Patents Assigned to Vanderbilt Chemicals, LLC
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Patent number: 11339345Abstract: A liquid blend of octylated phenyl-?-naphthylamine, and at least one low molecular weight aromatic ester, wherein the octylated phenyl-?-naphthylamine is present from about 15% to about 35% by weight of the blend, as well as a lubricating composition comprising a lubricant base and an amount of the blend which provides up to 2.0% by weight of the octylated phenyl-?-naphthylamine in the composition.Type: GrantFiled: February 24, 2021Date of Patent: May 24, 2022Assignee: VANDERBILT CHEMICALS, LLCInventors: Vincent J. Gatto, Shubhada Dantale
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Publication number: 20210269733Abstract: A liquid blend of octylated phenyl-?-naphthylamine, and at least one low molecular weight aromatic ester, wherein the octylated phenyl-?-naphthylamine is present from about 15% to about 35% by weight of the blend, as well as a lubricating composition comprising a lubricant base and an amount of the blend which provides up to 2.0% by weight of the octylated phenyl-?-naphthylamine in the composition.Type: ApplicationFiled: February 24, 2021Publication date: September 2, 2021Applicant: VANDERBILT CHEMICALS, LLCInventors: Vincent J. GATTO, Shubhada DANTALE
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Patent number: 11046717Abstract: A borate ester represented by the following formula: where R1 is a hydrocarbon chain, R2 and R3 are independently either a hydrogen atom or a hydrocarbon chain, and m and n are independently from 1 to 5.Type: GrantFiled: April 9, 2020Date of Patent: June 29, 2021Assignee: VANDERBILT CHEMICALS, LLCInventors: Brian M. Casey, Vincent J. Gatto
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Publication number: 20210139807Abstract: This invention relates to a liquid antioxidant composition which finds utility as an antioxidant additive in candle wax and lubricant compositions, and has an additional effect of preventing crystallization of the tolutriazole additive used in such compositions. In particular, the antioxidant composition is a combination of an alkylated diphenylamine derivative of tolutriazole with benzyl benzoate.Type: ApplicationFiled: November 10, 2020Publication date: May 13, 2021Applicant: VANDERBILT CHEMICALS, LLCInventors: Martin PAISNER, Shubhada DANTALE, Vincent J. GATTO
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Publication number: 20210139806Abstract: A mixture of compounds, in which the mixture is a liquid at room temperature, represented by the following formula: where R1 consists of a mixture of at least one unsaturated or branched hydrocarbon chain and at least one saturated or unbranched hydrocarbon chain, R2 is either a hydrogen atom or a hydrocarbon chain, and m and n are independently from 1 to 5, when used in a lubricating composition, being effective for friction and wear reduction, while providing improved protection against copper and lead corrosion in an engine.Type: ApplicationFiled: January 8, 2021Publication date: May 13, 2021Applicant: VANDERBILT CHEMICALS, LLCInventors: Brian M. CASEY, Vincent J. GATTO
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Patent number: 10947473Abstract: A composition of matter represented by the following formula: where R1 is an unsaturated or branched hydrocarbon chain, R2 is either a hydrogen atom or a hydrocarbon chain, and m and n are independently from 1 to 5, when used in a lubricating composition, being effective for friction and wear reduction, while providing improved protection against copper and lead corrosion in an engine.Type: GrantFiled: May 17, 2019Date of Patent: March 16, 2021Assignee: VANDERBILT CHEMICALS, LLCInventors: Brian M. Casey, Vincent J. Gatto
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Publication number: 20200361964Abstract: A borate ester represented by the following formula: where R1 is a hydrocarbon chain, R2 and R3 are independently either a hydrogen atom or a hydrocarbon chain, and m and n are independently from 1 to 5.Type: ApplicationFiled: April 9, 2020Publication date: November 19, 2020Applicant: VANDERBILT CHEMICALS, LLCInventors: Brian M. CASEY, Vincent J. GATTO
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Publication number: 20200362261Abstract: A composition of matter represented by the following formula: where R1 is an unsaturated or branched hydrocarbon chain, R2 is either a hydrogen atom or a hydrocarbon chain, and m and n are independently from 1 to 5, when used in a lubricating composition, being effective for friction and wear reduction, while providing improved protection against copper and lead corrosion in an engine.Type: ApplicationFiled: May 17, 2019Publication date: November 19, 2020Applicant: VANDERBILT CHEMICALS, LLCInventors: Brian M. CASEY, Vincent J. GATTO
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Publication number: 20200339912Abstract: A stabilization composition for a scented candle formulation comprising: (A) an aromatic triazole compound of the formula (I) wherein R1 is a hydrocarbon chain of 4 to 12 carbon atoms, R2 is a hydrocarbon chain of 4 to 12 carbon atoms, and R3 is hydrogen or methyl; and (B) at least one longer wavelength UV light absorber, preferably a 2-(2?-Hydroxyphenyl)benzotriazole.Type: ApplicationFiled: April 20, 2020Publication date: October 29, 2020Applicant: Vanderbilt Chemicals, LLCInventor: Martin PAISNER
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Patent number: 10767134Abstract: A molybdate ester represented by the following formula: where R1 is a hydrocarbon chain, R2 is either a hydrogen atom or a hydrocarbon chain, and m and n are independently from 1 to 5, is effective when used in a lubricating composition in an amount sufficient to provide about 50-5000 ppm of molybdenum, with respect to friction and wear reduction, while providing improved protection against copper and lead corrosion.Type: GrantFiled: May 17, 2019Date of Patent: September 8, 2020Assignee: VANDERBILT CHEMICALS, LLCInventors: Brian M. Casey, Vincent J. Gatto
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Patent number: 10590364Abstract: The present invention relates to lubricating compositions comprising a compound of Formula I: wherein R1-R4 and R5-R8 are independently selected from the group consisting of hydrocarbyl groups and hydrocarbyl groups containing heteroatoms, such that the total carbon atoms from counterions Q1 and Q2 is from 8 to 76, and molybdate anion (Y) is a binuclear sulfur-containing dianion selected from the group consisting of [Mo2S8O2]2?, [Mo2S9O]2?, [Mo2S10]2, and mixtures thereof, and are present in the lubricating composition in an amount sufficient to provide about 100-15,000 ppm molybdenum.Type: GrantFiled: July 25, 2018Date of Patent: March 17, 2020Assignee: VANDERBILT CHEMICALS, LLCInventors: Brian M. Casey, Vincent J. Gatto
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Patent number: 10280381Abstract: A lubricating composition for use in heavy duty diesel engines which is formulated to allow the use of organo-molybdenum compounds but which overcomes the issue of Cu and/or Pb corrosion and also maintains elastomer seal compatibility. The lubricant is characterized by having a composition comprising (A) an organo-molybdenum compound, (B) an alkylated diphenylamine derivative of triazole, (C) base oil, and optionally (D) one or more additives selected from the group including antioxidants, dispersants, detergents, anti-wear additives, extreme pressure additives, friction modifiers, rust inhibitors, corrosion inhibitors, seal swell agents, anti-foaming agents, pour point depressants and viscosity index modifiers.Type: GrantFiled: August 2, 2016Date of Patent: May 7, 2019Assignee: VANDERBILT CHEMICALS, LLCInventors: Mihir K. Patel, Vincent J. Gatto
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Patent number: 10087390Abstract: A lubricant composition is provided which mitigates the negative effect of zinc in ZDDP with respect to wear on timing chains by using in contact with the timing chain a lubricant composition comprising an ashless zinc-free organophosphorus compound and optionally zinc dialkyldithiophosphate, together providing about 50 to about 1000 ppm phosphorus, preferably about 300-800 ppm phosphorus, and more preferably about 500-750 ppm phosphorus; less than about 350 ppm to lower than <1 ppm zinc from ZDDP; and at least about 100 ppm molybdenum from an organomolybdenum compound (preferably molybdate ester); wherein the Mo:Zn ratio is at least about 0.2:1 and the Zn:P ratio is lower than or equal to about 1.1:1; or in the alternative an organomolybdenum compound providing between about 300-700 ppm molybdenum, in combination with ZDDP providing zinc between about 200-800 ppm zinc, wherein the ratio of Mo:Zn ratio is at least about 0.4:1 to about 3:1.Type: GrantFiled: May 3, 2016Date of Patent: October 2, 2018Assignee: VANDERBILT CHEMICALS, LLCInventors: Carl K. Esche, Glenn A. Mazzamaro
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Patent number: 10059901Abstract: The present invention relates to lubricating compositions comprising a compound of Formula I: wherein R1-R4 and R5-R8 are independently selected from the group consisting of hydrocarbyl groups and hydrocarbyl groups containing heteroatoms, such that the total carbon atoms from counterions Q1 and Q2 is from 8 to 76, and molybdate anion (Y) is a binuclear sulfur-containing dianion selected from the group consisting of [Mo2S8O2]2?, [Mo2S9O]2?, [Mo2S10]2?, and mixtures thereof, and are present in the lubricating composition in an amount sufficient to provide about 100-15,000 ppm molybdenum.Type: GrantFiled: February 14, 2017Date of Patent: August 28, 2018Assignee: VANDERBILT CHEMICALS, LLCInventors: Brian M. Casey, Vincent J. Gatto
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Patent number: 9994531Abstract: An antioxidant composition which comprises: (a) methylenebis(di-n-butyldithiocarbamate); and (b) an alkylated diphenylamine derivative of triazole wherein the alkyl group on at least one of the phenyl groups is C8 or higher. Lubricating compositions containing the antioxidant composition are also contemplated.Type: GrantFiled: August 2, 2016Date of Patent: June 12, 2018Assignee: VANDERBILT CHEMICALS, LLCInventor: Vincent J. Gatto
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Patent number: 9902915Abstract: The present invention relates to a compound of the Formula I: and a lubricating composition containing and a method for preparing the same. In Formula I, R1-R5 and R6-R10 are independently selected from the group consisting of hydrogen, hydrocarbyl groups and hydrocarbyl groups containing heteroatoms, such that the total carbon atoms from Q1 and Q2 is from 6 to 166 carbon atoms, and molybdate anion (Y) is a binuclear sulfur-containing dianion selected from the group consisting of [Mo2S8O2]2?, [Mo2S9O]2?, and [Mo2S10]2.Type: GrantFiled: February 14, 2017Date of Patent: February 27, 2018Assignee: VANDERBILT CHEMICALS, LLCInventors: Brian M. Casey, Vincent J. Gatto
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Patent number: 9896638Abstract: A low-phosphorus lubricating composition having less than 600 ppm phosphorus, comprising at least 85 weight % of a lubricating base blend, and an additive comprising the following, as weight % of the total composition: (1) an organomolybdenum component comprising: (a) an organomolybdenum complex, and (b) a molybdenum dithiocarbamate, the organomolybdenum component being present at an amount which provides about 400-800 ppm Mo; (2) (iso-octyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate), at about 0.25-1.5%; (3) a dithiocarbamate component comprising (a) methylene-bis-dialkyldithiocarbamate and (b) said molybdenum dithiocarbamate, at a total dithiocarbamate component of about 0.6-1.2%; and (4) an alkylated diphenyl amine, at about 0.5-1.5%.Type: GrantFiled: December 2, 2016Date of Patent: February 20, 2018Assignee: VANDERBILT CHEMICALS, LLCInventors: Glenn A. Mazzamaro, Steven G. Donnelly, Ronald J. Hiza
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Patent number: 9783759Abstract: A lubricating composition comprising at least 90% by weight of a base oil, and an antioxidant composition comprising the components, set forth as weight % of the lubricating composition: (1) solid alkylated-phenyl-alpha-naphthylamine at 0.01-0.3%, (2) an alkylated diphenylamine derivative of triazole, tolutriazole or benzotriazole, at 0.01-0.3%, and (3) methylenebis(di-n-butyldithiocarbamate), at 0.01-0.4%.Type: GrantFiled: August 14, 2015Date of Patent: October 10, 2017Assignee: VANDERBILT CHEMICALS, LLCInventors: Junbing Yao, Vincent Gatto
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Patent number: 9765276Abstract: A lubricating composition for use in heavy duty diesel engines which is formulated to allow the use of organomolybdenum compounds but which overcomes the issue of Cu and/or Pb corrosion. The lubricant is characterized by having a synergistic additive composition comprising (A) a sulfur-free organo-molybdenum compound, (B) a sulfur-containing organo-molybdenum compound and (C) a triazole derivative prepared by reacting 1,2,4-triazole, a formaldehyde source and an amine; (A), (B) and (C) being present in an amount sufficient to allow the lubricating composition to pass the High Temperature Corrosion Bench Test ASTM D 6594 with respect to Cu and/or Pb corrosion.Type: GrantFiled: August 2, 2016Date of Patent: September 19, 2017Assignee: VANDERBILT CHEMICALS, LLCInventors: Mihir K. Patel, Vincent J. Gatto
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Publication number: 20170240838Abstract: The present invention relates to lubricating compositions comprising a compound of Formula I: wherein R1-R4 and R5-R8 are independently selected from the group consisting of hydrocarbyl groups and hydrocarbyl groups containing heteroatoms, such that the total carbon atoms from counterions Q1 and Q2 is from 8 to 76, and molybdate anion (Y) is a binuclear sulfur-containing dianion selected from the group consisting of [Mo2S8O2]2?, [Mo2S9O]2?, [Mo2S10]2?, and mixtures thereof, and are present in the lubricating composition in an amount sufficient to provide about 100-15,000 ppm molybdenum.Type: ApplicationFiled: February 14, 2017Publication date: August 24, 2017Applicant: VANDERBILT CHEMICALS, LLCInventors: Brian M. CASEY, Vincent J. GATTO