Abstract: A device for converting carbon dioxide in flue gas into natural gas using dump energy. The device includes a transformer and rectifier device, an electrolytic cell, a turbine, a carbon dioxide heater, a primary fixed bed reactor, a secondary fixed bed reactor, a natural gas condenser, and a process water line. An outlet of the transformer and rectifier device is connected to a power interface of the electrolytic cell, a gas-liquid outlet of a cathode of the electrolytic cell is connected to a gas-liquid inlet of a hydrogen separator, and a liquid outlet of the hydrogen separator is connected to a liquid reflux port of the cathode of the electrolytic cell.

Abstract: A catalyst for methanation of carbon dioxide, a method of preparing the catalyst, and a method of hydrogenating carbon dioxide in the presence of the catalyst in a fixed bed reactor are disclosed. The catalyst is formed by mixing ash from a biomass power plant with a nickel compound and calcining the resulting mixture. The catalyst formed by calcination includes between 2 and 20 wt. % of nickel supported on ash from combusting biomass.

Abstract: A microwave plasma based entrained flow gasifier of biomass, including a furnace body and a fuel pretreatment system. The furnace body includes a fuel inlet disposed at the lower part of the furnace body, a syngas outlet disposed at the top of the furnace body, and a slag outlet disposed at the bottom of the furnace body. The fuel inlet presents in the form of nozzles. The fuel pretreatment system is disposed outside of the furnace body, and includes a fuel crushing apparatus, a sieving apparatus disposed downstream to the fuel crushing apparatus, a first fuel container for receiving particle size-qualified fuel, a second fuel container for receiving particle size-unqualified fuel, and a feeding hopper disposed downstream to the first fuel container. The first fuel container and the second fuel container are disposed side-by-side downstream to the sieving apparatus.

Abstract: A method for recycling carbon dioxide from biomass gasification. The method includes: 1) employing carbon dioxide as a gasifying agent, allowing the carbon dioxide to gasify biomass to yield syngas; 2) cooling the syngas; 3) introduced cooled syngas to a cyclone separator and a gas scrubber for dust removal and purification; 4) allowing purified syngas in 3) to react with the vapor to modify a ratio of hydrogen to carbon monoxide of the syngas; 5) desulfurizing modified syngas to remove H2S and COS therein; 6) decarburizing desulfurized syngas to separate carbon dioxide therein; 7) introducing desulfurized and decarburized syngas to a synthesizing tower to yield oil products and exhaust gas including carbon dioxide; 8) decarburizing the exhaust gas including carbon dioxide and separating the carbon dioxide; and 9) introducing the carbon dioxide separated in 6) and 8) to 1) as the gasifying agent for gasification.

Abstract: A method for purifying biomass syngas, including: a) introducing syngas out of a gasifier, through a water-cooling flue to a water-cooling quench tower; b) introducing the syngas from the water-cooling quench tower to a waste heat boiler of a water-tube type and a waste heat boiler of a heat-tube type; c) washing the syngas from the waste heat boiler of the heat-tube type in a Venturi scrubber in the absence of a filler to remove dust; d) introducing the syngas from the Venturi scrubber to a wet electrical dust precipitator for conducting dust removal and tar mist removal; and e) extracting the syngas by a coal gas draft fan, and transporting the syngas to a wet gas tank for storage or to a downstream process for use.

Abstract: A method for cooling and washing biomass syngas, the method including the following steps: 1) introducing biomass syngas having a temperature of between 1000 and 1100° C., a dust content of less than 20 g/Nm3, and a tar content of less than 3 g/Nm3 to a quench tower for condensing a slag; 2) introducing the biomass syngas after slag condensation to a waste heat boiler for recovering waste heat and condensing a heavy tar in the syngas; 3) introducing the biomass syngas from the waste heat boiler to a scrubbing-cooling tower for removing dust and decreasing a temperature of the syngas; and 4) introducing the biomass syngas after dust removal and temperature decrease from the scrubbing-cooling tower to an electro-precipitator for further removal of the dust and the tar.

Abstract: A method of gasification of biomass using a gasification island. The gasification island includes: a biomass pre-treatment and storage unit, a biomass feeder, an external heat source, a gasifier, a crude syngas cooling unit, a crude syngas washing unit, a fresh syngas storage unit, and an ash and wastewater treatment unit. The method includes: pre-treating and storing biomass, gasifying the biomass in the gasifier, cooling a crude syngas, washing and removing dust from the crude syngas, and storing fresh syngas.

Abstract: A method for preparation of amorphous silica from biomass. The method includes pyrolyzing the biomass under anaerobic conditions to yield a pyrolysis gas and solid residues, collecting the pyrolysis gas, and calcining the solid residues under aerobic conditions to yield amorphous silica.

Abstract: A catalyst for methanation of carbon dioxide. The catalyst is formed by mixing ash from a biomass power plant with a nickel compound and calcining the resulting mixture. The catalyst formed by calcination includes between 2 and 20 wt. % of nickel.

Abstract: A method for recycling exhaust gas from Fischer-Tropsch synthesis. The method includes: 1) introducing raw gas to a shift reactor to conduct a water-gas shift reaction, and collecting shift gas; 2) introducing the shift gas to a Fischer-Tropsch synthesis device to yield a hydrocarbon fuel and exhaust gas, returning part of the exhaust gas as recycle gas; 3) introducing another part of the exhaust gas to a methanation reactor, allowing a methanation reaction to happen between the part of the exhaust gas and water vapor; 4) introducing a mixed gas product from the methanation reaction to a methane reforming reactor; 5) transporting the hydrogen and carbon monoxide resulting from the methane reforming reaction to a gas separator, separating the hydrogen and obtaining a mixed gas including carbon dioxide; and 6) returning the mixed gas including carbon dioxide to the methane reforming reactor.

Abstract: A cobalt-based nano catalyst including a metal combination as a core and a porous material as a shell. The metal combination includes a first metal component Co, a second metal component selected from Ce, La, and Zr, and a third metal component selected from Pt, Ru, Rh, and Re. The catalyst includes between 10 and 35 wt. % of the first metal component, between 0.5 and 10 wt. % of the second metal component, between 0.02 and 2 wt. % of the third metal component, and a carrier. The carrier is a porous material such as nano silica or alumina. The carrier is in the shape of a spheroid, has a pore size of between 1 and 20 nm and a specific area of between 300 and 500 m2/g. The active component of the catalyst has a particle size of between 0.5 and 20 nm.

Abstract: A method for preparing a liquid hydrocarbon from syngas. The method includes: 1) mixing crude syngas from a biomass gasifier and a hydrogen-rich gas to yield a mixed gas; 2) dehydrating and decarbonizing the mixed gas for removal of moisture, carbon dioxide, and impurities, to yield a fine syngas; 3) introducing the fine syngas to a Fischer-Tropsch synthesis device in the presence of a catalyst, controlling a reaction temperature of the Fischer-Tropsch synthesis at between 150 and 300° C. and a reaction pressure of between 2 and 4 MPa (A), to yield a liquid hydrocarbon and water which is discharged out of the Fischer-Tropsch synthesis device; and 4) returning 70-95 vol. % of exhaust gases from the Fischer-Tropsch synthesis device to step 3) to mix with the fine syngas, and introducing the resulting mixed gas to the Fischer-Tropsch synthesis device.

Abstract: A method for improving Fischer-Tropsch synthesis and recycling exhaust gases therefrom. The method includes: 1) transforming raw gas for Fischer-Tropsch synthesis using a water-gas shift reaction, transporting the transformed raw gas to a Fischer-Tropsch synthesis device for Fischer-Tropsch synthesis in the presence of a Fe-based or Co-based catalyst; 2) introducing exhaust gases from the Fischer-Tropsch synthesis device to a first pressure-swing adsorber for hydrogen recovery; 3) introducing the exhaust gases from 2) to a second pressure-swing adsorber for methane recovery; 4) returning part of the hydrogen obtained from 2) to 1) to mix with the raw gas, and transforming a resulting mixed gas to adjust a hydrogen/carbon ratio of the raw gas; and 5) introducing the methane in 3) to a methane reforming device to reform the methane whereby yielding syngas having relatively high hydrogen/carbon ratio, and transporting the syngas to 1) to mix with the raw gas.

Abstract: A method for producing synthesis gas, including: 1) pre-processing a biomass raw material; 2) pyrolyzing the biomass raw material to yield a pyrolysis gas and a carbon powder; 3) separating the pyrolysis gas from the carbon powder and a solid heat carrier; 4) separating the carbon powder away from the solid heat carrier via a solid-solid separator; 5) conveying the generated pyrolysis gas to a condensate tank for spray condensation, condensing a condensable part in the pyrolysis gas to generate biological fuel oil, pressurizing the generated biological fuel oil by a high pressure oil pump and feeding to a gasification furnace to be gasified; and 6) feeding one part of non-condensable pyrolysis gas to a combustion bed to combust with air, and conveying the other part of the non-condensable pyrolysis gas to the pyrolysis bed as a fluidizing medium.

Abstract: A high capacity polymer hydrogen storage material, including a linear high molecular polymer as a main chain. At least one side chain or a terminal group of the linear high molecular polymer is first aminated using a polyamine compound and then reacts with a borohydride to yield an ammonia borane derivative grafted to the side chain or the terminal group of the linear high molecular polymer.

Abstract: A method for converting carbon dioxide in flue gas into natural gas using dump energy. The method includes: 1) transforming and rectifying a voltage of dump energy generated from a renewable energy plant, introducing the voltage-transformed and rectified dump energy into an electrolyte solution to electrolyze water therein to yield H2 and O2; 2) purifying industrial flue gas to separate CO2 therein and purifying CO2; 3) transporting H2 generated and CO2 to a synthesis equipment, allowing a methanation reaction between H2 and CO2 to happen to yield a high-temperature mixed gas with main ingredients of CH4 and water vapor; 4) employing the high-temperature mixed gas to conduct indirect heat exchange with process water to yield superheated water vapor; 5) delivering the superheated water vapor to a turbine to generate electric energy, and returning the electric energy to step 1); and 6) condensing and drying the mixed gas.

Abstract: A dish-type Stirling solar generator capable of running continuously day and night, including a dish-type Stirling solar generating set. The dish-type Stirling solar generating set includes a combustor, a position adjustment mechanism, and a bracket. The combustor includes an opening. The position adjustment mechanism is capable of adjusting the opening of the combustor to align or deviate from a heat receiver of the dish-type Stirling solar generating set. The position adjustment mechanism is disposed on the bracket of the dish-type Stirling solar generating set. The combustor is disposed on the position adjustment mechanism. A fuel supply system of the combustor is connected to the combustor via a main switch valve, a branch switch valve, a regulating valve, and a flexible conveying pipe.

Abstract: A method of power generation, including: igniting a biomass boiler; starting a solar concentrating collector; measuring water temperature t3 at water outlet main of the solar concentrating collector; opening a second control valve arranged between the water outlet main and the boiler drum when t3 is greater or equal to 95° C.; closing the second control valve and the third control valve to prevent water in the solar collector tube from running and to maintain the water in a heat preserving and inactive state if the water temperature t3 decreases and t3 is less than 95° C.; turning the turbonator unit into a thermal power generation mode; opening a first control valve arranged between the water outlet main and a water supply tank if the water temperature t3 continues decreasing and when t3 is between 5 and 9° C.; and turning the turbonator unit into a biomass boiler power generation mode.

Abstract: A method for preparing surface-modified nano silicon dioxide from rice hulls. The method includes: 1) pretreating rice hulls using a treating gas containing CO2 to remove metal ions, impurities, and dusts, and desiccating and grinding the rice hulls; 2) submerging the rice hulls into a dilute solution of phosphoric acid, boric acid, hydrochloric acid, formic acid, acetic acid, propionic acid, butyric acid, or a strong-acid-weak-base salt for between 4 and 8 hrs, controlling the immersion temperature not to exceed 10° C., leaching a resulting mixture, removing a filtrate, and desiccating the rice hulls; and 3) calcining the rice hulls in the absence of oxygen at a temperature of between 300 and 450° C.

Abstract: A method for preparing crystalline cobalt nitrate. The method includes: 1) calcining a spent Co/SiO2 catalyst, cooling the calcined material to room temperature, and grinding it to yield a powder; 2) heating the powder in a fluidized bed reactor; 3) adding the heated powder into excess dilute nitric acid solution and filtering to obtain a cobalt nitrate solution; 4) adjusting the pH value of the cobalt nitrate solution to 1.5, adding a preheated oxalic acid solution, adjusting a pH value of the resulting solution to 1.5, immediately filtering the resulting solution to yield a precipitate of cobalt oxalate, washing the precipitate of cobalt oxalate to yield a neutral filtrate; 5) drying the precipitate and calcining to yield cobalt oxide; 6) dissolving the cobalt oxide in nitric acid to yield a second cobalt nitrate solution; and 7) evaporating the second cobalt nitrate solution to obtain crystalline cobalt nitrate.