Abstract: A redox flow battery includes an anolyte storage tank having a height configured for containing a quantity of an anolyte; a catholyte storage tank having a height configured for containing a quantity of a catholyte; an electrochemical cell configured for fluid communication with the anolyte and catholyte storage tanks; and a tub defining a cavity formed in at least one of the anolyte and catholyte storage tanks to provide a sealed fluid connection point below the height of the at least one storage tank.
Abstract: Methods of determining concentrations and/or amounts of redox-active elements at each valence state in an electrolyte solution of a redox flow battery are provided. Once determined, the concentrations and/or amounts of the redox-active elements at each valence state can be used to determine side-reactions, make chemical adjustments, periodically monitor battery capacity, adjust performance, or to otherwise determine a baseline concentration of the redox-active ions for any purpose.
Abstract: Disclosed herein are improved electrochemical cell stacks having at least one protective channel on an end of the stack. Redox flow batteries (RFBs) containing the “protected” electrochemical cell stacks, and methods of operating such RFBs, are also provided.
Abstract: Systems and methods for shunt current and mechanical loss mitigation in electrochemical systems include a conduit providing at least a portion of an electrically conductive pathway between the first and second electrochemical cells, wherein the conduit includes at least one shunt current suppression device configured as a loop, and/or a connector assembly for maintaining first and second connecting portions in adjacent positioning.
Abstract: Systems and methods for shunt current and mechanical loss mitigation in electrochemical systems include a conduit providing at least a portion of an electrically conductive pathway between the first and second electrochemical cells, wherein the conduit includes at least one shunt current suppression device configured as a loop, and/or a connector assembly for maintaining first and second connecting portions in adjacent positioning.
Abstract: A barrier on the surface of the negative electrolyte solution of a redox flow battery can decrease air oxidation of a charged species in the negative electrolyte solution and can decrease water loss from the negative electrolyte solution. A negative electrolyte tank including a barrier on the surface of the negative electrolyte can have many advantages, including simplified setup, low cost, and low maintenance.
Abstract: Disclosed herein are improved electrochemical cell stacks having at least one protective channel on an end of the stack. Redox flow batteries (RFBs) containing the “protected” electrochemical cell stacks, and methods of operating such RFBs, are also provided.