Patents Assigned to Vetrotex Saint Gobain
  • Patent number: 5389440
    Abstract: An aqueous emulsion for use in forming a weight average sizing coating for treating a surface of a substrate. The emulsion comprises at least one polyolefin having a molecular weight greater than 10,000; an acid material selected from the group consisting of saturated fatty acids, unsaturated fatty acids which do not includ any hydroxyl groups and mixtures thereof; at least one base; optionally, an emulsifying agent; and a sufficient amount of water to form an aqueous phase emulsion comprising from about 10-50% of solid materials.
    Type: Grant
    Filed: May 31, 1994
    Date of Patent: February 14, 1995
    Assignee: Vetrotex Saint-Gobain
    Inventors: Michel Arpin, Paul Petit, Andre Vagnon
  • Patent number: 5242969
    Abstract: An aqueous emulsion for use in forming a sizing coating for treating a surface of a substrate. The emulsion comprises at least one polyolefin having a weight average molecular weight greater than 10,000; an acid material selected from the group consisting of saturated fatty acids, unsaturated fatty acids which do not includ any hydroxyl groups and mixtures thereof; at least one base; optionally, an emulsifying agent; and a sufficient amount of water to form an aqueous phase emulsion comprising from about 10-50% of solid materials.
    Type: Grant
    Filed: September 5, 1991
    Date of Patent: September 7, 1993
    Assignee: Vetrotex-Saint Gobain
    Inventors: Michel Arpin, Paul Petit, Andre Vagnon
  • Patent number: 5236743
    Abstract: A method for continuously coating individual fibers of a fiber bundle with resin. The individual fibers are grouped at a single grouping pint defined by a first concave supporting surface. The fibers are directed through a resin bath while spreading the fibers apart on a convex surface in a regularly spaced arrangement to form a continuous coating of resin along at least a portion of the fibers. The convex surface is at least partially described by an arc rotated about a horizontal axis, and comprises at least a portion of a surface of maximum radius R which is symmetrical relative to a vertical plane of symmetry passing through the fiber grouping point.
    Type: Grant
    Filed: March 16, 1992
    Date of Patent: August 17, 1993
    Assignee: Vetrotex Saint Gobain
    Inventors: Philip J. Bates, Jean-Michel Charrier
  • Patent number: 5171634
    Abstract: A process for producing coated glass yarns which comprises drawing a plurality of fibers formed from strands of molten glass, applying to the strands a sizing coating comprising at least a monounsaturated or polyunsaturated oligomer and a photostarter composition such as a photoinitiator compound, a photosensitizer compound or a mixture thereof and optionally an organic solvent and an additive composition comprising at least one of a wetting agent, an adhesion promoting agent, an antishrinking agent and a coupling agent, gathering the coated strands into a yarn and irradiating the coated yarn with a source of actinic radiation.
    Type: Grant
    Filed: June 5, 1991
    Date of Patent: December 15, 1992
    Assignee: Vetrotex Saint-Gobain
    Inventors: Barbara Soszka, Jacques Mahler, Eric Augier
  • Patent number: 5133282
    Abstract: An apparatus for continuously coating individual fibers of a fiber bundle with resin, which comprises a first concave support surface for grouping the fibers of the bundle substantially at a single grouping point and a second, convex, support surface at least partially described by an arc rotated about its horizontal axis, having a maximum radius R, which at least approximately satisfies the relationship expressed in the following formula: wherein r designates the radius of the arc at distance x from the plane of symmetry, passing through fiber grouping point (P): ##EQU1## and wherein L designates the length of a tangent to the second support surface which passes through grouping point (P), in the plane of symmetry, and .phi. designates the radian angle formed between the tangent and the vertical line.
    Type: Grant
    Filed: September 13, 1990
    Date of Patent: July 28, 1992
    Assignee: Vetrotex Saint Gobain
    Inventors: Philip J. Bates, Jean-Michel Charrier
  • Patent number: 5049407
    Abstract: A process for producing coated glass yarns which comprises drawing a plurality of fibers formed from strands of molten glass, applying to the strands a sizing coating comprising at least a monounsaturated or polyunsaturated oligomer and a photostarter composition such as a photoinitiator compound, a photosensitizer compound or a mixture thereof and optionally an organic solvent and an additive composition comprising at least one of a wetting agent, an adhesion promoting agent, an antishrinking agent and a coupling agent, gathering the coated strands into a yarn and irradiating the coated yarn with a source of actinic radiation.
    Type: Grant
    Filed: February 17, 1989
    Date of Patent: September 17, 1991
    Assignee: Vetrotex Saint-Gobain
    Inventors: Barbara Soszka, Jacques Mahler, Eric Augier
  • Patent number: 5018255
    Abstract: This invention relates to needling of continuous glass yarn mats.The invention consists in subjecting the mat to the action, preferably simultaneous action, of needles of different diameters. Thus perforations of different dimensions, preferably regularly distributed, are made in the mat.This mat is intended to be used as reinforcement in composite materials with a base of thermoplastic resins, in particular in laminates.
    Type: Grant
    Filed: June 24, 1988
    Date of Patent: May 28, 1991
    Assignees: Vetrotex Saint-Gobain S.A., Institut Textile de France
    Inventor: Robert Bolliand
  • Patent number: 5011523
    Abstract: The invention relates to an apparatus and process for the direct production of a composite yarn or ribbon of continuous reinforcement fibers and a thermoplastic organic material. The process includes drawing reinforcement fibers from molten glass, driving or extruding a thermoplastic organic material, converging the paths followed by the reinforcement fibers and the organic material toward one another, and joining the organic material and fibers in at least one composite yarn or ribbon. An apparatus for conducting this process is also disclosed.
    Type: Grant
    Filed: October 27, 1989
    Date of Patent: April 30, 1991
    Assignee: Vetrotex Saint Gobain
    Inventors: Giordano Roncato, Robert Federowsky
  • Patent number: 5002598
    Abstract: The application discloses an apparatus and a process for the manufacture of continuous fibers by mechanical attenuation. It is especially useful in obtaining a strand composed of a mixture of filaments of differing cross sections in constant and definite proportion. This is obtained by employment of a bushing having a lower surface comprising a multiplicity of fiberizing centers of varying configurations, each fiberizing center being formed by a zone perforated by a group of orifices from which at least one filament can be attenuated in a stable manner. The strands produced are particularly adapted for the reinforcement of plastic materials.
    Type: Grant
    Filed: January 6, 1989
    Date of Patent: March 26, 1991
    Assignee: Societe Vetrotex Saint-Gobain
    Inventors: Jacques Lecron, Maxime Manera, Jean-Paul Faure, Jean-Pierre Renaudin
  • Patent number: 4994114
    Abstract: According to the invention a pozzolan is selected which exhibits a capacity for fixing lime during the Chapelle test at 90.degree. C. greater than 700 mg of CaO per gram of pozzolan, a capacity for fixing lime during the Chapelle test at 50.degree. C. greater than 200 mg of CaO per gram of pozzolan and a ratio of the quantity of CaO fixed during the 50.degree. C. Chapelle test to the specific surface area of the pozzolan which is greater than about 10 mg of CaO per square meter of pozzolan. The composite material obtained is used in construction to produce facade elements, for example, which have improved resistance to aging.
    Type: Grant
    Filed: July 6, 1989
    Date of Patent: February 19, 1991
    Assignee: Vetrotex Saint-Gobain
    Inventors: Jacques Thiery, Pascal Soukatchoff
  • Patent number: 4975396
    Abstract: A process for producing reinforced cementitious compositions in which the following constituents are mixed in the aqueous phase in the following order: about 35-55 parts by weight of water mixed with about 3-12 parts of a polymer, by weight of dry polymer; up to about 5 parts of a water-reducing auxiliary agent and/or a liquifying agent; from about 15-30 parts of metakaolin; from about 50-120 parts of silica sand; and about 100 parts of cement. Continuous mixing is maintained until a homogeneous, thixotropic paste is obtained. Then between 2 and 15% by weight of alkaline-resistant glass fibers, relative to the weight of the paste, is introduced into the paste. The product produced by this method is particularly suitable for use as a mortar or paste which may be easily sprayed upon vertical surfaces and as hydraulic concretes, resistant to the effects of weather and aging.
    Type: Grant
    Filed: March 16, 1989
    Date of Patent: December 4, 1990
    Assignee: Vetrotex Saint-Gobain
    Inventor: Jacques Thiery
  • Patent number: 4927445
    Abstract: A process for producing coated, single twist glass yarns which comprises drawing a plurality of fibers formed from fibers of molten glass, applying to the fibers a sizing comprising a thermoplastic, thermosetting or photosetting composition, gathering the coated fibers into a yarn, imparting a continuous rotative twisting movement to the coated yarn and curing the coated yarn so as to polymerize and/or crosslink the sizing coating.
    Type: Grant
    Filed: April 5, 1989
    Date of Patent: May 22, 1990
    Assignee: Vetrotex Saint-Gobain
    Inventors: Barbara Soszka, Robert Federowsky, Jacques Mahler
  • Patent number: 4853021
    Abstract: A process for producing coated, single twist glass yarns which comprises drawing a plurality of fibers formed from fibers of molten glass, applying to the fibers a sizing comprising a thermoplastic, thermosetting or photosetting composition, gathering the coated fibers into a yarn, imparting a continuous rotative twisting movement to the coated yarn and curing the coated yarn so as to polymerize and/or crosslink the sizing coating. An apparatus for performing this process comprises a spinneret having a plurality of nozzles or orifices from which fibers of molten glass are discharged; means for drawing a plurality of glass fibers from the spinneret; at least one coating applicator for applying the sizing coating to the glass fibers; guide means for gathering the coated fibers into a yarn; means for imparting a single twist to the coated yarn, such as a strap spindle device and means for curing the sizing coating wherein the coating is crosslinked and/or polymerized.
    Type: Grant
    Filed: December 2, 1987
    Date of Patent: August 1, 1989
    Assignee: Vetrotex Saint-Gobain
    Inventors: Barbara Soszka, Robert Federowsky, Jacques Mahler
  • Patent number: 4835122
    Abstract: The invention relates to glass fiber compositions and fibers having use as a reinforcement element of cement-base products. As such, the composition is able to resist attack of strongly basic media.The fibers of the invention comprise the following constituents, in proportions by weight:SiO.sub.2 --56 to 68%,ZrO.sub.2 --14 to 17%,Na.sub.2 O--12 to 20%,K.sub.2 O--0 to 8%,Al.sub.2 O.sub.3 --1 to 9%,and wherein the sum of Na.sub.2 O and K.sub.2 O is between 14 and 22%, and wherein the sum of SiO.sub.2 and Al.sub.2 O.sub.3 is less than 70%.
    Type: Grant
    Filed: January 28, 1986
    Date of Patent: May 30, 1989
    Assignee: Vetrotex Saint-Gobain
    Inventor: Marie-Helene Chopinet
  • Patent number: 4793861
    Abstract: The invention relates to a cement-based product which is reinforced with glass fibers having good resistance to alkaline environments. The product of the invention contains, for each 100 parts by weight of cement, about 10 to 40 parts by weight of metakaolin, the latter exhibiting a reactivity to the modified Chapelle test greater than 500 mg of CaO per gram of metakaolin. The product of the invention has many uses in the building trade, particularly to produce facade coverings.
    Type: Grant
    Filed: July 7, 1987
    Date of Patent: December 27, 1988
    Assignee: Vetrotex Saint-Gobain
    Inventor: Jean-Michel Sohm
  • Patent number: 4790900
    Abstract: A method and apparatus are disclosed for winding at least a layer of separate fibers or groups of fibers onto a rotating support while modifying the width of the layer by moving the layer between two extreme positions perpendicular to the direction of fiber travel and simultaneously moving each fiber or group of fibers in its own plane of motion, offset in relation to a vertical plane at an angle varying from one plane to the next.
    Type: Grant
    Filed: April 2, 1986
    Date of Patent: December 13, 1988
    Assignee: Vetrotex Saint-Gobain, c/o Saint Gobain Recherche
    Inventors: Daniel Guillon, Alain Bricard
  • Patent number: 4727096
    Abstract: The invention relates to a composition of polymerizable resins reinforced with cut yarns of different lengths, such as glass yarns, and a process for its production. This composition comprises at least a representative of each of the following constituents: an unsaturated polyester, a thermoplastic polymer, a monomer liquid substance having at least a polymerizable reactive CH.sub.2 .dbd.C< group per molecule, an inert filler and optionally a thickening agent, a catalyst, an inhibitor and a releasing agent, the cut yarns being in the dispersed state in filament form for the longest ones, with the shortest yarns remaining in state of yarn formed from a multiplicity of filaments glued together. The process steps include making the mixture of the organic constituents and successively incorporating therein first the yarns previously coated with an insoluble lubricant, then the yarns coated with a lubricant which is soluble in the mixture.
    Type: Grant
    Filed: October 16, 1986
    Date of Patent: February 23, 1988
    Assignee: Vetrotex Saint-Gobain
    Inventor: Claude Choudin
  • Patent number: 4693429
    Abstract: The invention relates to a winding device and process to produce packages from several separate continuous fibers. The installation of this invention includes a spinneret receiving a thermoplastic material in the molten state, a rotating spindle carrying a support and drawing strands of material from the orifices of the spinneret and winding of the resulting fibers, a gathering and guiding device and a crisscrossing device including a fiber guide with an opening opposite the spindle communicating with an interior guide zone provided with at least two notches on its periphery.
    Type: Grant
    Filed: November 14, 1985
    Date of Patent: September 15, 1987
    Assignee: Vetrotex Saint Gobain
    Inventors: Georges Billard, Francoise Blanchard, Willy Klemenz, Roger Combet, Daniel Richard
  • Patent number: 4473387
    Abstract: Apparatus for the manufacture of thermoplastic mineral fibers is disclosed.A bushing base is formed by a flat plate in which a multitude of conduits are arranged. The upper ends of the conduits open toward the inside of the bushing and their lower ends toward a multitude of small alveoles, each alveole being in communication with the inside of the bushing by means of one of the said conduits. A continuous flat wall closes the base of each alveole, the said wall being perforated by several orifices forming a grouping of orifices.
    Type: Grant
    Filed: October 20, 1983
    Date of Patent: September 25, 1984
    Assignee: Societe Vetrotex Saint-Gobain
    Inventors: Jacques Lecron, Maxime Manera, Jean-Paul Faure, Jean-Pierre Renaudin
  • Patent number: 4469499
    Abstract: A process and apparatus is disclosed for forming fibers from attenuable materials, such as molten glass, by attenuating streams of glass from the bottom of a bushing wherein the bottom has downwardly presented wall portions at upper and lower levels. According to the disclosure the upper or lower wall portions are formed into series of bosses, each having a multiplicity of orifices in the lower ball portions. Bosses with alveoles are disclosed. Filamentary material is manufactured by drawing at least one filament from each boss independently of each other boss or from separate fiber forming regions in each boss regardless of whether or not the material has flooded the bottom surface of any boss. Embodiments with one alveole per boss or plural alveoles per boss are disclosed. Where plural alveoles per boss are provided, shallow transverse grooves in the lower wall portions of the bosses may be used to separate the orifices of one alveole from the orifices of adjacent alveoles.
    Type: Grant
    Filed: May 3, 1983
    Date of Patent: September 4, 1984
    Assignee: Societe Vetrotex Saint-Gobain
    Inventors: Jacques Lecron, Maxime Manera, Jean-Paul Faure, Jean-Pierre Renaudin