Abstract: The invention provides an electrode comprising a substrate and a coating on the substrate. The coating comprises a plurality of layers, including the following layers in sequence moving outwardly from the substrate: a base layer comprising an oxide of a valve metal; a lower layer comprising an oxide of a platinum group metal and/or an oxide of a precious metal; and a mixed oxide primary layer comprising both: (i) an oxide of a platinum group metal and/or an oxide of a precious metal, and (ii) an oxide of a valve metal and/or an oxide of a group 15 metal. The base layer is devoid of any platinum group metal oxide, and the lower layer is devoid of any valve metal oxide. The present invention also provides methods of manufacturing such electrodes. Also provide are methods of using an electrochemical cell equipped with a certain multilayer coated electrode.

Abstract: A point of use electrolysis system can be used to generate oxidizing species within liquid retained by a point of use discharge nozzle, helping to prevent pathogens from growing and multiplying in the nozzle. In one example, a system includes a point of use discharge nozzle having an inlet and an outlet and electrodes. The electrodes are configured to electrochemically generate an oxidizing species within the point of use discharge nozzle. According to the example, the point of use discharge nozzle is configured to trap liquid from a liquid source, when liquid ceases flowing through the point of use discharge nozzle, thereby providing a trapped liquid. Further, the electrodes are configured to generate the oxidizing species within the trapped liquid.

Abstract: Dissolved oxygen may be generated by adding a peroxide to a fluid stream and then catalytically decomposing the peroxide to generate oxygen. As the peroxide is catalytically decomposed, the oxygen may solubilize in a surrounding fluid so as to provide dissolved oxygen. In some examples, the amount of peroxide added to the fluid stream is controlled such that substantially all of the hydrogen peroxide added to the fluid stream catalytically decomposes and yet the dissolved oxygen concentration of the fluid stream does not exceed a dissolved oxygen saturation limit for the fluid stream.

Abstract: Dissolved oxygen may be generated by adding a peroxide to a fluid stream and then catalytically decomposing the peroxide to generate oxygen. As the peroxide is catalytically decomposed, the oxygen may solubilize in a surrounding fluid so as to provide dissolved oxygen. In some examples, the amount of peroxide added to the fluid stream is controlled such that substantially all of the hydrogen peroxide added to the fluid stream catalytically decomposes and yet the dissolved oxygen concentration of the fluid stream does not exceed a dissolved oxygen saturation limit for the fluid stream.

Abstract: A composition and method of manufacture of electrodes having controlled electrochemical activity to allow the electrodes to be designed for a variety of electro-oxidation processes. The electrodes are comprised of a compact coating deposited onto a conductive substrate, the coating being formed as multiple layers of a mixture of one or more platinum group metal oxides and one or more valve metal oxides. The formation of multiple layers allows the concentrations of platinum group metal and valve metal to be varied for each layer as desired for an application. For example, an electrode structure can be manufactured for use as an anode in electroplating processes, such that the oxidation of the organic additives in the electrolyte is markedly inhibited. Another electrode can be manufactured to operate at high anodic potentials in aqueous electrolytes to generate strong oxidants, e.g., hydrogen peroxide or ozone.

Abstract: High concentrations of hypochlorous acid can be produced from, most typically, brine using an system of simple design with minimum residual salt production, reduced power consumption, and at high operating efficiencies. This is accomplished by separating the system into two operations, each of which is preferably optimized. This process employs at least two electrochemical cells, the first of which has no separator between the anode and cathode and generates a high-strength hypochlorite solution. The hypochlorite is then diluted to a desired chlorine concentration and/or pH and fed into the anode compartment of a second electrochemical cell wherein the electrodes are separated by a barrier, such as, for example, a membrane or diaphragm. The separated cell produces a solution containing predominantly hypochlorous acid.