Abstract: A high temperature, redox tolerant fuel cell anode electrode and method of fabrication in which the anode electrode is pre-conditioned by application of an initial controlled redox cycle to the electrode whereby an initial re-oxidation of the anode electrode is carried out at temperatures less than or equal to about 650° C.

Abstract: A high temperature, redox tolerant fuel cell anode electrode and method of fabrication in which the anode electrode is pre-conditioned by application of an initial controlled redox cycle to the electrode whereby an initial re-oxidation of the anode electrode is carried out at temperatures less than or equal to about 650° C.

Abstract: A multilayer contact approach for use in a planar solid oxide fuel cell stack includes at least 3 layers of an electrically conductive perovskite which has a coefficient of thermal expansion closely matching the fuel cell material. The perovskite material may comprise La1-xExCo0.6Ni0.4O3 where E is a alkaline earth metal and x is greater than or equal to zero. The middle layer is a stress relief layer which may fracture during thermal cycling to relieve stress, but remains conductive and prevents mechanical damage of more critical interfaces.

Abstract: The present invention relates to an apparatus for steam purging a solid oxide fuel cell stack. Purging the SOFC stack with steam has a physical flushing effect, removing carbon monoxide containing reformate and free oxygen gas from the anode area thereby reducing the potential for nickel oxide or nickel carbonyl formation.

Abstract: A multilayer contact approach for use in a planar solid oxide fuel cell stack includes at least 3 layers of an electrically conductive perovskite which has a coefficient of thermal expansion closely matching the fuel cell material. The perovskite material may comprise La1-x Ex Co0.6Ni0.4O3 where E is a alkaline earth metal and x is greater than or equal to zero. The middle layer is a stress relief layer which may fracture during thermal cycling to relieve stress, but remains conductive and prevents mechanical damage of more critical interfaces.

Abstract: The present invention relates to a method and apparatus for steam purging a solid oxide fuel cell stack. Purging the SOFC stack with steam has a physical flushing effect, removing carbon monoxide containing reformate and free oxygen gas from the anode area thereby reducing the potential for nickel oxide or nickel carbonyl formation.

Abstract: A flexible seal for use in a solid oxide fuel cell stack is formed from a fibre matrix with a plurality of solid particles through tape casting method. The fibres and particles are preferably ceramic and may be formed from alumina or zirconia. The seal may be formed by forming a slurry of fibres, particles, a binder and a non-aqueous solvent, tape casting the slurry, drying the tape seal, die-cutting, prior to installation in the fuel cell stack.

Abstract: A flexible seal for use in a solid oxide fuel cell stack is formed from a fiber matrix with a plurality of solid particles through tape casting method. The fibers and particles are preferably ceramic and may be formed from alumina or zirconia. The seal may be formed by forming a slurry of fibers, particles, a binder and a non-aqueous solvent, tape casting the slurry, drying the tape seal, die-cutting, prior to installation in the fuel cell stack.

Abstract: A thermally integrated fuel cell system includes a stack zone, a burner zone and a low temperature zone. The fuel is combined with steam and passed sequentially through a primary reformer and a secondary reformer. Air is split into two parallel streams and preheated in a low temperature heat exchanger. One air stream passes to a high temperature heat exchanger while the other passes to a radiative heat exchanger. The air and fuel streams are equalized in an equalization heat exchanger before entering the fuel cell stacks. The stack exhaust is combusted in an afterburner. Afterburner exhaust heats the primary reformer, the high temperature heat exchanger, the low temperature heat exchanger and steam generator. The stack zone includes the stacks, the secondary reformer, the radiative heat exchanger and the equalization heat exchanger. The burner zone includes the afterburner, the primary reformer and the high temperature heat exchanger.

Abstract: A high temperature, redox tolerant fuel cell anode electrode and method of fabrication in which the anode electrode is pre-conditioned by application of an initial controlled redox cycle to the electrode whereby an initial re-oxidation of the anode electrode is carried out at temperatures less than or equal to about 650° C.

Abstract: A thermally integrated fuel cell system includes a stack zone, a burner zone and a low temperature zone. The fuel is combined with steam and passed sequentially through a primary reformer and a secondary reformer or a radiative fuel heat exchanger. Air may be passed sequentially through an afterburner heat exchanger and a radiative air heat exchanger such that the radiative heat exchanger may be used to heat the stack zone. The stack exhaust is combusted in an afterburner. Afterburner exhaust heats the primary reformer, the high temperature air heat exchanger, the low temperature air heat exchanger and steam generator. The stack zone includes the stacks, the secondary reformer and the radiative heat exchanger. The burner zone includes the afterburner which includes a start burner, the primary reformer and the high temperature air heat exchanger. The low temperature zone includes the low temperature air heat exchanger and a steam generator.

Abstract: A thermally integrated fuel cell system includes a stack zone, a burner zone and a low temperature zone. The fuel is combined with steam and passed sequentially through a primary reformer and a secondary reformer or a radiative fuel heat exchanger. Air may be passed sequentially through an afterburner heat exchanger and a radiative air heat exchanger such that the radiative heat exchanger may be used to heat the stack zone. The stack exhaust is combusted in an afterburner. Afterburner exhaust heats the primary reformer, the high temperature air heat exchanger, the low temperature air heat exchanger and steam generator. The stack zone includes the stacks, the secondary reformer and the radiative heat exchanger. The burner zone includes the afterburner which includes a start burner, the primary reformer and the high temperature air heat exchanger. The low temperature zone includes the low temperature air heat exchanger and a steam generator.

Abstract: A high-temperature, flexible conductive cable is formed from a solid copper core, sheathed and hermetically sealed in a flexible stainless steel sheath, which may be corrugated.

Abstract: A solid oxide fuel cell stack includes a fuel cell unit consisting of a fuel cell framed by a cell holder plate and upper and lower cushioning elements. The fuel cell unit is stacked with flow field seals and solid flow separator plates. The fuel cell thus floats without direct contact with rigid stack elements.

Abstract: A solid oxide fuel cell having a plurality of planar layered fuel cell units, an electrically conductive flow separator plate disposed between each of the fuel cell units, and a cathode contact material element disposed between each cathode electrode of the fuel cell units and each electrically conductive flow separator plate. The cathodes of the individual fuel cell units are modified such that the operating temperatures of the cathodes are matched with the temperatures they experience based upon their locations in the fuel cell stack. The modification involves adding to the cathode contact material and/or cathode at least one alloying agent which modifies the temperature of the cathode electrodes based upon the location of the cathode electrodes within the fuel cell stack. These alloying agents react with a component of the cathode electrode to form alloys.

Abstract: In a solid oxide fuel cell having an anode, a cathode, and a dense electrolyte disposed between the anode and the cathode, the cathode having a ceramic-ionic conducting phase of a plurality of ionic conducting particles and a metallic phase of a plurality of metallic particles. The metallic phase includes a metal alloy having an oxide-to-metal transition temperature in the range of about 600° C. to about 800° C. With this cathode, solid oxide fuel cell operating temperatures as low as about 600° C. may be possible.

Abstract: A solid oxide fuel cell stack may include repeating fuel cell units each having a planar fuel cell, an interconnect, a cathode contact layer disposed between sealing strips, and an anode contact layer disposed between sealing strips. The sealing strips have end extensions which overlap with corner extensions on the interconnect. The extensions stack to form vertical columns which enclose the external manifolds, along with a manifold plate.

Abstract: A solid oxide fuel cell electrode is stable during thermal cycling and includes a plurality of discrete geometric elements lightly packed on the electrolyte surface. Preferably, the geometric elements are regular hexagons, creating a “Thoneycomb” pattern electrode.

Abstract: A thermally integrated fuel cell system includes a stack zone, a burner zone and a low temperature zone. The fuel is combined with steam and passed sequentially through a primary reformer and a secondary reformer. Air is split into two parallel streams and preheated in a low temperature heat exchanger. One air stream passes to a high temperature heat exchanger while the other passes to a radiative heat exchanger. The air and fuel streams are equalized in an equalization heat exchanger before entering the fuel cell stacks. The stack exhaust is combusted in an afterburner. Afterburner exhaust heats the primary reformer, the high temperature heat exchanger, the low temperature heat exchanger and steam generator. The stack zone includes the stacks, the secondary reformer, the radiative heat exchanger and the equalization heat exchanger. The burner zone includes the afterburner, the primary reformer and the high temperature heat exchanger.

Abstract: A multilayer contact approach for use in a planar solid oxide fuel cell stack includes at least 3 layers of an electrically conductive perovskite which has a coefficient of thermal expansion closely matching the fuel cell material. The perovskite material may comprise La1-xEx Co0.6Ni0.4O3 where E is a alkaline earth metal and x is greater than or equal to zero. The middle layer is a stress relief layer which may fracture during thermal cycling to relieve stress, but remains conductive and prevents mechanical damage of more critical interfaces.