Abstract: A method for treating an aqueous system which contains solid particles of iron (III) oxide is disclosed which comprises adding to the system catechol, hydroquinone, their water soluble salts, and mixtures thereof in an amount effective to disperse or suspend iron (III) oxide particles. The aqueous system should have a pH greater than 7 and have low to moderate hardness.
Abstract: Flexographic photosensitive printing plates are made with formulations comprising triblock polymers of poly(vinylpyridine)-poly(butadiene) or poly(isoprene)poly(vinylpyridine). The polymers may be quaternized. When made with quaternized polymers, the plates after imaging with UV may be developed in aqueous solutions.
Abstract: A cement admixture is disclosed which is capable of inhibiting slump loss without set retardation to hydraulic cement compositions. The admixture is composed of a mixture comprising a copolymer of maleic anhydride and an oxyalkylene containing monomer, lignosulfonic acid or its salts and an anionic surfactant.
Abstract: A method is disclosed for inhibiting or preventing the formation of scale on surfaces in contact with an aqueous system comprising adding to the system an amount effective to inhibit scale formation of a sulfonated organophosphonate compound having the formula: ##STR1## wherein n is an integer from 3 to 10 X is OH or NH.sub.2 ; and water soluble salts thereof.
Abstract: A universally applicable SiO.sub.2 -flatting agent is described, which consists of SiO.sub.2, 1 to 25% by weight polyol and optionally 1 to 25% by weight wax. The novel flatting agent is, even after lengthy storage, especially at pressure, still easily dispersible, does not lead to the formation of a hard sediment with non-thixotropic paints and lacquers, and has practically no negative effect on the thixotropic behaviour of paints and lacquers based on thixotropic polyamide-modified alkyd resins. The SiO.sub.2, polyol and wax can be brought together in a variety of ways, e.g. during the micronization of the SiO.sub.2 in a jet-mill or mechanical mill by adding polyol and wax at the same time, by spray-drying a suspension of SiO.sub.2 in an aqueous polyol solution or even before drying by adding polyol during washing or an earlier production step. It is also possible to spray-dry a suspension of SiO.sub.2, wax emulsion and polyol.
Type:
Grant
Filed:
November 1, 1991
Date of Patent:
June 22, 1993
Assignee:
W. R. Grace & Co.-Conn.
Inventors:
Georg Luers, Gerd W. Scheuren, Heiko Zeh
Abstract: V-groovable gravure printable paper having the machinability of vinyl and the printability of paper, and a process for manufacturing such a product. A smooth, saturated only paper is subjected to heavy calendering during processing in order to provide adequate smoothness as required by printers. The paper is saturated with an acrylic/PVC blend designed to give good "miter-fold" strength, good smoothness and adequate adhesive anchorage. The saturant also allows the ink types used on vinyl films to adhere to the paper, and exhibits good stain resistance.
Abstract: A lead/sulphuric acid storage battery with negative and positive electrode plates, between which plastics microporous separators or glass-fiber separators are arranged, comprises un-crosslinked natural or synthetic rubber to combat antimony poisoning in the battery. The rubber is preferably in the form of a layer comprising un-crosslinked natural or synthetic rubber or is incorporated into a carrier layer on the separators, on the side facing the negative electrode plate. Alternatively, the un-crosslinked natural or synthetic rubber can be incorporated into the separator sheet or into the negative electrode plate. The deposition of the rubber as a coating onto the inner walls of the battery box is also possible.
Abstract: Polymeric, oriented films can be made by the use of a combination of a hot blown process and a blown bubble process. Styrene butadiene copolymer (SBC) forms two outer layers of the preferred embodiment, with a core layer of very low density polyethylene (VLDPE) or blends thereof, and intermediate polymeric adhesive layers such as ethylene vinyl acetate copolymer (EVA) bonding the core layer to the outer layers. A monoaxially or biaxially oriented film is produced with excellent optics.
Type:
Grant
Filed:
February 26, 1992
Date of Patent:
June 15, 1993
Assignee:
W.R. Grace & Co.-Conn.
Inventors:
Henry G. Schirmer, Stephen F. Compton, Martin Nelson
Abstract: Superconductors having a composition Bi.sub.2-a-b-c Sn.sub.a Pb.sub.b Sb.sub.c Sr.sub.2 Ca.sub.n-1 Cu.sub.n O.sub.2n+4 can be made by firing the appropriate mixtures of designated oxides or carbonates. In the composition a=about 0.001-0.4, b about 0-0.4, c about 0-0.4, and n 2 or 3. The addition of Sn improves the superconductive properties of comparable compositions that lack Sn. For example, Bi.sub.1.6 Sn.sub.0.4 Sr.sub.2 Ca.sub.2 Cu.sub.3 O.sub.x (x=ca 10), calcined at 830.degree. C. for 15 hours shows superconductivity by magnetic susceptibility tests at about 77.degree. K. whereas Bi.sub.2 Sr.sub.2 Ca.sub.2 Cu.sub.3 O.sub.10 prepared under the same conditions but lacking Sn, shows nothing at this temperature.
Abstract: An epoxy composition suitable for adhesives, coatings and sealants is prepared from (a) at least one reaction product of an epoxy and amine-capped oligomer, (b) an epoxy adduct of dimer acid, (c) dicyandiamide and (d) a catalyst which yields a dimethyl amine radical upon being heated. When the epoxy composition is cured, it exhibits two glass transition temperatures and good adhesion properties at and below room temperature. The epoxy is particularly suitable for adhesives used in the manufacturing of automobiles.
Abstract: A method of reclaiming unset cement compositions by mixing a polymethoxy polyphosphonate to the unset composition to cause long-term retardation of cement hydration and subsequently treating the composition with a set accelerator to reinitiate hydration.
Type:
Grant
Filed:
October 25, 1991
Date of Patent:
June 1, 1993
Assignee:
W. R. Grace & Co.-Conn.
Inventors:
Narender P. Luthra, Charles G. Carter, Paul C. Scheiner
Abstract: Hot and cold heat seals are obtained in a multiple layer cook-in film from which packages such as bags or casings can be made wherein the films have a first food contact layer that adheres during cook-in to a contained meat product and wherein the first layer comprises a blend of a first and a second polyamide, preferably with a small amount of an antioxidant.
Abstract: The disclosure herein describes a bovine embryo culture medium which includes epithelial cells from the oviduct of a donor animal. Additionally, a process for maturing immature bovine oocytes in an in vitro bovine culture medium containing epithelial cells from a donor oviduct is described. As an alternative to co-culture of the embryos with the epithelial cells, it is described how a culture medium can be conditioned for the culture of bovine embryos by the culture of epithelial cells therein which are later removed.
Abstract: An enclosure suitable for enclosing aerial cable splices comprises an elongate generally cylindrical housing comprising a first, second, and third member, a first elongate hinge connecting the first and second members together, a second elongate hinge connecting the second and third members together, at least one female boss disposed on an outside surface of each of the first and third members, and at least one male boss disposed on an outside surface of the second member such that the first and third members can be releasably locked in an open position by means of the respective bosses.
Abstract: A method of initiating oxygen scavenging by compositions which comprise oxidizable organic compounds and transition metal catalysts is disclosed. The method comprises initiating scavenging by exposing the composition, etc., to radiation. The radiation exposure is preferably electron beam or ultraviolet light and is preferably used on oxygen scavenging compositions which comprise a substituted or unsubstituted ethylenically unsaturated hydrocarbon and a transition metal catalyst. Inclusion of a photoinitiator or antioxidant in the scavenging composition is also preferred to facilitate and/or control the composition's scavenging properties. The method can be used for initiating scavenging in packaging layers or articles for oxygen sensitive products such as food and beverage.
Type:
Grant
Filed:
June 27, 1991
Date of Patent:
May 18, 1993
Assignee:
W. R. Grace & Co.-Conn.
Inventors:
Drew V. Speer, William P. Roberts, Charles R. Morgan
Abstract: New set-accelerating admixtures for hydraulic cement compositions are disclosed. These admixtures incorporate set-accelerating compounds and methylol derivatives of amino acids, are found to be surprisingly effective in decreasing the initial set time of hydraulic cements, mortars, and concretes, and are particularly advantageous in reduced-temperature set-accelerators.
Type:
Grant
Filed:
February 28, 1992
Date of Patent:
May 18, 1993
Assignee:
W.R. Grace & Co.-Conn.
Inventors:
Ahmad Arfaei, Leslie A. Jardine, Ara Jeknavorian
Abstract: The present invention overcomes the problems caused by certain intergranular phases present during hot pressing. The invention provides a method of removing such problematic intergranular phases while avoiding problems of non-uniformity. In one aspect, the invention encompasses an improvement in a method of sintering a green body by hot pressing, where the green body contains ceramic grains to be sintered and material capable of existing as intergranular phase material during sintering. The improvement embraces hot pressing the body in the presence of a permeable material adapted to receive at least a portion of intergranular phase material as the sintering takes place or after the sintering has been completed.
Abstract: The invention provides a control system and method for curing composite articles such as corrugated fiberglass resin plastic (FRP) panels. An exemplary system of the invention includes a curing oven, at least one infrared pyrometer sensor which is located within the oven curing zone and which provides an output indicating the temperature of the resin being cured, a tractor unit for moving the panel through the oven, and a comparator circuit which adjusts the speed of the tractor unit in predetermined response to sensor output. The invention thereby provides for the detection of the peak temperature or gelation point of resin in the panel, and allows its specific location in the oven to be controlled to optimize the performance and efficiency of the panel production line.
Abstract: A water-based silicon nitride powder extrusion mixture is prepared. The mixture also contains oleic acid, glycerin, methyl cellulose and a polyacrylic acid-containing polymer. The mixture can be extruded at ambient temperatures. The extrudate can be dried at low temperature and sintered to form a dense silicon nitride part.
Abstract: A compact efficient air flotation dryer with a built-in afterburner for combustion of solvent-laden air within a dryer-enclosed combustion chamber. An internal exhaust fan propels internal solvent-laden air across a burner where it combusts, causing a heat rise. Heated, combusted air is routed to a recirculating supply air fan which provides for pressurized heated air for air bars for drying a web. Heated air in excess of that required to dry the web is vented externally and helps to maintain desired solvent concentration levels Variable parameters such as fan speed, burner temperatures, air box pressures, exhaust air rate, solvent concentration, supply air flow, supply air temperature and damper vane position are monitored, and the components are actuated to effect a high level of clean up efficiency.
Type:
Grant
Filed:
October 31, 1990
Date of Patent:
May 4, 1993
Assignee:
W. R. Grace & Co.-Conn.
Inventors:
Richard J. Wimberger, Richard A. Carman