Abstract: Compositions comprising: A. Ethylene-based polymer, e.g., LDPE; B. Polyalkylene glycol, e.g., PEG; C. Tertiary hindered amine stabilizer; D. Sulphur-containing hindered phenol antioxidant; E. Peroxide; and F. Optional coagent are useful in the preparation of TRXLPE insulation for medium voltage cable that exhibits a commercially desirable balance of long term heat aging retardancy and water-tree resistance.

Abstract: A cellulose ether having (i) one or more substituents selected from the group consisting of methyl, hydroxyethyl and hydroxypropyl, (ii) one or more hydrophobic substituents, and (iii) one or more cationic, tertiary amino, or anionic substituents, and having a retained dynamic viscosity, % ?80/25, of at least 30 percent, wherein % ?80/25=[dynamic solution viscosity at 80° C./dynamic solution viscosity at 25° C.]×100, the dynamic solution viscosity at 25° C. and 80° being measured as 1% aqueous solution, is useful for modifying the viscosity of a composition selected from the group consisting of wellbore servicing fluids, cementitious formulations, ceramics, metal working fluids and cutting fluids.

Abstract: Novel nonionic cellulose ethers exhibit a reduced degree of thermal thinning and are efficient thickeners at elevated temperatures. The nonionic cellulose ether has hydroxyethyl groups and is further substituted with one or more hydrophobic substituents. The cellulose ether further has at least one of the properties a), b) or c): a) a retained dynamic viscosity, %?80/25, of at least 30 percent, wherein % ?180/25=[dynamic solution viscosity at 80° C./dynamic solution viscosity at 25° C.? 100, the dynamic solution viscosity at 25° C. and 80° C. being measured as 1% aqueous solution; b) a storage modulus of at least 15 Pascals at 25° C. and a retained storage modulus, % G?80/25, of at least 12 percent, wherein %G?80/25=[storage modulus at 80° C./storage modulus at 25° C.] 100, the storage modulus at 25° C. and 80° C. being measured as a 1% aqueous solution; c) a critical association concentration of less than 15 ppm as measured by light-scattering.

Abstract: Silicone-thermoplastic polymer reactive blends and copolymer products are prepared using economical post-reactor reactive mixing, e.g., extrusion. The procedure is based on the ring-opening polymerization of cyclic siloxanes within a thermoplastic polymer matrix. In a preferred mode, the thermoplastic polymer is a polyolefin, optionally containing silane groups that are available for reaction with the silicone polymer that is formed in situ. The resulting materials provide hybrid performance that can extend the range of applications beyond those which are served by thermoplastic polymers or silicones alone, or their physical blends.

Abstract: The present invention reacts ethylenediamine with one or more additional ethyleneamines in the presence of a transamination catalyst to provide a different, preferably more desirable product mix of one or more ethyleneamines.

Abstract: The present invention provides catalyst compositions useful for transamination reactions. The catalyst compositions have a catalyst support that includes transitional alumina, use a low metal loading (for example, less than 25 wt. %), and do not require the presence of rhenium. The catalyst compositions are able to advantageously promote transamination of a reactant product (such as the transamination of EDA to DETA) with excellent activity and selectivity, and similar to transaminations promoted using a precious metal-containing catalyst.

Abstract: The present invention provides catalyst compositions useful for transamination reactions. The catalyst compositions have a catalyst support that includes transitional alumina, use a low metal loading (for example, less than 25 wt. %), and do not require the presence of rhenium. The catalyst compositions are able to advantageously promote transamination of a reactant product (such as the transamination of EDA to DETA) with excellent activity and selectivity, and similar to transaminations promoted using a precious metal-containing catalyst.

Abstract: The present invention provides strategies for making cyclic triamines. Reactant media including certain precursors and/or certain types of catalysts can be converted into cyclic triamines with improved conversion and selectivity. The strategies can be incorporated into reactions that involve transamination schemes and/or reductive amination schemes. In the case of transamination, for instance, using transamination to cause ring closure of higher amines in the presence of a suitable catalyst leads to desired cyclic triamines with notable conversion and yield. In the case of reductive amination, reacting suitable polyfunctional precursors in the presence of a suitable catalyst also yields cyclic triamines via ring closure with notable selectivity and conversion. Both transamination and reductive amination methodologies can be practiced under much milder temperatures than are used when solely acid catalysts are used. Preferred embodiments can produce reaction mixtures that are generally free of salt by-products.

Abstract: Use of a bimodal filler system allows masterbatches with higher filler levels to be processable. When used with moisture curable resins, the use of a masterbatch having a bimodal filler allows the preparation of a composition having a higher percentage of moisture curable resin than if a unimodal filler was used and also provides enhanced flame retardant properties.

Abstract: Provided is a procatalyst composition containing a multiple internal electron donor with at least two components, one of which is a silyl ester. The other component of the mixed internal electron donor may be an electron donor component. The electron donor component may be an aromatic acid ester, a di-ether, and combinations thereof. Catalyst compositions containing the multiple internal electron donor exhibit improved hydrogen response during olefin polymerization and produce propylene-based polymers with broad molecular weight distribution, high flexural modulus, and high melt flow rate.

Abstract: A Ziegler-Natta procatalyst composition in the form of solid particles and comprising magnesium, halide and transition metal moieties, said particles having an average size (D50) of from 10 to 70 ?m, characterized in that at least 5 percent of the particles have internal void volume substantially or fully enclosed by a monolithic surface layer (shell), said layer being characterized by an average shell thickness/particle size ratio (Thickness Ratio) determined by SEM techniques for particles having particle size greater than 30 ?m of greater than 0.2.

Abstract: An injection molding process for making a plastic article, the process comprising the steps of: A. Forming a moisture-curable composition comprising a 1. Silane-functionalized polyethylene, 2. Moisture source, e.g., a moisture-containing filler, wherein the moisture source excludes alcohols, and 3. Condensation catalyst; B. Injecting the composition into a mold; C. Subjecting the composition to conditions sufficient to 1. Release moisture from the moisture source, and 2. Partially cure the composition; D. Removing the partially cured composition from the mold; and E. Continuing the cure of the composition outside of the mold. The process is particularly well suited for the manufacture of thick parts, such as wire and cable elastomeric connectors.

Abstract: The present invention is a moisture crosslinkable composition. It may be (i) a blend of a nonpolar polyolefin and a second highly polar or amorphous polyolefin or (ii) a copolymer of a nonpolar polyolefin and the second polar or amorphous polyolefin. The present invention is useful for the preparation of moisture-cured wires, cables, film, pipe, hot melt adhesives, and other extruded or injection molded articles. The present invention is also useful in the preparation of media for fast transport of selective species, including film membranes.

Abstract: The present invention provides methods of manufacturing ethyleneamines that makes use of an ethyleneamine-generating process that is coupled to a transamination process. The combination of an ethyleneamine-generating process with a transamination process improves the mix flexibility that can be obtained from the single process allowing the production of ethyleneamine compositions having an improved and more desirable product mix.

Abstract: A Ziegler-Natta procatalyst composition in the form of solid particles and comprising magnesium, halide and transition metal moieties, said particles having an average size (D50) of from 10 to 70 ?m, characterized in that at least 5 percent of the particles have internal void volume substantially or fully enclosed by a monolithic surface layer (shell), said layer being characterized by an average shell thickness/particle size ratio (Thickness Ratio) determined by SEM techniques for particles having particle size greater than 30 ?m of greater than 0.2.

Abstract: The present invention is a replacement plasticizer system made from or containing an epoxidized fatty acid ester plasticizer as a primary plasticizer and a secondary plasticizer. The replacement placement system is useful with a variety of polymers in applications such as wire-and-cable insulations, wire-and-cable jackets, coatings, adhesives, and castings.

Abstract: A method for making a support impregnated Ziegler-Natta-type catalyst precursor including at least two transition metals and a support material wherein the resulting catalyst precursor is free-flowing is provided. Also provided is a process for producing a Ziegler-Natta type procatalyst by halogenating the free flowing catalyst precursor. The Ziegler-Natta type procatalyst and the reaction product of at least one monomer in the presence of the Ziegler-Natta type procatalyst and cocatalyst are also provided.

Abstract: A method of transalkoxylation of nucleophilic compounds in which an alkoxylated and a nucleophilic compound are combined in a suitable vessel and reacted in the presence of a heterogeneous catalyst under conditions capable of transferring at least one hydroxyalkyl group from the alkoxylated compound to the nucleophilic compound. The method is especially useful in the transalkoxylation of alkanolamines to transfer a hydroxyalkyl group from an alkanolamine having a greater number of hydroxyalkyl groups to an alkanolamine having a lesser number of hydroxyalkyl groups.

Abstract: The present invention relates to post-treatment compositions and methods useful for modifying the distribution of metal biocide(s) in biodegradable substrates such as wood, other cellulosic products, starch-based products, and the like that are vulnerable to decay due to insects, fungi, microbes, and the like. The compositions include complexing agents of moderate strength that are able to facilitate mobilization and redistribution of metal biocide(s) in substrates without undue leaching. The compositions can be used, for example, to redistribute the metal biocide(s) into depleted regions of a substrate by redistribution of metal biocide from other regions of the substrate. Post-treatment compositions that include additional metal biocide can also replenish these regions with the freshly supplied, additional biocide. Thus, the depleted regions can be restored by redistribution and/or replenishment mechanisms. Service life of substrates in the field benefits by these post-treatments as a consequence.

Abstract: The invention is directed to a polymerization system and method of controlling resin properties during the production of bimodal and multimodal polymer compositions using at least one manipulated variable to minimize dynamic deviations from polymer characteristics. In particular embodiments, the method of control includes determining a property of the resin based on a current and/or previous values or estimates or process variables or polymer characteristics. In this manner the control actions serve to reduce process upsets or facilitate in transitioning to a new product or grade to reduce the amount of off-grade resin material produced during transition or during steady state manufacture.