Patents Assigned to Uranium Pechiney
  • Patent number: 5340447
    Abstract: A process for the selective electrofluorination of metallic alloy based on U characterized by effecting a selective anodic reaction on at least one of the components of the alloy by means of a controlled anodic voltage applied to the alloy in a bath of molten fluorides.
    Type: Grant
    Filed: June 21, 1993
    Date of Patent: August 23, 1994
    Assignee: Uranium Pechiney
    Inventors: Yves Bertaud, Sylvie Bouvet, Airy-Pierre Lamaze
  • Patent number: 5272740
    Abstract: An agent for trapping the radioactivity of the fission products which appear in a nuclear fuel based on sintered uraniferous oxides in the course of irradiation characterized in that it comprises a stable oxygenated compound, a combination of at least two metallic oxides and at least one oxide of a non-radioactive isotope of the radioactive fission product or products whose radioactivity is to be trapped.
    Type: Grant
    Filed: October 19, 1992
    Date of Patent: December 21, 1993
    Assignee: Uranium Pechiney
    Inventors: Serge Marsaud, Bertrand Morel
  • Patent number: 5268947
    Abstract: A nuclear fuel element comprising sintered pellets based on uraniferous oxide which are surrounded by a metallic sheath and permitting trapping of the fission products which appear in the course of irradiation characterized in that the pellets contain or are coated with or that the sheath is internally coated with an agent for trapping said fission products based on mixed metallic oxide comprising SiO.sub.2 and one at least of the oxides ZrO.sub.2 or CeO.sub.2.
    Type: Grant
    Filed: October 19, 1992
    Date of Patent: December 7, 1993
    Assignee: Uranium Pechiney
    Inventors: Bernard Bastide, Bertrand Morel, Michel Allibert
  • Patent number: 5091120
    Abstract: Process for obtaining nuclear fuel pellets, which produces no liquid effluent, for which the starting product is metallic uranium, which is oxidized to U.sub.3 O .sub.8, then crushed and either reduced to UO.sub.2 and activated (or vice versa) with the aid of at least one fine milling operation, or reduced to UO.sub.2 and activated using at least one oxidation-reduction cycle, the UO.sub.2 obtained then being shaped by pressing and fritting and the intermediate powders obtained are dense and pourable, no intermediate conditioning operation being required.
    Type: Grant
    Filed: November 26, 1990
    Date of Patent: February 25, 1992
    Assignee: Uranium Pechiney
    Inventors: Andre Feugier, Michel Pirsoul
  • Patent number: 4971734
    Abstract: A method of obtaining pellets of MxOy oxide, where M represents one or more elements used to make nuclear fuel pellets, as a means of obtaining very high density fritted pellets directly, i.e. without the intermediate powders being conditioned, comprising starting with a solution of soluble salts of the M elements, and treating them with hydrogen peroxide with the pH kept at from 2 to 2.5, in a continuous fluidized bed reactor comprising at least 3 superposed cylindrical sections of different diameters, the solutions in the central section being agitated vigorously, to obtain a precipitate which is subsequently calcined reduced, pressed then fritted.
    Type: Grant
    Filed: July 10, 1989
    Date of Patent: November 20, 1990
    Assignee: Uranium Pechiney
    Inventors: Antoine Floreancig, Paul Mollard
  • Patent number: 4938921
    Abstract: The present invention relates to a method of manufacturing tubes for a nuclear fuel element sheath, comprising a plurality of successive cold rolling and annealing steps including a final .beta. phase heat treatment consisting of maintaining said tube at a temperature between 950.degree. C. and 1250.degree. C. for a time duration sufficient for obtaining a homogeneous .beta. phase within and throughout the whole thickness of said tube, and rapidly cooling said tube to ambient temperature for retaining said .beta. phase throughout the whole thickness of said tube during subsequent cold processing steps including final cleaning of the tube.
    Type: Grant
    Filed: June 23, 1988
    Date of Patent: July 3, 1990
    Assignees: Framatome, S.N.C. Uranium Pechiney et Framatome
    Inventors: Jean-Paul Mardon, Jacques Decours, Michel Weisz, Jacques Pelchat, Jean Le Pape
  • Patent number: 4891192
    Abstract: Process for the purification of reprocessing uranium from which have previously been separated the fission products generated in a nuclear reactor and consisting of eliminating the U232 daughter products appearing during storage, by passing said uranium in its hexafluoride form through a chemically inert porous material.
    Type: Grant
    Filed: August 26, 1988
    Date of Patent: January 2, 1990
    Assignee: Uranium Pechiney
    Inventors: Alain Sarda, Jean-Pierre Segaud
  • Patent number: 4889663
    Abstract: For manufacturing uranium oxide based nuclear fuel pellets, a fine and reactive U.sub.3 O.sub.8 powder is mixed with a fine UO.sub.2 powder obtained by dry conversion. The U.sub.3 O.sub.8 is obtained by oxidation in air of UO.sub.2 obtained by a dry process, at a temperture less than 800.degree. C.
    Type: Grant
    Filed: June 10, 1987
    Date of Patent: December 26, 1989
    Assignee: Societe Uranium Pechiney, Framatome & Cogema, & Cie
    Inventor: Pirsoul Michel
  • Patent number: 4852645
    Abstract: The invention concerns a thermal transfer layer with high transfer coefficient between two materials which can have different expansion coefficients. The thermal transfer layer comprises expanded graphite inserted between the materials which are selected from among carbonaceous materials, ceramics and metals or metal alloys. The expanded graphite is either inserted in the form of a rolled or compressed sheet, or is compressed in situ. The invention also concerns a device for the cooling of a structure subjected to intense, continuous, intermittent or pulsating heat flux, by means of fluid circulation tubes placed in the passages in the structure. A flexible material which is a good heat conductor in a compressed state, such as expanded graphite, is placed between the structure to be cooled and each tube.
    Type: Grant
    Filed: February 12, 1988
    Date of Patent: August 1, 1989
    Assignees: Le Carbone Lorraine, Uranium Pechiney, Navatome
    Inventors: Michel Coulon, Robert Faron, Daniel Besson
  • Patent number: 4758411
    Abstract: A process for the recovery of uranium which has been extracted from phosphate-bearing solutions by means of an organic solvent and which is re-extracted from said solvent by means of hydrofluoric acid is disclosed.The process is characterized in that sodium ions are introduced into the solution of hydrofluoric acid, while aluminum and magnesium ions may also be added to the sodium ions. That solution may be produced by recycling of a fraction of the suspension of fluoride from the re-extraction step, after having separated the solvent, and to which a make-up of sodium, aluminum and magnesium ions and hydrofluoric acid was added.
    Type: Grant
    Filed: November 6, 1985
    Date of Patent: July 19, 1988
    Assignee: Uranium Pechiney
    Inventor: Antoine Floreancig
  • Patent number: 4744960
    Abstract: The present invention relates to a proces for separating rare earths and uranium from a UF.sub.4 concentrate and for placing them into useful form, comprising attacking the UF.sub.4 concentrate with potassium hydroxide, followed by nitric acid dissolution of the resulting precipitate, and extraction of the solution using an organic solvent. The extraction results in an organic solution containing purified uranyl nitrate, and an aqueous solution from which rare earths are precipitated by means of a base.
    Type: Grant
    Filed: June 25, 1986
    Date of Patent: May 17, 1988
    Assignee: Uranium Pechiney
    Inventors: Antoine Floreancig, Bernard Martinez
  • Patent number: 4714596
    Abstract: Uranium is recovered as UF.sub.4 from phosphate solutions. The uranium is reduced to the tetravalent state and extracted with an organic extractant. The uranium is recovered as UF.sub.4 by reextracting with an aqueous HF solution which includes UF.sub.4 in suspension for improved reextraction.
    Type: Grant
    Filed: November 6, 1985
    Date of Patent: December 22, 1987
    Assignee: Uranium Pechiney
    Inventor: Antoine Floreancig
  • Patent number: 4702820
    Abstract: Process for pretreatment at atmospheric pressure or a pressure close to atmospheric pressure by alkaline wetting and holding at temperature of natural materials whose gangue comprises argillaceous compounds capable of forming a stable plastic suspension in the presence of water and containing at least one combustible element which can be put into useful form wherein, in order to permit subsequent easy operations for separation of the liquid aqueous and solid phases of the gangue:(a) the natural material which was possibly been subjected to a preliminary drying operation is brought into intimate contact with at least 4 kg expressed in terms of OH.sup.- of at least one alkaline agent per ton of clay contained in said material, the total volume of liquid present in the natural material after the contacting operation being such that the ratio L/S of said volume expressed in terms of cubic meters to the weight of solid expressed in tons of dry ore is at most equal to 0.
    Type: Grant
    Filed: August 8, 1986
    Date of Patent: October 27, 1987
    Assignee: Uranium Pechiney
    Inventors: Pierre-Bernard Personnet, Jean-Michel Philbert
  • Patent number: 4700824
    Abstract: A manufacturing installation having several fixed work stations and a handling device, said work stations being disposed along at least one handling bay. It further comprises a handling device having, on the one hand, an overhead transporter movable along the handling bay and having means for grasping, transporting and setting down a batch of a given number of objects and, on the other hand, at right angles to each work station, an intermediate take up and storage device having an upstream station for setting down by the transporter, a downstream station for taking up by the transporter and a conveyor capable of grasping the batch of objects as a whole at the upstream station, presenting the objects one by one at the work station and placing them as a whole in the downstream station, so as to completely decouple the operation of the transporter from each work station.
    Type: Grant
    Filed: December 28, 1984
    Date of Patent: October 20, 1987
    Assignee: Societe Cogema, Framatome et Uranium Pechiney
    Inventors: Bernard Vere, Paul Mathevon
  • Patent number: 4680920
    Abstract: A device is provided for transferring nuclear fuel element sheaths to a fixed pellet filling station. This device comprises a sheath transfer assembly. This latter comprises a first transporter for taking as a whole a layer of several sheaths placed on the laying rack of the first means associated with the first transporter and intended for changing the spacing pitch of the sheaths in the layer and for presenting the layer at the position for simultaneous filling of several sheaths by the vibrating table machine (50) for inserting fuel pellets, second pitch change means for bringing the sheaths back to the original pitch, a transporter cooperating with a second pitch change means for bringing the layer of sheaths as a whole onto a take up rack and means for the automatic synchronized control of the components of the assembly ensuring the movements of the sheaths always in the same direction.
    Type: Grant
    Filed: December 28, 1984
    Date of Patent: July 21, 1987
    Assignee: Societe Cogema, Framatome et Uranium Pechiney
    Inventors: Bernard Vere, Paul Mathevon
  • Patent number: 4680443
    Abstract: The apparatus is for welding grids, particularly for a nuclear fuel assembly, constituted by two sets of strips at right angles and whose terminal portions are made fast to a belt. It comprises, in an enclosure with a controlled atmosphere provided with a lock, a double cross movement table bearing at least one orientation device and which is capable of bringing each surface and each side of the grid in its turn into an orientation perpendicular to the firing line of a radiation welding member and to move the frame in two directions perpendicular to the firing line, so as to bring each spot to be welded in its turn opposite the firing line. The orientation device and the table are provided with control motors and constitute an automation for presenting all the weld spots to be formed successively opposite the firing line.
    Type: Grant
    Filed: March 12, 1985
    Date of Patent: July 14, 1987
    Assignee: Cogema, Framatome et Uranium Pechiney
    Inventors: Bernard Vere, Paul Mathevon
  • Patent number: 4675166
    Abstract: Process for the selective separation of uranium in carbonated aqueous solution from soluble impurities including in particular at least one of the elements zirconium and/or hafnium and/or molybdenum, thereby making it possible to produce a uraniferous liquor in a greatly improved state of purity, comprising precipitation of the zirconium and/or hafnium by introducing an alkali metal hydroxide, then separation of the zirconiferous precipitate which possibly contains hafnium and/or molybdenum from the resulting uraniferous solution with its reduced impurities content, which still possibly contains molybdenum, which is characterized in that in order to increase the removal of zirconium and/or hafnium and/or molybdenum, the uraniferous carbonated aqueous solution is treated by means of a dilute alkaline aqueous solution containing at most 17 g/l of at least one alkali metal hydroxide expressed in respect of OH.sup.
    Type: Grant
    Filed: October 15, 1984
    Date of Patent: June 23, 1987
    Assignee: Uranium Pechiney
    Inventor: Philippe Joubert
  • Patent number: 4649030
    Abstract: A process for the purification by selective separation of uranium and/or molybdenum from zirconium and/or hafnium among other impurities contained in an amino organic phase by bringing them together with an aqueous sulphuric re-extraction solution, characterized in that, with a view to increasing the separation factor of the zirconium and/or hafnium on the one hand and the uranium and/or molbydenum on the other hand, the aqueous sulphuric re-extraction solution contains at least one alkali or equivalent sulphate.
    Type: Grant
    Filed: June 1, 1984
    Date of Patent: March 10, 1987
    Assignee: Uranium Pechiney
    Inventor: Philippe Joubert
  • Patent number: 4643882
    Abstract: A process for the recovery of the uranium present in phosphoric acid produced by a wet process in (A) by means of a suitable solvent (L.sub.9), which is carried out after separation of the gypsum in (B) formed in the attack operation, and elimination of the solid materials which are still in suspension, characterized in that, in order to avoid the formation of dross in the course of the operation of extracting the uranium which is previously reduced in (D), the step of eliminating the solid materials which are still in suspension is effected by a final solid-liquid separation operation in (C) and/or in (E), prior to extraction of the uranium in (F), in the presence of an added fraction of gypsum (S.sub.22) and/or (S.sub.23) resulting from the production of H.sub.3 PO.sub.4.
    Type: Grant
    Filed: March 5, 1984
    Date of Patent: February 17, 1987
    Assignee: Uranium Pechiney
    Inventor: Antoine Floreancig
  • Patent number: 4634580
    Abstract: A process for the removal of cadmium contained in wet-process phosphoric acid by flotation by means of a cadmium-collector anionic surface active agent and an injected gas in the presence of other impurities including iron and possibly uranium which is characterized in that, in order to improve the removal of cadmium, the iron contained in the phosphoric acid in the trivalent state is reduced to the divalent state before the cadmium collector is introduced into the medium to be purified by flotation.The collector agent is selected from the group of dithiophosphoric acid esters and the alkali metal salts thereof.
    Type: Grant
    Filed: December 14, 1984
    Date of Patent: January 6, 1987
    Assignee: Uranium Pechiney
    Inventors: El A. Jdid, Pierre Blazy, Jacques Bessiere, Antoine Floreancig