Abstract: The present invention is to provide a nonaqueous electrolytic solution prepared by dissolving an electrolyte salt in a nonaqueous solvent and an energy storage device, wherein the nonaqueous electrolytic solution includes LiPF2(—OC(?O)—C(?O)O—)2 and at least one kind of a compound having a carbon-carbon triple bond represented by the following general formula (I): (wherein R1 and R2 each independently represent a hydrogen atom or an alkyl group having from 1 to 6 carbon atoms and optionally substituted with a halogen atom; and R3 represents a methyl group or an ethyl group. X represents a hydrogen atom or —CR1R2—OS(?O)2—R3.).
Abstract: A polyimide precursor comprising at least one repeating unit represented by the following chemical formula (5): in which A3 is a divalent group of an aromatic diamine or an aliphatic diamine, from which amino groups have been removed; and X3 and Y3 are each independently hydrogen, an alkyl group having 1 to 6 carbon atoms, or an alkylsilyl group having 3 to 9 carbon atoms, and/or at least one repeating unit represented by the following chemical formula (6): in which A3 is a divalent group of an aromatic diamine or an aliphatic diamine, from which amino groups have been removed; and X4 and Y4 are each independently hydrogen, an alkyl group having 1 to 6 carbon atoms, or an alkylsilyl group having 3 to 9 carbon atoms.
Abstract: Provided is a production device including: a first reactor to form a second gas containing an ester and nitric oxide from a first gas containing carbon monoxide, a nitrite, and nitric oxide; an absorption column to separate the second gas and an absorbing solution into a condensate containing the ester and a noncondensable gas; a second reactor to introduce an alcohol, the noncondensable gas, and oxygen gas thereinto to form a third gas containing nitric oxide and a nitrite; a third reactor to form a fourth gas containing a nitrite from the noncondensable gas and a bottom liquid from the second reactor and to feed the fourth gas to the second reactor; a first measurement unit to measure the concentration of a nitrite in the first gas; and a first flow rate-adjusting unit to adjust the amount of the noncondensable gas to the third reactor based on the concentration.
Abstract: An oxynitride phosphor powder is an ?-SiAlON phosphor having a dominant wavelength of 565-577 nm and fluorescence intensity and external quantum efficiency that are high enough for practical use. The oxynitride phosphor powder comprises an ?-SiAlON represented by the compositional formula: Cax1Eux2Ybx3Si12?(y+z)Al(y+z)OzN16?z (wherein 0.0<x1?2.0, 0.0000<x2?0.0100, 0.0000<x3?0.0100, 0.4?x2/x3?1.4, 1.0?y?4.0, 0.5?z?2.0).
Abstract: The present invention is concerned with a nonaqueous electrolytic solution having an electrolyte salt dissolved in a nonaqueous solvent, the nonaqueous electrolytic solution containing a compound represented by the following general formula (X), in which a polar group (X) is bound to a phosphorus atom (P), and capable of improving electrochemical characteristics in a broad temperature range; an energy storage device using the same; and a novel compound.
Abstract: Provided is a lithium titanate powder for an electrode of an energy storage device, the lithium titanate powder comprising Li4Ti5O12 as a main component, wherein, when the volume surface diameter calculated from the specific surface area determined by the BET method is represented as DBET and the crystallite diameter calculated from the half-peak width of the peak of the (111) plane of Li4Ti5O12 by the Scherrer equation is represented as DX, DBET is 0.1 to 0.6 ?m, DX is greater than 80 nm, and (DBET/DX (?m/?m)) the ratio of DBET to DX is 3 or less. Also provided are an active material including the lithium titanate powder and an energy storage device using the active material.
Abstract: A nonaqueous electrolytic solution having an electrolyte salt dissolved in a nonaqueous solvent, the nonaqueous electrolytic solution containing a lithium salt having a specific ?,?-dihydroxy carboxylic acid ester structure, phosphono hydroxy carboxylic acid structure, alkoxycarbonyl hydroxy carboxylic acid structure, or formyloxy structure; an energy storage device using the nonaqueous electrolytic solution; and a lithium salt used for the nonaqueous electrolytic solution. This nonaqueous electrolytic solution makes it possible not only to improve the electrochemical characteristics when the energy storage device is used at a high temperature and a high voltage and to improve the capacity retention rate after high-voltage and high-temperature storage, but also to suppress gas generation.
Type:
Application
Filed:
May 13, 2015
Publication date:
September 21, 2017
Applicant:
UBE INDUSTRIES, LTD.
Inventors:
Koji ABE, Shoji SHIKITA, Junichi CHIKA, Kei SHIMAMOTO, Yosuke SATO
Abstract: Provided is a multilayer tube that has a layer containing an aliphatic polyamide (such as Polyamide 11 or Polyamide 12), a layer containing a Polyamide 6 composition or Polyamide 6/66/12 composition, a layer containing a saponified ethylene-vinyl acetate copolymer, and a layer containing a semi-aromatic polyamide composition that contains a semi-aromatic polyamide having a specific structure, and further has a fluorine-containing polymer in which a functional group having reactivity with an amino group is introduced into the molecular chain thereof.
Type:
Application
Filed:
September 11, 2015
Publication date:
September 14, 2017
Applicant:
UBE INDUSTRIES, LTD.
Inventors:
Koji NAKAMURA, Takeru ABE, Hiroaki FUJII
Abstract: There is provided a fluorescent material having a composition represented by the following Formula (1). (Sra,Bab,Eux,M11,M2e)SiOf·cMgO . . . Formula (1) (In the formula, M1 is at least one tertiary group element selected from Y and Tb; M2 is an alkali metal selected from Li, Na, and K; and 0<a<2, 0<b<2, 0?c<1, 0.001?d?0.06, 0?e?0.06, 0<x<0.1, and 3.7?f?4.1 are set.) Further, there is provided a light-emitting device including: the fluorescent material; and a light source irradiating the fluorescent material with excitation light to cause the fluorescent material to emit light.
Abstract: The present invention relates to a polyimide precursor comprising a repeating unit represented by the following chemical formula (1): wherein A is a tetravalent group having at least one aliphatic six membered ring and no aromatic ring in the chemical structure, and B is a divalent group having at least one amide bond and an aromatic ring in the chemical structure; or A is an aliphatic tetravalent group and B is a divalent group having at least one chemical structure represented by the following chemical formula (2) in the chemical structure: and X1 and X2 are each independently hydrogen, a C1-6 alkyl group or a C3-9 alkylsilyl group.
Abstract: An oxynitride phosphor powder contains ?-SiAlON and aluminum nitride, obtained by mixing a silicon source, an aluminum source, a calcium source, and a europium source to produce a composition represented by a compositional formula: Cax1Eux2Si12?(y+z)Al(y+z)OzN16?z (wherein x1, x2, y and z are 0<x1?3.40, 0.05?x2?0.20, 4.0?y?7.0, and 0?z?1), and firing the mixture.
Abstract: Provided are a nonaqueous electrolytic solution having an electrolyte salt dissolved in a nonaqueous solvent, the nonaqueous electrolytic solution containing 0.01 to 4% by mass of a compound represented by the following general formula (I), and an energy storage device including the nonaqueous electrolytic solution: wherein R1 and R2 each independently represent a methyl group, an ethyl group, or a fluoroethyl group. The nonaqueous electrolytic solution and the energy storage device have improved high-temperature storage property and low-temperature cycle property.
Abstract: A non-aqueous electrolytic solution comprising a non-aqueous solvent and an electrolyte, which further contains a combination of a nitrile compound and an S?O group-containing compound (or a dinitrile compound) in an amount of 0.001 to 10 wt. % imparts improved cycle performance and storage property to a lithium battery, particularly a lithium secondary battery.
Type:
Grant
Filed:
December 22, 2016
Date of Patent:
August 22, 2017
Assignee:
UBE INDUSTRIES, LTD.
Inventors:
Koji Abe, Takashi Hattori, Yasuo Matsumori
Abstract: Provided are a nonaqueous electrolytic solution having an electrolyte salt dissolved in a nonaqueous solvent, the electrolyte salt including at least one first lithium salt selected from LiPF6, LiBF4, LiN(SO2F)2, LiN(SO2CF3)2, and LiN(SO2C2F5)2, and at least one second lithium salt selected from a lithium salt having an oxalate structure, a lithium salt having a phosphate structure, and a lithium salt having an S?O group, with a sum total of the first lithium salt and the second lithium salt being four or more, and an energy storage device using the same. This nonaqueous electrolytic solution is not only able to improve electrochemical characteristics at a high temperature and much more improve a discharge capacity retention rate and low-temperature output characteristics after a high-temperature storage test but also able to improve low-temperature input characteristics even for high-density electrodes.
Abstract: A process for producing nitrogen-rich air by feeding high temperature air at 150° C. or more to an air separation membrane module is described. After being placed at 175° C. for two hours, the air separation module exhibits a shape-retention ratio of 95% or more in one embodiment. The nitrogen-rich air can be fed to a fuel tank for an aircraft, for example.
Abstract: A nonaqueous electrolytic solution where an electrolyte salt is dissolved to a nonaqueous solvent, wherein the electrolyte salt includes at least one kind of first lithium salt selected from a group consisting of LiPF6, LiBF4, LiN(SO2F)2, LiN(SO2CF3)2, and LiN(SO2C2F5)2, at least two kinds of second lithium salts selected from a group consisting of a lithium salt having an oxalic acid structure, a lithium salt having a phosphoric acid structure, and a lithium salt including a S?O group, and at least one kind of tertiary carboxylic acid ester represented by the following general formula (I) is contained, and an energy storage device containing the same. (In the formula, each of R1 to R3 independently represents a methyl group or ethyl group, and R4 represents a C1 to C6 alkyl group in which at least one hydrogen atom is substituted or not substituted by a halogen atom.
Abstract: A method of manufacturing a wavelength conversion member including a polycrystalline ceramics includes mixing a substance serving as a silicon source, a substance serving as an aluminum source, a substance serving as a calcium source, and a substance serving as a europium source; firing the obtained mixture to obtain an oxynitride phosphor powder; then sintering the oxynitride phosphor powder in an inert atmosphere to obtain the polycrystalline ceramics, characterized in that the sintered oxynitride phosphor powder has a composition (excluding oxygen) represented by the Formula: Cax1Eux2Si12-(y+z)Al(y+z)OzN16-z (in the Formula, x1, x2, y, and z are values such that 0<x1?3.40, 0.05?x2?0.20, 3.5?y?7.0, 0?z?1).
Abstract: The present invention relates to a polyamide resin comprising a unit derived from ?-caprolactam and/or ?-aminocaproic acid (to also be referred to as “Unit 1”), a unit derived from adipic acid (to also be referred to as “Unit 2”) and a unit derived from hexamethylenediamine (to also be referred to as “Unit 3”), wherein the concentration of terminal amino groups in the polyamide resin is greater than the concentration of terminal carboxyl groups in the polyamide resin, and the amount of Unit 1 is greater than 60% by weight to less than 80% by weight of the total amount of Unit 1, Unit 2 and Unit 3.
Abstract: Provided is a salt including a compound represented by a formula (4) and a compound represented by a formula (5). A method for producing the salt includes reacting a compound represented by a formula (2) with a compound represented by a formula (3) in the presence of a quaternary onium salt and a base to form the compound represented by the formula (4); and mixing the compound represented by the formula (4) with the compound represented by the formula (5). A method for producing a compound represented by a formula (6) includes removing, from the salt including the compounds of formulae (4) and (5), a protecting group P1. In the following formulae, P1 and P2 are both protecting groups.
Abstract: Provided is a method for producing an inorganic fiber-bonded ceramic material, which can produce, at a high yield, an inorganic fiber-bonded ceramic material with fewer defects, and with an end part and a central part equivalent to each other in microstructure and mechanical properties, and also makes it possible to increase the ceramic material in size. The method for producing an inorganic fiber-bonded ceramic material is characterized in that it includes: a first pressing step of setting, in a carbon die, a laminate to be surrounded by a ceramic powder, the laminate obtained by stacking a coated inorganic fiber shaped product including an inorganic fiber part of inorganic fibers that have a pyrolysis initiation temperature of 1900° C. or lower, and a surface layer of an inorganic substance for bonding the inorganic fibers to each other, and pressing the laminate at a temperature of 1000 to 1800° C.