Abstract: A chromium-free insulation coating composition includes 100 parts by weight of a phosphate solution, 1-5 parts by weight of molybdate, 50-150 parts by weight of silica sol, 3-13 parts by weight of selenium dioxide, 1-10 parts by weight of metal oxide and/or metal hydroxide, 5-15 parts by weight of organic acid, 1-6 parts by weight of boric acid, and 100-300 parts by weight of water.