Abstract: It is now possible to desulfurize gases containing appreciable carbon dioxide proportions by limiting the production of carbon oxysulfide to a very low level, by treating these gases with adsorbents composed of very small, partially calcic zeolite A crystals agglomerated by clays containing low levels of iron and having reduced acidity and basicity. These clays may be obtained by phosphatization of montmorillonite, bentonite, attapulgite, or kaolin.
Type:
Grant
Filed:
November 22, 1994
Date of Patent:
March 11, 1997
Assignee:
Vniigaz
Inventors:
Albert M. Tsybulevski, Vladimir I. Mourine, Dominique Plee, Francis Mayolet
Abstract: Particular mixed vanadium/other metal catalysts, well suited for the desulfurization of gaseous effluents containing contaminating amounts of objectionable sulfur compounds, typically via the Claus reaction and notably in the presence of oxygen, comprise a support substrate, e.g., titanium dioxide, having an active catalytic phase deposited thereon, such active catalytic phase being constituted of an electroneutral solid solution having the average composition:A.sub.4.+-.y V.sub.2.+-.x O.sub.9in which A is a metal other than vanadium, e.g., magnesium, calcium or zinc, 0.ltoreq.x.ltoreq.0.2 and 0.ltoreq.y.ltoreq.0.5.
Type:
Grant
Filed:
June 5, 1995
Date of Patent:
February 18, 1997
Assignees:
Institut De Catalyse Du Department Siberien De L'Academie Des Sciences De Russie, Vniigaz
Inventors:
Roman A. Bouyanov, Albert M. Tsyboulesky, Boris P. Zolotovsky, Dimitri P. Klevtsov, Vladimir L. Mourine
Abstract: The desulfurization of gaseous effluents containing contaminating amounts of objectionable sulfur compounds, typically via the Claus reaction and notably in the presence of oxygen, utilizing a support substrate, e.g., titanium dioxide, having an active catalytic phase deposited thereon, such active catalytic phase being constituted of an electroneutral solid solution having the average composition:A.sub.4.+-.y V.sub.2.+-.x O.sub.9in which A is a metal other than vanadium, e.g., magnesium, calcium or zinc, 0.ltoreq.x.ltoreq.0.2 and 0.ltoreq.y.ltoreq.0.5.
Type:
Grant
Filed:
August 16, 1994
Date of Patent:
April 30, 1996
Assignee:
Institut De Catalyse Du Departement Siberien De L'Academie Des Sciences De Russie and Vniigaz
Inventors:
Roman A. Bouyanov, Albert M. Tsyboulesky, Dimitri P. Klevtsov, Vladimir I. Mourine
Abstract: Particular mixed vanadium/other metal catalysts, well suited for the desulfurization of gaseous effluents containing contaminating amounts of objectionable sulfur compounds, typically via the Claus reaction and notably in the presence of oxygen, comprise a support substrate, e.g., titanium dioxide, having an active catalytic phase deposited thereon, such active catalytic phase being constituted of an electroneutral solid solution having the average composition:A.sub.4.+-.y V.sub.2.+-.x O.sub.9in which A is a metal other than vanadium, e.g., magnesium, calcium or zinc, 0.ltoreq.x.ltoreq.0.2 and 0.ltoreq.y.ltoreq.0.5.
Type:
Grant
Filed:
June 17, 1992
Date of Patent:
November 29, 1994
Assignee:
Institut de Catalyse du Department Siberien de l'Academie des Sciences de Russie and Vniigaz (Institut de recherches de gas naturels)
Inventors:
Roman A. Bouyanov, Albert M. Tsyboulesky, Boris P. Zolotovsky, Dimitri P. Klevtsov, Vladimir I. Mourine
Abstract: A method for the recovery of a methane-rich natural gas from a natural gas containing, apart from methane, also hydrogen sulfide, carbondioxide, higher hydrocarbons and, in most cases, organosulfur compounds. According to the invention a hydrocarbon fraction of C.sub.4 hydrocarbons and higher is naturally removed from the natural gas which is then subjected to a selective scrubbing for the removal of hydrogen sulfide with a regeneratable extraction, of scrubbing liquid. Next a C.sub.3 fraction is removed, the remaining gas being scrubbed with a second regeneratable washing agent, for the removal of carbondioxide to leave the methane-rich gas.
Type:
Grant
Filed:
March 6, 1980
Date of Patent:
December 15, 1981
Assignees:
Linde AG, Vniigaz
Inventors:
Walter Scholz, Gerhard Ranke, Hans Becker, Boris G. Bergo, Alexander I. Grizenko, Alexej V. Frolov