Abstract: Processes and apparatuses for separating chlorides from a butane product stream by removing chlorides from a portion of said feed stream in a rectification section of the separation zone. The rectification section may be in a rectification column which may be combined with a stripper column. Alternatively, a wall may be used to provide the rectification section in a fractionation column. The processes and apparatuses can be used in both new designs and revamped designs.

Abstract: A process for catalytic cracking recovery locates the stripping column to receive the main column receiver liquid. The columns purposed for removing light hydrocarbons from the liquid streams are removed from the high-pressure section thus saving energy.

Abstract: A process for separating a carbon dioxide product stream from a flue gas stream is disclosed. The process comprises passing a stream of carbon dioxide and oxygen to a regenerator to generate a catalyst stream and produce a flue gas stream comprising carbon oxides, and/or nitrogen oxides, catalyst fines, oxygen, and water. Heat is transferred to a water stream from the flue gas stream in a heat recovery unit to form a cooled flue gas stream and a steam stream. Water is removed from the cooled flue gas stream in a dehydration unit to provide a dehydrated flue gas stream. The dehydrated flue gas stream is separated into an oxygen stream and a carbon dioxide product stream.

Abstract: A process and an apparatus are disclosed for separation of a hydrocarbon gas stream containing methane and heavier hydrocarbons and significant quantities of nitrogen and carbon dioxide. The gas stream is cooled and expanded, then fractionated in a first distillation column into a first overhead vapor and a hydrocarbon liquid stream containing the majority of the carbon dioxide. The hydrocarbon liquid stream is fractionated into a hydrocarbon vapor stream and a less volatile fraction comprised of heavier hydrocarbons. The first overhead vapor is cooled, expanded, and separated into vapor and liquid streams. Both streams are cooled and expanded before feeding a second distillation column that produces a second overhead vapor that is predominantly nitrogen and a bottom liquid that is predominantly methane. The bottom liquid is vaporized and combined with the hydrocarbon vapor stream to form a volatile residue gas fraction containing the majority of the methane.

Abstract: A process for oligomerizing and oligomerizing olefins to distillate fuels which regenerates a first stage oligomerization catalyst bed and/or a second oligomerization catalyst bed in situ by contact with an oxygen gas at elevated temperature. The oligomerization catalyst can be restored to full activity. A regeneration process can enable continuous operation.

Abstract: Transalkylation processes using catalysts comprising three dimensional 12 membered ring zeolites with a combination of small and large pores are described. These catalysts have increased conversion of alkylphenols to phenol, cresols, and alkylbenzenes from coal-derived liquid streams compared to catalysts consisting of HZSM-5 zeolite.

Abstract: A redox flow battery with an electrochemical balancing cell having first and second chambers. The first chamber includes a catalyst coated substrate and the second chamber includes an electrode. Each receives an electrolyte from the redox flow battery. There is a single interface between the two chambers. The balancing cell reverses parasitic reactions in the first chamber that occur in the redox flow battery. The products of the reversed reactions are carried away from the electrochemical balancing cell and back to the redox flow battery in the electrolyte that carried the reactant to the first chamber. Also, processes for reversing a parasitic reaction in a redox flow battery.

Abstract: A catalyst is provided for hydrodeoxygenation and hydroisomerization of paraffins having higher activity. The catalyst contains a molecular sieve, such as SAPO-11, a metal component such as platinum and/or palladium or nickel tungsten sulfide or nickel molybdenum sulfide and a binder such as gamma alumina. The catalyst exhibits a high proportion of weak acid sites and a relatively equal distribution of the metal component on the molecular sieve and the binder.

Abstract: Processes and apparatuses for operating a centrifugal gas compressor. A storage tank containing a liquid buffer material is provided and used to offset density fluctuations in the gas stream passed to the compressor. The storage tank may contain a component of the high-pressure gas stream provided by the compressor, such as carbon dioxide.

Abstract: A process for preparing an olefin stream for oligomerization comprises fractionating an olefin stream to provide a light gas stream and an olefin rich stream. Oxygenates are absorbed from the olefin rich stream into a water wash stream to provide an oxygenate rich water wash stream and a washed olefin stream. The washed olefin stream can then be oligomerized.

Abstract: A fixed bed, radial flow reforming reactor having an inner catalyst zone between an inlet fluid zone and an outlet fluid zone. The catalyst zone is separated into two concentric, annular zones, a first annular zone having a first solid particle material having a first catalytic activity for reforming hydrocarbons into the catalyst zone, and, a second annular zone having a second solid particle material having a second catalytic activity for reforming hydrocarbons into the catalyst zone, wherein the second catalytic activity is different. One of the materials may be inert. A divider may be used to separate the two annular zones.

Abstract: A process for oligomerizing olefin streams comprising sending olefin streams comprising a C2? olefin vapor stream and a C3+ olefin liquids stream to a first stage oligomerization reactor containing a solid acid oligomerization catalyst to produce a first stage oligomerized stream; oligomerizing said first-stage oligomerization stream in a second stage oligomerization reactor containing a metal catalyst to provide a second stage oligomerized stream.

Abstract: Processes and apparatuses for recovering a high purity carbon dioxide stream. A first separation zone that may include a cryogenic fractionation column provides the high-purity CO2 stream. A vapor stream from the cryogenic fractionation column is passed to a second separation zone to separate the CO2 from the other components. The second separation zone may include a pressure swing adsorption unit or a solvent separation unit. The second separation zone provides a hydrogen enriched gas stream that may be used in a gas turbine. The second stream from the second separation zone includes carbon dioxide and, after a pressure increase in a compressor, may be recycled to the first separation zone.

Abstract: A process for converting naphtha to light olefins comprises contacting a naphtha stream with a zeolitic catalyst to produce a light paraffin stream at conditions which dehydrogenate the naphtha to olefins, interconvert the olefins to lighter olefins and hydrogenate the lighter olefins to produce a light paraffin stream comprising ethane and propane. The catalyst may comprise a zeolite and a metal.

Abstract: A feed stream of cyclic paraffins may be separated to obtain an overhead of methylcyclopentane or cyclohexane and a bottoms stream cyclohexane or methylcyclohexane. The overhead stream may be subjected to separation of normal paraffins from non-normal paraffins with the former being isomerized or the entire overhead stream may be isomerized. In a further embodiment, the bottoms stream may be subjected to steam cracking. In an additional embodiment, the feed stream of cyclic paraffins may be formerly subjected to aromatic saturation.

Abstract: The apparatus produces a diesel stream from a biorenewable feedstock by hydrotreating to remove heteroatoms and hydroisomerization to improve cold flow properties. Heavy diesel can be hydrocracked to jet fuel range material or further hydroisomerized to increase its value lower its freeze point while light diesel may be taken as a motor fuel.

Abstract: An integrated apparatus for hydrogenating olefins wherein the hydrogen stream is generated from the electrolysis of water is described. Water is derived from a first reaction step wherein a first feed stream comprising oxygenated hydrocarbons is reacted to produce a first reacted product stream comprising olefins and a second reacted product stream comprising water. The second reacted product stream is electrolyzed to produce an electrolyzer product stream comprising hydrogen. Hydrogen is used to hydrogenate olefins. A paraffin stream can be obtained from the hydrogenated effluent.

Abstract: A flow battery system with a cathode cell including a first electrode, an anode cell includes a second electrode, and a membrane between the two cells. A first electrolyte tank includes a catholyte. A second electrolyte tank includes an anolyte. The system includes two rebalancing cells. A first rebalancing cell is in fluid communication between the cathode cell and the first electrolyte tank and is configured to reduce active species from the catholyte. The second rebalancing cell is in fluid communication with the first electrolyte tank and the second electrolyte tank such that the first electrolyte tank and the second electrolyte tank are in direct fluid communication. The second rebalancing cell is configured to reduce active species from the catholyte and the reduced catholyte may be combined directly with the anolyte. The second rebalancing cell may be a chemical reactor, a catalytic reactor, or an electrochemical reactor.

Abstract: A family of crystalline aluminosilicate zeolites has been synthesized that is a layered pentasil zeolite. These zeolites are represented by the empirical formula: Mmn+Rrp+Al1-xExSiyOz where M is an alkali, alkaline earth, or rare earth metal such as sodium or strontium, R can be a mixture of organoammonium cations and E is a framework element such as gallium, iron, boron, or indium. These zeolites are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes.

Abstract: A process for electrochemical conversion of carbon dioxide using a three-compartment cell provides low voltage requirements, high faradaic efficiencies, and high concentration of formic acid in product solutions. The applied voltage between anode and cathode should be less than 3.5V. Carbon dioxide may be converted to an organic acid.