Abstract: Improved silica based matting agents are disclosed. The matting agents are useful in waterborne coatings composition to provide exceptional properties to a wood based substrate. Films resulting on the coated substrate unexpectedly provide improved chemical resistance, thermal stress resistance, weather resistance, and/or film clarity to the surface of a wood substrate. Methods of making and using the matting agents are also disclosed.
Abstract: A process of producing a spherical catalyst component for use in producing polyolefin polymers includes dissolving a magnesium halide compound in a solvent to form a homogeneous solution, the solvent comprising an alcohol; and treating the homogeneous solution with a titanium compound in the presence of a surfactant, a supportive electron donor, and an internal electron donor to form a solid catalyst component comprising a magnesium halide compound base incorporating a titanium unit, the supportive electron donor, and the internal electron donor; wherein the catalyst component comprises particles having a substantially spherical shape and a D50 from about 3 ?m to about 150 ?m.
Abstract: Disclosed are catalyst compositions having an internal electron donor which includes a 3,6-di-substituted-1,2-phenylene aromatic diester. Ziegler-Natta catalyst compositions containing the present catalyst compositions exhibit very high hydrogen response, high activity, high selectivity and produce propylene-based olefins with high melt flow rate.
Type:
Grant
Filed:
December 16, 2021
Date of Patent:
May 28, 2024
Assignee:
W.R. Grace & Co.-Conn.
Inventors:
Linfeng Chen, Tak W. Leung, Tao Tao, Kuanqiang Gao
Abstract: Catalyst systems for polymerization of mixtures comprising an olefin include a selectivity control agent comprising at least one silicon-containing compound containing at least one C1-C10 alkoxy group bonded to a silicon atom and an amount of one or more agent compounds. The agent compound comprises C2-C13 mono- or polycarboxylic esters of aliphatic C2-C7 carboxylic acids and inertly substituted derivatives thereof. One or more polymerization catalysts may also be present. A polymerization process includes contacting an olefin or a mixture of the olefin and one or more copolymerizable comonomers under polymerization conditions with the catalyst composition.
Abstract: A modified zeolite catalyst composition is disclosed formed from a zeolite, alumina binder, and matrix. The modified zeolite catalyst composition may contain fluorine. Also disclosed, are methods for the preparation of pyridine and/or its alkylpyridine derivatives in high yield utilizing the modified zeolite catalyst composition.
Abstract: A stationary phase for high-performance liquid chromatography including monofunctional primary silane functionalized silica provides improved separation performance for the preparative or process scale purification of cannabidiol (CBD) and tetrahydro-cannabinol (THC). Silica bonded with monofunctional primary silane(s) provides more efficient separation of these molecules through higher resolution values, reduced peak broadening and lower separation impedance, thus enabling higher purity product or more efficient purification process.
Type:
Application
Filed:
March 9, 2022
Publication date:
May 16, 2024
Applicant:
W.R. Grace & Co.-Conn.
Inventors:
Keling ZHANG, Reno NGUYEN, Simon THOMAS
Abstract: A propylene-ethylene copolymer includes propylene as a primary monomer, an ethylene content (ET) of 3.0% to 5% by weight, a melt flow rate of from 20 to 45 g/10 min, a xylene soluble fraction (XS) of from 2.0% to 7.0% by weight, and an XS/ET ratio of less than or equal to 1.51.
Type:
Application
Filed:
December 5, 2023
Publication date:
May 9, 2024
Applicant:
W.R. GRACE & CO.-CONN.
Inventors:
Matthew Fedec, Jan Van Egmond, Manu Rego, John Kaarto, Li-Min Tau
Abstract: A Ziegler-Natta catalyst composition is disclosed. The catalyst composition includes an internal electron donor with improved polymerization kinetics, a long lifetime, improved stereoselectivity and/or improved hydrogen response.
Type:
Grant
Filed:
September 10, 2020
Date of Patent:
April 2, 2024
Assignee:
W.R. Grace & Co.-CONN.
Inventors:
Joseph Coalter, III, Rose Kent, Adam Marwitz, Ronald Epstein, Michael Elder
Abstract: Propylene and alpha olefin random copolymers are disclosed that have excellent flow characteristics. For instance, the copolymers can be formulated so as to have a melt flow rate of greater than about 45 g/10 min. While still retaining the above flow characteristics, the copolymer can also be formulated to have greater stiffness, low xylene soluble content, and excellent transparency characteristics especially when combined with one or more clarifying agents.
Type:
Grant
Filed:
June 7, 2019
Date of Patent:
February 20, 2024
Assignee:
W.R. GRACE & CO .- CONN.
Inventors:
Matthew John Fedec, Jan Willem Van Egmond, John Kalevi Kaarto, Amaia Montoya-Goni
Abstract: Olefin polymers are produced having a controlled amount of xylene soluble content. For example, polypropylene polymers can be produced having a relatively high xylene soluble content. The polymers are produced using particular external electron donors. The polymers can be produced without using a silicon-containing external electron donor.
Abstract: An activated solid catalyst component is disclosed formed from a magnesium compound, a titanium compound, an organosilicon compound, a supportive electron donor, and at least one internal electron donor. The solid catalyst component is activated to include titanium and carbon bonds by reaction with an activation agent, such as an aluminum compound. In one embodiment, small amounts of polymer are polymerized with the catalyst component during activation. The activated catalyst component is stable and, when formed, can later be used to produce various polyolefin polymers. The activated catalyst component has controlled reaction kinetics so that the catalyst does not overheat and degrade during initial polymerization.
Abstract: A polymer composition includes a low ethylene random copolymer that can be used to form a meltspun or spunbond article at high spinning velocities. The polymer composition has a low xylene soluble content, a high crystallinity, or both, while having reduced spin-break at high spinning velocities. The polymer composition also exhibits good fiber tenacity and fabric softness.
Abstract: Propylene-ethylene copolymer compositions and production methods are provided. The copolymer compositions can be particularly advantageous for use in hot fill packaging of foodstuffs. The propylene-ethylene copolymers can be produced using a Ziegler-Natta catalyst and an alkoxysilane electron donor. The compositions can have propylene as a primary monomer with an ethylene content ranging from 2.0 to 6.0 percent by weight with a xylene soluble content of less than 7.0 percent by weight.
Type:
Grant
Filed:
June 7, 2019
Date of Patent:
January 16, 2024
Assignee:
W.R. Grace & Co.-Conn.
Inventors:
Matthew John Fedec, Jan Willem Van Egmond, Manu Rego, John Kalevi Kaarto, Li-Min Tau
Abstract: Polymer compositions are disclosed that can be used to produce different types of molded articles, such as extruded piping structures. The polymer composition contains an oxidative stabilizing package. The oxidative stabilizing package contains at least one antioxidant, a nucleating agent, and an acid scavenger. The nucleating agent is a phosphate ester or a dicarboxylate metal salt. The stabilizing package of the present disclosure dramatically improves oxidation induction time.
Abstract: Olefin polymers are produced having an ultra-high melt flow rate. The olefin polymers can be used to produce meltblown fibers and meltblown webs, which can then be incorporated into protective apparel. The polyolefin polymer is produced using a Ziegler-Natta catalyst and without having to use peroxides in order to obtain the high melt flow rate.
Abstract: Phthalate-free polypropylene homopolymers and compositions incorporating the homopolymers are described. The phthalate-free polypropylene homopolymers exhibit high molecular weight as well as low XS content. Composition incorporating the phthalate-free polypropylene homopolymer can have relatively high stiffness properties. In addition, the polypropylene compositions can have good melt flow characteristics. Phthalate-free compositions including the homopolymers can be advantageously utilized in forming containers and other articles in food contacting, medical, and personal care applications.
Abstract: A process for catalytic cracking of an iron-contaminated fluid catalytic cracking (FCC) feedstock. The process may include combining a FCC catalyst, a slurry containing a magnesium compound, and an iron-contaminated FCC feedstock during a FCC process under fluid catalytic cracking conditions, thereby generating an equilibrium FCC catalyst with reduced iron poisoning. The slurry containing the magnesium compound may not contain a calcium compound.
Type:
Application
Filed:
July 7, 2021
Publication date:
August 31, 2023
Applicant:
W. R. Grace & Co.-Conn.
Inventors:
Shankhamala Kundu, Ruizhong Hu, Wu-Cheng Cheng, Michael Ziebarth
Abstract: Propylene and butene random copolymers are disclosed that have excellent stiffness properties and excellent transparency characteristics especially when combined with one or more nucleating agents. The propylene-butene copolymers can be made with different melt flow characteristics making them well suited for use in injection molding, blow molding and thermoforming applications.
Abstract: Propylene and butene random copolymers are disclosed that have excellent stiffness properties, low xylene soluble content, and excellent transparency characteristics especially when combined with one or more nucleating agents. The propylene-butene copolymers can be made with different melt flow characteristics making them well suited for use in injection molding, blow molding and thermoforming applications.
Abstract: A process for preparing a catalyst comprises coating substantial internal surfaces of porous inorganic powders with titanium oxide to form titanium oxide-coated inorganic powders. After the coating, an extrudate comprising the titanium oxide-coated inorganic powders is formed and calcined to form a catalyst support. Then, the catalyst support is impregnated with a solution containing one or more salts of metal selected from the group consisting of molybdenum, cobalt, and nickel.