Abstract: Provided are a self-crosslinking polyhydroxy polyurethane resin derived from a reaction of a 5-membered cyclic carbonate compound and an amine compound and having masked isocyanate groups in its structure; a process for producing the resin; an imitation leather composed of a base fabric and a resin composition composed of the resin as its principal component and impregnated in or laminated on the base fabric; as kin material made of a thermoplastic polyolefin resin, said skin material including a thermoplastic polyolefin resin sheet and a top coat layer formed directly or via a primer layer on the sheet, wherein the top coat layer has been formed with a resin composition composed of the resin as its principal component; and a weather strip material composed, as its principal components, of the resin and a specific diorganopolysiloxane and/or a silicone oil.
Type:
Grant
Filed:
June 21, 2011
Date of Patent:
September 4, 2018
Assignees:
DAINICHISEIKA COLOR & CHEMICALS MFG. CO., LTD., UKIMA CHEMICALS & COLOR MFG. CO., LTD.
Abstract: The present invention is a method for eliminating radioactive iodine using a hydrophilic resin that adsorbs radioactive iodine, wherein the hydrophilic resin is at least one selected from the group consisting of a hydrophilic polyurethane resin, a hydrophilic polyurea resin, and a hydrophilic polyurethane-polyurea resin and has a hydrophilic segment and, in the principal chain and/or a side chain in the structure thereof, has a tertiary amino group or has a tertiary amino group and polysiloxane segment. By means of the present invention, a novel method for eliminating radioactive iodine is provided that is simple and low-cost, furthermore does not require an energy source such as electricity, moreover can take in and stably immobilize the eliminated radioactive iodine within a solid, and is capable of reducing the volume of radioactive waste as necessary.
Type:
Grant
Filed:
March 12, 2014
Date of Patent:
June 26, 2018
Assignees:
Dainichiseika Color & Chemicals Mfg. Co. Ltd., Ukima Chemicals & Color Mfg. Co., Ltd.
Abstract: Provided are a self-crosslinking polysiloxane-modified polyhydroxy polyurethane resin derived from a reaction of a 5-membered cyclic carbonate polysiloxane compound represented by the following formula (1) and an amine compound and having polysiloxane segments and masked isocyanate groups in its structure: wherein A means and its production process. The present invention can provide a polyhydroxy polyurethane resin, the development of applications of which has not moved ahead in the prior art, as a novel self-crosslinking polyhydroxy polyurethane resin that enables to provide products excellent in lubricity, abrasion resistance, chemical resistance, non-tackiness, heat resistance and the like, is useful from the viewpoint of the reduction of warming gas, and is responsive to the environment.
Type:
Grant
Filed:
August 11, 2011
Date of Patent:
June 19, 2018
Assignees:
DAINICHISEIKA COLOR & CHEMICALS MFG. CO., LTD., UKIMA CHEMICALS & COLOR MFG. CO., LTD.
Abstract: The present invention is a method for eliminating radioactive iodine using a hydrophilic resin that adsorbs radioactive iodine, wherein the hydrophilic resin is at least one selected from the group consisting of a hydrophilic polyurethane resin, a hydrophilic polyurea resin, and a hydrophilic polyurethane-polyurea resin and has a hydrophilic segment and, in the principal chain and/or a side chain in the structure thereof, has a tertiary amino group or has a tertiary amino group and polysiloxane segment. By means of the present invention, a novel method for eliminating radioactive iodine is provided that is simple and low-cost, furthermore does not require an energy source such as electricity, moreover can take in and stably immobilize the eliminated radioactive iodine within a solid, and is capable of reducing the volume of radioactive waste as necessary.
Type:
Application
Filed:
March 12, 2014
Publication date:
May 31, 2018
Applicants:
Ukima Chemicals & Color Mfg. Co., Ltd., Dainichiseika Color & Chemicals Mfg.Co., Ltd.
Abstract: Provided are a coating composition for forming a gas barrier layer as configured such that a specific compound having two or more 5-membered cyclic carbonate groups and a compound having two or more amino groups are reactable at an equivalent ratio of functional groups of 0.8 to 1.25 to form the gas barrier layer with a polyhydroxyurethane resin as a principal component; a gas barrier film formed of a single layer or multiple layers, at least one of the layer or layers that forms or form the film is a layer that exhibits gas barrier properties, and the layer is formed of a polyhydroxyurethane resin having a specific chemical structure; and a production method of a film having gas barrier properties.
Type:
Grant
Filed:
February 22, 2012
Date of Patent:
January 10, 2017
Assignees:
DAINICHISEIKA COLOR & CHEMICALS MFG. CO., LTD., UKIMA CHEMICALS & COLOR MFG. CO. LTD.
Abstract: A method for removing radioactive cesium and/or iodine from a radioactive substance in liquid and/or a solid matter using a hydrophilic resin composition comprising a hydrophilic resin and a metal ferrocyanide compound, wherein the hydrophilic resin includes at least one hydrophilic resin selected from the group consisting of a hydrophilic polyurethane resin, a hydrophilic polyurea resin, and a hydrophilic polyurethane-polyurea resin each having at least a hydrophilic segment, and a metal ferrocyanide compound is dispersed in the hydrophilic resin composition in a ratio of at least 1 to 200 mass parts relative to 100 mass parts of the hydrophilic resin.
Type:
Grant
Filed:
April 30, 2014
Date of Patent:
January 3, 2017
Assignees:
Dainichiseika Color & Chemicals Mfg. Co., Ltd., Ukima Chemicals & Color Mfg. Co., Ltd.
Abstract: The present invention intends to provide a method for removing radioactive cesium, or radioactive iodine and radioactive cesium that is simple and low-cost, further does not require an energy source such as electricity, moreover can take in and stably immobilize the removed radioactive substances within a solid, and can reduce the volume of radioactive waste as necessary, and to provide a hydrophilic resin composition using for the method for removing radioactive cesium, or radioactive iodine and radioactive cesium, and the object of the present invention is achieved by using a hydrophilic resin composition containing: at least one hydrophilic resin selected from the group consisting of a hydrophilic polyurethane resin, a hydrophilic polyurea resin, and a hydrophilic polyurethane-polyurea resin each having at least a hydrophilic segment; and a clay mineral dispersed therein in a ratio of at least 1 to 180 mass parts relative to 100 mass parts of the hydrophilic resin.
Type:
Grant
Filed:
July 10, 2015
Date of Patent:
August 9, 2016
Assignees:
Dainichiseika Color & Chemicals Mfg. Co., Ltd., Ukima Chemicals & Color Mfg. Co., Ltd.
Abstract: Disclosed are a polysiloxane-modified polyhydroxy polyurethane resin characterized by being derived from a reaction between a 5-membered cyclic carbonate polysiloxane compound represented by the below-described formula (1) and an amine compound, and its production process; and a resin composition, thermal recording medium, imitation leather, thermoplastic polyolefin resin skin material, weather strip material, and weather strip, all of which make use of the resin.
Type:
Grant
Filed:
August 25, 2014
Date of Patent:
July 19, 2016
Assignees:
DAINICHISEIKA COLOR & CHEMICALS MFG. CO., LTD, UKIMA CHEMICALS & COLOR MFG. CO., LTD.
Abstract: A problem is to provide, in the field of polyhydroxy polyurethane resins the development of applications of which has not moved ahead by conventional technologies, a self-crosslinking polyhydroxy polyurethane resin, which enables to provide products, such as imitation leathers, excellent in abrasion resistance, chemical resistance, heat resistance and the like, and moreover, which is useful from the viewpoint of a reduction in greenhouse gas, contains carbon dioxide incorporated and fixed therein, and is responsive to environmental conservation.
Type:
Grant
Filed:
April 2, 2012
Date of Patent:
June 7, 2016
Assignees:
DAINICHISEIKA COLOR & CHEMICALS MFG. CO., LTD., UKIMA CHEMICALS & COLOR MFG. CO., LTD.
Abstract: A 5-membered cyclic carbonate polysiloxane compound is represented by the below-described formula (1), and is produced by a process that reacts an epoxy-modified polysiloxane compound with carbon dioxide. wherein A means in which R1 means an alkylene group which has from 1 to 12 carbon atoms and may be linked via an element of O, S or N and/or —(C2H4O)b—, R2 means a direct bond or an alkylene group having from 2 to 20 carbon atoms, R2 may be linked to an alicyclic group or aromatic group, b stands for a number of from 1 to 300, and a stands for a number of from 1 to 300.
Type:
Grant
Filed:
October 7, 2010
Date of Patent:
March 10, 2015
Assignees:
Dainichiseika Color & Chemicals Mfg. Co., Ltd., Ukima Chemicals & Color Mfg. Co., Ltd.
Abstract: The present invention intends to provide a method for removing radioactive cesium, or radioactive iodine and radioactive cesium that is simple and low-cost, further does not require an energy source such as electricity, moreover can take in and stably immobilize the removed radioactive substances within a solid, and can reduce the volume of radioactive waste as necessary, and to provide a hydrophilic resin composition using for the method for removing radioactive cesium, or radioactive iodine and radioactive cesium, and the object of the present invention is achieved by using a hydrophilic resin composition containing: at least one hydrophilic resin selected from the group consisting of a hydrophilic polyurethane resin, a hydrophilic polyurea resin, and a hydrophilic polyurethane-polyurea resin each having at least a hydrophilic segment; and a zeolite dispersed therein in a ratio of at least 1 to 200 mass parts relative to 100 mass parts of the hydrophilic resin.
Type:
Grant
Filed:
June 10, 2014
Date of Patent:
February 24, 2015
Assignees:
Dainichiseika Color & Chemicals Mfg. Co., Ltd., Ukima Chemicals & Color Mfg. Co., Ltd.
Abstract: Disclosed are a polysiloxane-modified polyhydroxy polyurethane resin characterized by being derived from a reaction between a 5-membered cyclic carbonate polysiloxane compound represented by the below-described formula (1) and an amine compound, and its production process; and a resin composition, thermal recording medium, imitation leather, thermoplastic polyolefin resin skin material, weather strip material, and weather strip, all of which make use of the resin.
Type:
Grant
Filed:
November 25, 2010
Date of Patent:
February 10, 2015
Assignees:
Dainichiseika Color & Chemicals Mfg. Co., Ltd., Ukima Chemicals & Color Mfg. Co., Ltd.
Abstract: A method for removing radioactive cesium and/or iodine from a radioactive substance in liquid and/or a solid matter using a hydrophilic resin composition comprising a hydrophilic resin and a metal ferrocyanide compound, wherein the hydrophilic resin includes at least one hydrophilic resin selected from the group consisting of a hydrophilic polyurethane resin, a hydrophilic polyurea resin, and a hydrophilic polyurethane-polyurea resin each having at least a hydrophilic segment, and a metal ferrocyanide compound is dispersed in the hydrophilic resin composition in a ratio of at least 1 to 200 mass parts relative to 100 mass parts of the hydrophilic resin.
Type:
Application
Filed:
April 30, 2014
Publication date:
August 21, 2014
Applicants:
Dainichiseika Color & Chemicals Mfg. Co., Ltd., Ukima Chemicals & Color Mfg. Co., Ltd.
Abstract: Disclosed are a polysiloxane-modified polyhydroxy polyurethane resin derived from a reaction between a 5-membered cyclic carbonate compound and an amine-modified polysiloxane compound, and its production process; and a resin composition, thermal recording medium, imitation leather, thermoplastic polyolefin resin skin material, weather strip material, and weather strip, all of which make use of the resin.
Type:
Grant
Filed:
November 25, 2010
Date of Patent:
April 22, 2014
Assignees:
Dainichiseika Color & Chemicals Mfg. Co., Ltd., Ukima Chemicals & Color Mfg. Co., Ltd.
Abstract: A problem is to provide polyhydroxyurethane microparticles, which have a narrow particle size distribution and are applicable to a wide range of use. Provided are polyhydroxyurethane microparticles which are spherical polymer microparticles having particle sizes of 0.1 ?m to 300 ?m. A polymer that makes up the polymer microparticles has in a structure thereof chemical structure units represented by the following formula (1) and/or chemical structure units represented by the following formula (2). In the chemical structure units (1) and (2), —O—CO— bonds have been derived from carbon dioxide.
Type:
Application
Filed:
April 24, 2012
Publication date:
January 30, 2014
Applicants:
UKIMA CHEMICALS & COLOR MFG. CO., LTD., DAINICHISEIKA COLOR & CHEMICALS MFG. CO., LTD.
Abstract: A problem is to provide, in the field of polyhydroxy polyurethane resins the development of applications of which has not moved ahead by conventional technologies, a self-crosslinking polyhydroxy polyurethane resin, which enables to provide products, such as imitation leathers, excellent in abrasion resistance, chemical resistance, heat resistance and the like, and moreover, which is useful from the view point of a reduction in greenhouse gas, contains carbon dioxide incorporated and fixed therein, and is responsive to environmental conservation.
Type:
Application
Filed:
April 2, 2012
Publication date:
January 23, 2014
Applicants:
UKIMA CHEMICALS & COLOR MFG. CO., LTD., DAINICHISEIKA COLOR & CHEMICALS MFG. CO., LTD.
Abstract: Provided are a coating composition for forming a gas barrier layer as configured such that a specific compound having two or more 5-membered cyclic carbonate groups and a compound having two or more amino groups are reactable at an equivalent ratio of functional groups of 0.8 to 1.25 to form the gas barrier layer with a polyhydroxyurethane resin as a principal component; a gas barrier film formed of a single layer or multiple layers, at least one of the layer or layers that forms or form the film is a layer that exhibits gas barrier properties, and the layer is formed of a polyhydroxyurethane resin having a specific chemical structure; and a production method of a film having gas barrier properties.
Type:
Application
Filed:
February 22, 2012
Publication date:
December 5, 2013
Applicants:
UKIMA CHEMICALS & COLOR MFG. CO., LTD., DAINICHISEIKA COLOR & CHEMICALS MFG. CO., LTD.
Abstract: Provided are a self-crosslinking polysiloxane-modified polyhydroxy polyurethane resin derived from a reaction of a 5-membered cyclic carbonate polysiloxane compound represented by the following formula (1) and an amine compound and having polysiloxane segments and masked isocyanate groups in its structure: wherein A means and its production process. The present invention can provide a polyhydroxy polyurethane resin, the development of applications of which has not moved ahead in the prior art, as a novel self-crosslinking polyhydroxy polyurethane resin that enables to provide products excellent in lubricity, abrasion resistance, chemical resistance, non-tackiness, heat resistance and the like, is useful from the viewpoint of the reduction of warming gas, and is responsive to the environment.
Type:
Application
Filed:
August 11, 2011
Publication date:
July 4, 2013
Applicants:
UKIMA CHEMICALS & COLOR MFG. CO., LTD., DAINICHISEIKA COLOR & CHEMICALS MFG. CO., LTD.
Abstract: Provided are a self-crosslinking polyhydroxy polyurethane resin derived from a reaction of a 5-membered cyclic carbonate compound and an amine compound and having masked isocyanate groups in its structure; a process for producing the resin; an imitation leather composed of a base fabric and a resin composition composed of the resin as its principal component and impregnated in or laminated on the base fabric; as kin material made of a thermoplastic polyolefin resin, said skin material including a thermoplastic polyolefin resin sheet and a top coat layer formed directly or via a primer layer on the sheet, wherein the top coat layer has been formed with a resin composition composed of the resin as its principal component; and a weather strip material composed, as its principal components, of the resin and a specific diorganopolysiloxane and/or a silicone oil.
Type:
Application
Filed:
June 21, 2011
Publication date:
April 18, 2013
Applicants:
UKIMA CHEMICALS & COLOR MFG. CO., LTD, DAINICHISEIKA COLOR & CHEMICALS MFG. CO. LTD.
Abstract: Disclosed are a polysiloxane-modified polyhydroxy polyurethane resin derived from a reaction between a 5-membered cyclic carbonate compound and an amine-modified polysiloxane compound, and its production process; and a resin composition, thermal recording medium, imitation leather, thermoplastic polyolefin resin skin material, weather strip material, and weather strip, all of which make use of the resin.
Type:
Application
Filed:
November 25, 2010
Publication date:
September 20, 2012
Applicants:
UKIMA CHEMICALS & COLOR MFG. CO., LTD., DAINICHISEIKA COLOR & CHEMICALS MFG. CO., LTD.