Patents Assigned to UNIBRA
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Patent number: 4419482Abstract: The invention relates to a process for preparing products containing polymer chains in which a linear prepolymer or polymer contains at least one free acid group at each chain and is reacted with an alkoxide of a metal having a valence of more than 2, such as zirconium, titanium or cerium, possibly in the presence of a non polar solvent, the alkoxide of the metal having a valence of more than 2 being used in such a quantity that the alkoxide functions are in excess with respect to the stoichiometric amount of the acid functions carried by said linear prepolymer or polymer, the reaction mixture being stirred in the presence of humidity until a product is obtained wherein the hydrogen atoms of the free acid end groups of the prepolymer or polymer are substituted by an atom of the metal (M) which is itself linked to another atom of said metal by M-O-M linkages. The invention relates also to the products containing a prepolymer or polymer .alpha.,.omega.Type: GrantFiled: February 2, 1982Date of Patent: December 6, 1983Assignee: Unibra Societe AnonymeInventors: Philippe J. Teyssie, Robert J. Jerome, Guy J. Broze
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Patent number: 4362837Abstract: Viscous, homogeneous and thermoreversible gels containing polymer chains are obtained by a process in which a solution of a prepolymer or polymer which contains at least one free acid group at each chain end in a non polar solvent selected among the aliphatic, alicyclic and aromatic hydrocarbons having a dielectric constant of less than about 3 is reacted at room temperature with a stoechiometric amount, based on the acid group content of the polymer, of a metal aliphatic alkoxide so as to neutralize all the free acid groups and a sufficient amount of the non polar solvent is distilled for removing, in a substantially quantitative manner, the aliphatic alcohol formed by said reaction.Type: GrantFiled: March 23, 1981Date of Patent: December 7, 1982Assignee: Unibra Societe AnonymeInventors: Philippe T. Teyssie, Robert J. Jerome, Guy J. Broze
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Patent number: 4233175Abstract: A reagent for treating flue gases constituted by an intimate mixture, in the solid state, of a main component selected from the group comprising alkaline-earth, oxides, hydroxides, carbonates, bicarbonates, and mixtures thereof, and an additive selected from the group comprising hydrogen halide acids, salts of such acids of alkaline metals, ammonium, and alkaline-earth metals, sulphuric acid, and mixtures thereof, said additive being present in an amount of from 0.1 to 15% by mole respect to said main component.Type: GrantFiled: September 1, 1978Date of Patent: November 11, 1980Assignee: UnibraInventors: Bernard Delmon, Ghislain Van Houte
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Patent number: 4203917Abstract: This invention relates to a new catalytic process for preparing nitriles such as acetonitrile, propionitrile or benzonitrile, from amides, such as acetamide or alkylacetamides, propionamide or alkylpropionamides, formanilide or alkylformanilides.According to this invention, the amide is reacted in gaseous phase in a reactor on a solid catalyst of the ammoxidation type, such as bismuth phosphomolybdate, at a temperature comprised between about 400.degree. and 650.degree. C.Type: GrantFiled: March 7, 1978Date of Patent: May 20, 1980Assignee: Unibra Societe AnonymeInventors: Bernard M. Delmon, Michel C. Portenart, Heinz Viehe
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Patent number: 4159994Abstract: The invention concerns a new method for obtaining intercalation complexes of kaolin materials having organic compounds or radicals in their chemical structure.The invention also concerns new intercalation complexes of kaolin materials and their use.Type: GrantFiled: February 2, 1978Date of Patent: July 3, 1979Assignee: Unibra Societe AnonymeInventors: Herbert Seto, Maria I. Cruz, Jose J. Fripiat
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Patent number: 4145301Abstract: This invention relates to a process for the preparation of magnetic oxides and possibly of at least one other metal. It relates also to new products consisting in mono- and polymetal magnetic oxides.According to the invention a glycerin complex of iron and possibly at least one other metal is first prepared and the complex is decomposed into a mono- or polymetal magnetic oxide by hydrolysis or pyrolysis, the possibly decomposed glycerin complex being subjected to a thermal treatment, such as annealing or pyrolysis in an atmosphere of an inert gas, such as nitrogen.The invention relates to magnetic oxides containing 0.2 to 3% by weight of carbon, said oxides preferably containing cobalt and possibly a rare earth element such as yttrium or europium.Type: GrantFiled: November 1, 1976Date of Patent: March 20, 1979Assignee: Unibra Societe AnonymeInventors: Philippe M. Bruylants, Jose J. Fripiat, Luc W. Rodrigue, Georges M. Poncelet, Antonin A. Munaut
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Patent number: 4115518Abstract: A desulphurization reagent comprising an intimate mixture, in the solid state, of a main component selected from the group consisting of alkaline-earth, oxides, hydroxides, carbonates, bicarbonates, and mixtures, thereof, and an additive selected from the group consisting of hydrogen halide acids, salts of such acids of alkaline metals, ammonium, and alkaline-earth metals, sulphuric acid, and mixtures thereof, said additive being present in an amount of from 0.1 to 15% by mole respect to said main component.Type: GrantFiled: November 4, 1975Date of Patent: September 19, 1978Assignee: UnibraInventors: Bernard Delmon, Ghislain Van Houte
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Patent number: 4082715Abstract: A moulding composition which comprises a polycarbonate polymer, a plasticizer for said polymer, and a finely divided nucleating agent selected from the group consisting of metal salts of polymers carrying lateral carboxylic groups.Type: GrantFiled: November 13, 1975Date of Patent: April 4, 1978Assignee: Unibra S.A.Inventor: Jean-Pierre Mercier
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Patent number: 4001362Abstract: The object of the invention is to provide a method for the treatment of all kinds of clay or any ceramic composition based on clay.The method consists in distributing in the clay metal ions capable of forming the corresponding oxide at a temperature at the most equal to the firing temperature of the clay thus treated, by maintaining the clay in contact with a liquid phase under conditions such that said ions pass at least in part into the liquid phase and a diffusion of said ions throughout the mass of clay is ensured.Type: GrantFiled: September 18, 1974Date of Patent: January 4, 1977Assignee: UNIBRAInventors: Bernard Delmon, Jacques LeMaitre, Michel Bulens
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Patent number: 3965064Abstract: The invention concerns a process for crystallizing a polycarbonate polymer which consists in incorporating to said polycarbonate polymer a finely divided nucleating agent and/or a plasticizer for said polycarbonate polymer, and crystallizing the mixture thus obtained at a temperature higher than the vitreous transition temperature.The semi-crystalline polymer material obtained can be reinforced by adding inorganic fibers.Type: GrantFiled: October 29, 1974Date of Patent: June 22, 1976Assignee: Unibra S.A.Inventors: Jean Mercier, Francis Gallez, Roger Legras