, the removal of these salts is significantly important in the preparation of L-rhamnose. In the present invention, an effective process therefor is combined with a conventional method by using an ion exchange resin to thereby establish an efficient desalting process.
    Type: Grant
    Filed: December 22, 1986
    Date of Patent: July 19, 1988
    Assignee: Towa Chemical Industry Co. Ltd.
    Inventors: Motohiro Takemura, Mochihiro Iljima, Yoshiaki Tateno, Naoki Okamoto, Masaaki Fuse