Abstract: The invention provides a process for laminating textile sheet materials onto moldable foam or onto foamed moldings, using, as an adhesive, a polymer preparation based on copolymers of one or more monomers selected from the group comprising vinyl esters, acrylates, methacrylates, vinylaromatics and vinyl chloride and from 0.01 to 25% by weight, based on the total weight of the copolymer, of one or more ethylenically unsaturated monomers containing carboxyl groups.
Type:
Application
Filed:
February 26, 2002
Publication date:
August 1, 2002
Applicant:
Wacker Polymer Systems GmbH & Co. KG
Inventors:
Klaus Kolhammer, Claudia Schmidt, Abdulmajid Hashemzadeh, Doris Bauer
Abstract: A process for reducing the odor emission of aqueous vinylaromatic/1,3-diene copolymer dispersions and of redispersion powders obtainable therefrom by drying, is by emulsion polymerization of a mixture containing at least one vinylaromatic and at least one 1,3-diene in the presence of one or more surfactant substances and optionally drying of the polymer dispersion obtained thereby. There are 0.01% to 15.0% by weight of one or more monomers of the branched or straight-chain alkyl esters having 1 to 8 C atoms in the alkyl radical of monounsaturated monocarboxylic or dicarboxylic acids and 0.01% to 15.0% by weight of one or more monomers based upon the vinyl esters of branched or straight-chain aliphatic carboxylic acids having 1 to 10 C atoms which are added in one step or in two successive steps toward the end of the polymerization, when the total content of free monomers in the aqueous copolymer dispersion is in the range from ≧0 to ≦20% by weight.
Abstract: The invention relates to a process for producing wood fiberboard by pressing wood fibers which have been treated with binder, in which the wood fibers are boiled and milled at elevated temperature under steam pressure in a refiner unit, subsequently are transferred to a blow-line, then dried and finally pressed under pressure and, if desired, at elevated temperature to produce boards, wherein the treatment with binder is carried out using a multi-component binder, preferably with one component A) containing functional groups which are nonreactive at elevated temperature and a second component B) containing functional groups which are reactive at elevated temperature the component A) being added in the refiner unit at a temperature of from 120° C. to 200° C. prior to the milling step, during the milling step, or shortly after the milling step in the front section of the blow-line and component B) being added at a lower temperature of not more than 150° C.
Type:
Application
Filed:
October 31, 2001
Publication date:
June 20, 2002
Applicant:
Wacker Polymer Systems GmbH & Co. KG
Inventors:
Konrad Alfons Wierer, Abdulmajid Hashemzadeh, Klaus Marquardt
Abstract: The invention relates to a process for producing wood particleboard, in which wood particles, if appropriate after a preceding comminution step, are treated with a crosslinkable binder and are subsequently pressed together under pressure and, if desired, elevated temperature to produce boards, wherein the thermoplastic binder comprises two constituents A) and B), where A) is a copolymer comprising one or more comonomer units selected from the group consisting of vinyl esters of unbranched or branched alkylcarboxylic acids having from 1 to 18 carbon atoms, acrylic esters or methacrylic esters of branched or unbranched alcohols having from 1 to 15 carbon atoms, dienes, olefins, vinylaromatics and vinyl halides, and from 0.
Type:
Application
Filed:
October 31, 2001
Publication date:
June 20, 2002
Applicant:
Wacker Polymer Systems GmbH & Co. KG
Inventors:
Konrad Alfons Wierer, Abdulmajid Hashemzadeh, Klaus Marquardt
Abstract: A process for preparing two-phase polymers based on vinyl ester and ethylene in the form of their aqueous polymer dispersions or water-redispersible polymer powders by means of free-radical initiated emulsion or suspension polymerization of one or more vinyl esters of carboxylic acids having 1 to 12 carbon atoms and ethylene as monomers and, if desired, further monomers copolymerizable therewith, in the presence of one or more protective colloids and/or emulsifiers and, if desired, drying the resultant aqueous polymer dispersion, wherein a first polymerization phase takes place at a low ethylene pressure of P less than or equat to 20 bar and in a second polymerization phase raising the pressure to a level of greater than 20 bar to less than 60 bar, the polymer product having an ethylene distribution of less than or equal to 50% by weight of total ethylene from the first polymerization phase and greater than 50% by weight ethylene from the second polymerization phase.
Abstract: A process for preparing copolymers based on vinyl esters and ethylene and, if desired, further comonomers in the form of their aqueous dispersions, having a solids content of greater than 65% and a Brookfield viscosity (20 s−1) of less than 10,000 mPa·s, by means of free-radically initiated polymerization of one or more monomers selected from vinyl esters and ethylene and, if desired, further monomers copolymerizable therewith, in the presence of one or more protective colloids, polymerization being conducted in the presence of from 2 to 15% by weight of seed latex, based on the amount of vinyl ester, said process comprising
Abstract: A process for the preparation of vinylaromatic copolymer redispersion powders redispersible in water is by free-radical emulsion polymerization of a comonomer mixture including
(a) one or more vinylaromatic comonomers,
(b) one or more 1,3-diene comonomers (b1) or one or more comonomers (b2) from the group including the alkyl esters having 1 to 8 C atoms of acrylic acid or methacrylic acid and
(c) 0.1 to 10% by weight, based on the total weight of the comonomer mixture, of one or more comonomers from the group including the ethylenically unsaturated mono- or dicarboxylic acids or the anhydrides thereof, the ethylenically unsaturated carboxamides, the ethylenically unsaturated sulfonic acid compounds and in each case the salts thereof,
and drying of the aqueous copolymer dispersion obtainable thereby.
Abstract: The present invention provides a crosslinkable polymer composition in the form of its aqueous polymer dispersion or polymer powder, including A) a copolymer having a glass transition temperature Tg or a melting temperature of ≧30° C. and containing units derived from one or more comonomers selected from the group consisting of vinyl esters of branched or unbranched alkylcarboxylic acids of 1 to 18 carbon atoms, acrylic esters or methacrylic esters of branched or unbranched alcohols of 1 to 15 carbon atoms, dienes, olefins, vinyl aromatics and vinyl halides and from 0.
Type:
Application
Filed:
March 12, 2001
Publication date:
October 25, 2001
Applicant:
Wacker Polymer System GmbH & Co. KG
Inventors:
Klaus Kohlhammer, Abdulmajid Hashemzadeh
Abstract: The invention discloses polyvinyl alcohol-stabilized copolymers of 1,3-dienes with methacrylates and/or acrylates in the form of their aqueous polymer dispersions or polymer powders redispersible in water, and to a process for their preparation and their use.