Patents Assigned to Toyo Soda Manufacturing Co., Ltd.
  • Patent number: 4625569
    Abstract: A liquid injection device, comprising:a pair of a rotor and a stator relatively rotatable in a face-contacting relationship under a liquid-tight state;a plurality of small openings penetrating through the rotor or stator and communicating to a plurality of liquid systems; anda plurality of bridging grooves or openings provided on the contacting surface of the rotor or stator to communicate two or more of the small openings so as to form a liquid flowing path. The rotor can be rotated to a predetermined angle in a normal or reverse direction with respect to the stator so as to communicate a desired number of small openings or cut off the communication between a desired number of small openings by the relative shift of the bridging grooves with respect to the small openings.
    Type: Grant
    Filed: January 16, 1985
    Date of Patent: December 2, 1986
    Assignee: Toyo Soda Manufacturing Co., Ltd.
    Inventors: Jun-ichi Toei, Nobuyuki Baba, Keiichi Housako, Tetsuo Ikushige
  • Patent number: 4625064
    Abstract: An improved process for preparing a bis [.beta.-(N,N-dimethylamino)ethyl]ether by reacting a bismethohalide of bis [.beta.-(N,N-dimethylamino)ethyl]ether represented by the following general formula: ##STR1## (wherein X denotes a halogen atom), with an aliphatic amine having a boiling point of not lower than 220.degree. C. at atmospheric pressure and having a primary amino group in the molecule thereof. The process comprises the following two steps (a) and (b): (a) a step of distilling out water at a temperature of not more than 130.degree. C. under reduced pressure from a mixture of said bismethohalide aqueous solution and said aliphatic amine to provide a concentration of said bismethohalide to water of not less than 85% by weight, and (b) a step of reacting said bismethohalide and amine in a solid-liquid phase at a temperature of not lower than 140.degree. C.
    Type: Grant
    Filed: April 6, 1984
    Date of Patent: November 25, 1986
    Assignee: Toyo Soda Manufacturing Co., Ltd.
    Inventors: Sadakatsu Kumoi, Keiji Mitarai, Yukihiro Tsutsumi
  • Patent number: 4623689
    Abstract: An aqueous colored polymer is provided, which comprises (a) a homopolymer of an ethylenically unsaturated sulfonic acid or its salt or (b) a copolymer of an ethylenically unsaturated sulfonic acid or its salt with other ethylenically unsaturated monomer, said homopolymer or copolymer being dyed with a basic dye and having a lowest film-forming temperature of not higher than 35.degree. C. The aqueous colored polymer is prepared by polymerizing an ethylenically unsaturated sulfonic acid or its salt, or its mixture with other ethylenically unsaturated monomer by an aqueous solution or emulsion polymerization procedure at a temperature of not higher than 100.degree. C. in a specified amount of water and then adding a basic dye to the resulting polymer solution or emulsion, or carrying out this solution or emulsion polymerization in the presence of a basic dye. The aqueous polymer is useful as an aqueous ink such as an ink for the ink jet recording.
    Type: Grant
    Filed: June 27, 1984
    Date of Patent: November 18, 1986
    Assignee: Toyo Soda Manufacturing Co., Ltd.
    Inventors: Takashi Shintani, Noriaki Emura, Tetsuo Tanaka, Yasuhiro Oda
  • Patent number: 4622113
    Abstract: Process or producing caustic alkalis or alkali hydroxides by electrolysis, employing a double electrode-type electrolysis tank in which a cation exchange membrane is provided to divide the inside of the tank into cathode and anode compartments, supplying to the anode compartment an alkali chloride, supplying water or a dilute solution of an alkali hydroxide into the cathode compartment, and taking away the alkali hydroxide and the hydrogen gas produced by electrolysis, in a mixed state of gas and liquid from the cathode compartment. The electrolysis tank comprises a number of finger-anodes extending from one of the walls of the tank and a number of finger-like hollow cathodes extending from the other wall of the tank, into which the finger-anodes project to form a gap therebetween, and a cation exchange membrane extending through the gap to divide the inside of the tank into cathode and anode compartments.
    Type: Grant
    Filed: November 19, 1984
    Date of Patent: November 11, 1986
    Assignees: Toyo Soda Manufacturing Co., Ltd., Chlorine Engineers Corp., Ltd.
    Inventors: Takao Satoh, Masaki Murakami, Nobuhiro Kawasaki, Teruo Ichisaka, Shinji Katayama
  • Patent number: 4622112
    Abstract: A process for the preparation of chlorinated polyvinyl aromatic compound is described, comprising the steps of: (1) in an aromatic organic solvent, forming a solution of an aromatic compound represented by formula (I): ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, and R.sup.6 is selected from hydrogen and an alkyl groups containing from 1 to 6 carbon atoms, and R.sup.4 and R.sup.5, or R.sup.5 and R.sup.6 can together form a ring by ##STR2## wherein each of R.sup.7, R.sup.8, R.sup.9, and R.sup.10 is selected from hydrogen and an alkyl group containing from 1 to 6 carbon atoms, and n has an average value of from 50 to 30,000; and (2) subjecting the solution to electrolysis reaction in the pressure of an aqueous solution containing chloride ions.
    Type: Grant
    Filed: March 19, 1985
    Date of Patent: November 11, 1986
    Assignee: Toyo Soda Manufacturing Co., Ltd.
    Inventors: Hiroyuki Watanabe, Toru Seita
  • Patent number: 4621090
    Abstract: An antifungal composition comprising an effective amount of carbamate derivative having the formula (I): ##STR1## where X is 2-naphthyl, 5-indanyl, 5,6,7,8-tetrahydro-2-naphthyl, 1,4-methano-1,2,3,4-tetrahydro-6-naphthyl, 1,4-ethano-1,2,3,4-tetrahydro-6-naphthyl, 2-quinolyl, or a phenyl group having one or two of the same or different substituents selected from the group of halogen atom, lower alkyl, lower alkenyl, lower alkoxy, lower alkenyloxy, halogenated lower alkyl, lower alkylthio, lower alkylsulfonyl, lower alkylamino, nitro, and methylenedioxy;Y is an oxygen atom or a sulfur atom;Z is lower alkyl group;W is pyridyl group having one or two of the same substituents selected from the group of lower alkyl, lower alkoxy, lower alkenyloxy, and lower alkylamino.
    Type: Grant
    Filed: September 13, 1984
    Date of Patent: November 4, 1986
    Assignee: Toyo Soda Manufacturing Co., Ltd.
    Inventors: Kazuo Iwata, Tetsuo Takematsu, Yuji Nonaka, Akira Nakanishi, Hideo Morinaka, Kenji Tsuzuki, Mitsuyuki Murakami, Takeshi Uotani
  • Patent number: 4617397
    Abstract: 2-Alkylaminopyridine derivatives represented by the general formula ##STR1## wherein R denotes a lower alkyl group and Y denotes a halogen atom, and a process for producing the same. These compounds are useful as intermediates in medicines and agricultural chemicals. The final products prepared from the intermediates of the invention are especially useful as herbicides for use in paddy fields and farmlands.
    Type: Grant
    Filed: June 21, 1985
    Date of Patent: October 14, 1986
    Assignee: Toyo Soda Manufacturing Co., Ltd.
    Inventors: Kenji Tsuzuki, Hideo Morinaka
  • Patent number: 4617286
    Abstract: The disclosed catalyst for polyurethane comprises an organic carboxylic acid salt of a tertiary amine compound and 1-methyl-4-(2-dimethylaminoethyl)piperazine. The tertiary amine compound is selected from the group of triethylenediamine, bis(2-dimethylaminoethyl)ether and N,N,N',N",N"-pentamethyldiethylenetriamine and the organic carboxylic acid is selected from the organic carboxylic acids having 1-20 carbon atoms.
    Type: Grant
    Filed: September 5, 1984
    Date of Patent: October 14, 1986
    Assignee: Toyo Soda Manufacturing Co., Ltd.
    Inventors: Shoji Arai, Yutaka Tamano, Yukihiro Tsutsumi
  • Patent number: 4604372
    Abstract: A zeolite agglomerated article is provided, which is formed from a zeolite composition having incorporated therein at least one additive selected from alkaline earth metal oxides and hydroxides, alkaline earth metal aluminates and silicates and double salts containing an alkaline earth metal chloride. The zeolite agglomerated article is stable against a hydrothermal reaction.
    Type: Grant
    Filed: November 25, 1985
    Date of Patent: August 5, 1986
    Assignee: Toyo Soda Manufacturing Co., Ltd.
    Inventors: Satoru Morishita, Kenzi Shindo, Isao Tozawa, Yukio Taga
  • Patent number: 4600432
    Abstract: Propionic acid derivatives represented by the formula (I) ##STR1## wherein X indicates an oxygen atom or a sulfur atom, Y indicates a hydrogen atom or a halogen atom, R.sub.1 and R.sub.2 are the same or different group, indicating an alkyl group, alkenyl group, alkynyl group, cycloalkyl group, lower alkoxy group, lower alkoxyalkyl group, phenyl group, respectively, or R.sub.1 and R.sub.2 may form a heterocyclic group together with a nitrogen atom bonding to said R.sub.1 and R.sub.2, and herbicidal compositions employing them.
    Type: Grant
    Filed: July 25, 1985
    Date of Patent: July 15, 1986
    Assignees: Agro-Kanesho Co., Ltd., Toyo Soda Manufacturing Co., Ltd.
    Inventors: Rokuro Akahira, Shinzo Someya, Mikio Ito, Akira Nakanishi, Yuji Nonaka
  • Patent number: 4594450
    Abstract: A process for producing an .alpha.-halogeno-.beta.-phenylpropionic acid represented by the general formula: ##STR1## where X is a halogen atom, which comprises hydrolyzing under heating a halogen-containing ethylbenzene derivative represented by the general formula: ##STR2## where W is a cyano group, an amidocarbonyl group or a lower alkoxycarbonyl group, and X is as defined above, in an aqueous mineral acid solution under vigorous stirring.
    Type: Grant
    Filed: October 12, 1984
    Date of Patent: June 10, 1986
    Assignee: Toyo Soda Manufacturing Co., Ltd.
    Inventors: Kiyotaka Oyama, Tuneo Harada
  • Patent number: 4590223
    Abstract: Disclosed is a catalytic composition comprising a substance having the general formula: ##STR1## where R.sub.1 is an alkyl group having 1 to 3 C atoms and R.sub.2 is a group selected from --H, --CH.sub.3 and CH.sub.2 CH.sub.3.The catalytic composition is odorless and excellent in the urethane forming reaction in production of polyurethane.
    Type: Grant
    Filed: June 24, 1985
    Date of Patent: May 20, 1986
    Assignee: Toyo Soda Manufacturing Co., Ltd.
    Inventors: Shoji Arai, Masazumi Hasegawa
  • Patent number: 4587214
    Abstract: .alpha.-L-aspartylphenylalanine lower alkyl esters are prepared by a process wherein fumaric acid, ammonia and a lower alkyl ester of L-phenylalanine are contacted with a culture or treated culture of a microorganism belonging to the genus Pseudomonas, and being capable of producing a .alpha.-L-aspartyl-L-phenylalanine lower alkyl ester from fumaric acid, ammonia and a lower alkyl ester of L-phenylalanine.
    Type: Grant
    Filed: August 3, 1983
    Date of Patent: May 6, 1986
    Assignee: Toyo Soda Manufacturing Co., Ltd.
    Inventors: Tuneo Harada, Hisao Takemoto, Tatsuo Igarashi
  • Patent number: 4587115
    Abstract: A faujasite type zeolite having a high SiO.sub.2 /Al.sub.2 O.sub.3 ratio is prepared by simultaneously and continuously supplying an aqueous solution of an alkali metal silicate and an aqueous solution of an aluminum-containing compound whereby the alkali metal silicate is continuously reacted with the aluminum-containing compound to prepare a homogeneous phase compound of a granular amorphous aluminosilicate containing aluminum in an amount of 10 to 16% by weight, as Al.sub.2 O.sub.3 and based on the anhydride; and then, crystallizing the granular homogeneous phase amorphous aluminosilicate in an aqueous alkali metal hydroxide solution having a concentration of 4 to 10% by weight.
    Type: Grant
    Filed: June 8, 1984
    Date of Patent: May 6, 1986
    Assignee: Toyo Soda Manufacturing Co., Ltd.
    Inventors: Junji Arika, Michiyuki Aimoto, Hiroshi Miyazaki
  • Patent number: 4587225
    Abstract: A zirconia type sintered body consisting essentially of 50 to 98% by weight of zirconia (ZrO.sub.2) containing 1.5 to 5 mole % of yttria (Y.sub.2 O.sub.3) and 50 to 2% by weight of alumina (Al.sub.2 O.sub.3), spinal (MgAl.sub.2 O.sub.4) or mullite (3Al.sub.2 O.sub.3.2SiO.sub.2), and having a three-point bending strength of at least 1700 MPa is provided. This sintered body is prepared by a process wherein a powdery composition consisting essentially of 50 to 98% by weight of (a1) a powder of zirconia containing 1.5 to 5 mole % of yttria or (a2) a mixture comprising 1.5 to 5 mole % of a yttria powder and 95 to 98.5 mole % of a zirconia powder and 2 to 50% by weight of (b) a powder of an alumina type oxide selected from alumina, an alumina-magnesia type oxide, an alumina-silica type oxide, a mixture of alumina and magnesia and a mixture of alumina and silica is subjected to a hot isotactic pressing treatment under a pressure of at lesast 50 MPa at temperature of 1300.degree. C. to 1700.degree. C.
    Type: Grant
    Filed: October 17, 1984
    Date of Patent: May 6, 1986
    Assignee: Toyo Soda Manufacturing Co., Ltd.
    Inventors: Koji Tsukuma, Kuniyoshi Ueda, Takaaki Tsukidate
  • Patent number: 4582937
    Abstract: Ethyleneamines are efficiently recovered from an aqueous solution thereof by extracting them from the aqueous solution into an organic phase with an extractant selected from carbonyl group-containing organic solvents, benzyl alcohol, carboxylic acids and salts thereof, alkylphosphoric acids and salts thereof, and mixed solvents containing at least one of these extractants. The ethyleneamines in the organic phase is recovered preferably from the organic phase to the aqueous phase by incorporating an acid therein, followed by phase separation.
    Type: Grant
    Filed: April 12, 1985
    Date of Patent: April 15, 1986
    Assignee: Toyo Soda Manufacturing Co., Ltd.
    Inventors: Yoichi Hiraga, Tsugio Murakami, Hiroyuki Saito, Osamu Fujii
  • Patent number: 4578222
    Abstract: A process for preparing a perfluorinated or polyfluorinated aliphatic carboxylic acids wherein a perfluorinated or polyfluorinated aliphatic halide of the formula: R.sub.f X where R.sub.f is a perfluorinated or polyfluorinated aliphatic group and X is a halogen atom is reacted with carbon dioxide in the presence of metal under the irradiation of ultrasound and the reaction product is hydrolyzed to form a perfluorinated or polyfluorinated aliphatic carboxylic acid of the formula: R.sub.f COOH where R.sub.f is the same as defined above.
    Type: Grant
    Filed: August 5, 1985
    Date of Patent: March 25, 1986
    Assignees: Daikin Kogyo Co., Ltd., Toyo Soda Manufacturing Co., Ltd.
    Inventors: Nobuo Ishikawa, Mitsuru Takahashi
  • Patent number: 4577004
    Abstract: A chloroprene polymer is produced by aqueous emulsion polymerization in the presence of a cyclic polysulfide compound which is employed in a quantity equal to at least 0.1% by weight of the weight of the chloroprene, followed by deflocculating the polymer.
    Type: Grant
    Filed: December 14, 1984
    Date of Patent: March 18, 1986
    Assignee: Toyo Soda Manufacturing Co., Ltd.
    Inventors: Noriaki Emura, Takashi Ariyoshi, Toshikazu Kato
  • Patent number: 4567206
    Abstract: A fluorocarbon polymer comprising a perfluorocarbon main chain and a pendant chain attached to the main chain, characterized in that the pendant chain has a quaternary ammonium type terminal group.
    Type: Grant
    Filed: December 28, 1983
    Date of Patent: January 28, 1986
    Assignees: Toyo Soda Manufacturing Co., Ltd., Sagami Chemical Research Center
    Inventors: Kiyohide Matsui, Yoshiyuki Kikuchi, Tamejiro Hiyama, Etsuko Tobita, Kiyoshi Kondo, Akira Akimoto, Toru Seita, Hiroyuki Watanabe
  • Patent number: 4562055
    Abstract: A zeolite similar to ZSM-5, having lattice spacings (d-values), shown in Table 1, of the X-ray powder diffraction pattern, and a ferrierite zeolite are prepared by crystallizing a homogeneous phase compound of a granular amorphous aluminosilicate in water or in an aqueous solution of an alkali metal hydroxide and/or an alkali metal silicate.
    Type: Grant
    Filed: September 20, 1983
    Date of Patent: December 31, 1985
    Assignee: Toyo Soda Manufacturing Co., Ltd.
    Inventors: Junji Arika, Hiroshi Miyazaki, Kazushige Igawa, Keiji Itabashi