Patents Assigned to Yamamoto Chemicals, Incorporated
  • Patent number: 5876820
    Abstract: An optical information recording medium is here disclosed which comprises a transparent substrate, a recording layer comprising an organic dyestuff on which information can be written by a laser beam, a reflective layer and a protective layer formed in this order on the substrate, the aforesaid optical information recording medium being characterized by containing a pit.multidot.edge control agent for the formation of recording pits, particularly a dyestuff thermal decomposition accelerator in the recording layer. By the addition of the pit.multidot.edge control agent, deviation properties and jitter properties can be remarkably improved, whereby a CD-R medium having a low error rate and good recording properties can be provided. In consequence, stable compatibility with a commercial CD player can be secured.
    Type: Grant
    Filed: November 9, 1995
    Date of Patent: March 2, 1999
    Assignees: Mitsui Chemicals, Inc., Yamamoto Chemicals, Incorporated
    Inventors: Tadashi Koike, Hideki Umehara, Yuji Inatomi, Takeshi Tsuda, Sumio Hirose
  • Patent number: 5695911
    Abstract: Phthalocyanine compounds represented by the below-described formula are suitable for use in the fabrication of color filters. ##STR1## wherein R.sup.1, R.sup.4, R.sup.5, R.sup.8, R.sup.9, R.sup.12, R.sup.13 and R.sup.16 represent a group represented by the below-described formula, H or a halogen atom, R.sup.2, R.sup.3, R.sup.6, R.sup.7, R.sup.10, R.sup.11, R.sup.14 and R.sup.15 represent an alkyl, alkoxyl, alkylthio, alkylamino, dialkylamino or aryloxyl, arylthio group or --COOR.sup.17, R.sup.17 being a particular monovalent group, H or a halogen atom; and Met represents a metal atom. ##STR2## wherein X and Z represent O or S, R.sup.18, R.sup.19 and R.sup.20 represent H or an alkyl group, A, B and D represent a connecting group, n and l is an integer of 0-10, m, q, t, u, r and w are an integer of 0-2, and p is 0 or 1.
    Type: Grant
    Filed: November 17, 1995
    Date of Patent: December 9, 1997
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Hisato Itoh, Akio Karasawa, Kenichi Sugimoto, Takahisa Oguchi, Shin Aihara
  • Patent number: 5582774
    Abstract: Near-infrared absorbers which contain phthalocyanine derivatives in which the four benzene rings contained in the molecule independently have 1 to 4 substituents are light and thermal resistant and possess high molar extinction coefficients. Such near-infrared absorbers are useful in optical recording media, near-infrared absorption filters, and liquid crystal display devices.
    Type: Grant
    Filed: February 26, 1991
    Date of Patent: December 10, 1996
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Hisato Itoh, Katashi Enomoto, Takahisa Oguchi, Tsutomu Nishizawa
  • Patent number: 5492744
    Abstract: An optical information recording medium is here disclosed which comprises a transparent substrate, a recording layer comprising an organic dyestuff on which information can be written by a laser beam, a reflective layer and a protective layer formed in this order on the substrate, the aforesaid optical information recording medium being characterized by containing a pit.edge control agent for the formation of recording pits, particularly a dyestuff thermal decomposition accelerator in the recording layer. By the addition of the pit.edge control agent, deviation properties and jitter properties can be remarkably improved, whereby a CD-R medium having a low error rate and good recording properties can be provided. In consequence, stable compatibility with a commercial CD player can be secured.
    Type: Grant
    Filed: December 1, 1993
    Date of Patent: February 20, 1996
    Assignees: Mitsui Toatsu Chemicals Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Tadashi Koike, Hideki Umehara, Yuji Inatomi, Takeshi Tsuda, Sumio Hirose
  • Patent number: 5449587
    Abstract: The invention discloses a CD-WO type optical recording medium which has a constitution obtained by successively laminating a recording layer, a metal reflection layer and a protective layer; is prepared by using in the recording layer a colorant having a melting point of 150.degree. to 300.degree. C., decomposition initiating temperature of 200.degree. to 350.degree. C., and .lambda. max of 720 nm; and has high sensitivity, low recording distortion and high durability. The colorant can be enhanced its effect by introducing halogen atoms.
    Type: Grant
    Filed: February 7, 1994
    Date of Patent: September 12, 1995
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Hisato Itoh, Takahisa Oguchi, Katashi Enomoto, Tsutomu Nishizawa
  • Patent number: 5446141
    Abstract: Near-infrared absorbers which contain phthalocyanine derivatives in which the four benzene rings contained in the molecule independently have 1 to 4 substituents are light and thermal resistant and possess high molar extinction coefficients. Such near-infrared absorbers are useful in optical recording media, near-infrared absorption filters, and liquid crystal display devices.
    Type: Grant
    Filed: September 17, 1992
    Date of Patent: August 29, 1995
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Hisato Itoh, Katashi Enomoto, Takahisa Oguchi, Tsutomu Nishizawa
  • Patent number: 5409634
    Abstract: Near infrared absorbers which have a molecular extinction coefficient of 200,000 or more and are represented by the formula (I) ##STR1## wherein each of Y.sup.1, Y.sup.2, Y.sup.3, Y.sup.4, Y.sup.5, Y.sup.6, Y.sup.7 and Y.sup.8 is hydrogen, an alkyl group, alkoxyl group or alkylthio group; each of A.sup.1, A.sup.2, A.sup.3, A.sup.4, A.sup.5, A.sup.6, A.sup.7 and A.sup.8 is hydrogen, halogen, a nitro group, alkyl group, aralkyl group, alkenyl group, alkynyl group, alkoxyl group, aryloxy group, alkylthio group or arylthio group; and Met represents two hydrogen atoms or a metal, are useful for the production of optical display and recording materials.
    Type: Grant
    Filed: December 11, 1991
    Date of Patent: April 25, 1995
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Hisato Itoh, Katashi Enomoto, Takahisa Oguchi, Tutomu Nishizawa
  • Patent number: 5387678
    Abstract: Halogenated alkoxyphthalocyanine having a controlled grade of halogenation can be prepared by reacting a single compound or a mixture of phthalocyanine represented by the formula (1): ##STR1## wherein R.sup.1 is a substituted or unsubstituted alkyl group and may be the same or different, and Met is two hydrogen atoms, a divalent metal atom or a trivalent or tetravalent metal derivative, with 1 to 6 mole ratio of a halogenating agent at 0.degree. to 260.degree. C. in a solvent of from 1 to 1000 times by weight.
    Type: Grant
    Filed: June 3, 1993
    Date of Patent: February 7, 1995
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Hisato Itoh, Takahisa Oguchi, Shin Aihara
  • Patent number: 5380842
    Abstract: Phthalocyanine compounds represented by the below-described formula are suitable for use in the fabrication of color filters. ##STR1## wherein R.sup.1, R.sup.4, R.sup.5, R.sup.8, R.sup.9, R.sup.12, R.sup.13 and R.sup.16 represent a group represented by the below-described formula, H or a halogen atom, R.sup.2, R.sup.3, R.sup.6, R.sup.7, R.sup.10, R.sup.11, R.sup.14 and R.sup.15 represent an alkyl, alkoxyl, alkylthio, alkylamino, dialkylamino or aryloxyl, arylthio group or --COOR.sup.17, R.sup.17 being a particular monovalent group, H or a halogen atom; and Met represents a metal atom. ##STR2## wherein X and Z represent O or S, R.sup.18, R.sup.19 and R.sup.20 represent H or an alkyl group, A, B and D represent a connecting group, n and l is an integer of 0-10, m, q, t, u, r and w are an integer of 0-2, and p is 0 or 1.
    Type: Grant
    Filed: June 22, 1992
    Date of Patent: January 10, 1995
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Hisato Itoh, Akio Karasawa, Kenichi Sugimoto, Takahisa Oguchi, Shin Aihara
  • Patent number: 5350843
    Abstract: A method for preparing a mixture of the halogenated alkoxyphthalocyanines represented by the formula (8) which comprises the step of reacting alkoxyphthalocyanines represented by the formula (7) and a mixture thereof with a halogenating agent in a mixed solvent of an organic solvent and water.
    Type: Grant
    Filed: July 6, 1992
    Date of Patent: September 27, 1994
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Hisato Itoh, Takahisa Oguchi, Shin Aihara, Kenichi Sugimoto
  • Patent number: 5334714
    Abstract: There is here disclosed a method for preparing an alkoxyphthalocyanine represented by the formula (1): ##STR1## wherein each of Rs is independently a secondary alkyl group having 3 to 20 carbon atoms, Met is a divalent metal atom or an oxy metal, and the substitution positions of -ORs are the 1- or 4-position, the 5- or 8-position, the 9- or 12 position, and the 13- or 16-position, which comprises the steps of heating a mixture of 3-alkoxyphthalonitrile and an organic base in an alcohol to 90.degree.-120.degree. C., adding a metal derivative at the same temperature, and then carrying out reaction, or alternatively the step of reacting a mixture of a 1,3-diimino-4-alkoxyisoindoline and a metal derivative in the presence or absence of an organic base in an aliphatic alcohol having 6 or more carbon atoms. In addition, the ratio of isomers of the alkoxyphthalocyanine can be controlled by regulating the addition time of the organic base.
    Type: Grant
    Filed: March 2, 1993
    Date of Patent: August 2, 1994
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Takahisa Oguchi, Kenichi Sugimoto, Shin Aihara, Hisato Itoh, Mansuke Matsumoto, Toshihiro Masaoka, Masakazu Nakamura
  • Patent number: 5296162
    Abstract: Near infrared absorbers which have a molecular extinction coefficient of 200,000 or more and are represented by the formula (I) ##STR1## wherein each of Y.sup.1, Y.sup.2, Y.sup.3, Y.sup.4, Y.sup.5, Y.sup.6, Y.sup.7 and Y.sup.8 is hydrogen, an alkyl group, alkoxyl group or alkylthio group; each of A.sup.1, A.sup.2, A.sup.3, A.sup.4, A.sup.5, A.sup.6, A.sup.7 and A.sup.8 is hydrogen, halogen, a nitro group, alkyl group, aralkyl group, alkenyl group, alkynyl group, alkoxyl group, aryloxy group, alkylthio group or arylthio group; and Met represents two hydrogen atoms or a metal, are useful for the production of optical display and recording materials.
    Type: Grant
    Filed: March 2, 1992
    Date of Patent: March 22, 1994
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Hisao Itoh, Katashi Enomoto, Takahisa Oguchi, Tutomu Nishizawa
  • Patent number: 5280114
    Abstract: Halogenated alkoxyphthalocyanine having a controlled grade of halogenation can be prepared by reacting a single compound or a mixture of phthalocyanine represented by the formula (1): ##STR1## wherein R.sup.1 is a substituted or unsubstituted alkyl group and may be the same or different, and Met is two hydrogen atoms, a divalent metal atom or a trivalent or tetravalent metal derivative, with 1 to 6 mole ratio of a halogenating agent at 0.degree. to 260.degree. C. in a solvent of from 1 to 1000 times by weight.
    Type: Grant
    Filed: July 12, 1991
    Date of Patent: January 18, 1994
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Hisato Itoh, Takahisa Oguchi, Shin Aihara
  • Patent number: 5270463
    Abstract: A method for preparing a halogenated alkoxyphthalocyanine represented by the formula (7) ##STR1## wherein R.sup.3 to R.sup.6 may be different and each of them is a secondary alkyl group, X is a halogen atom, n is the number of X and in the range of from 1 to 4, and Met is two hydrogen atoms, a divalent metal atom, or a trivalent or a tetravalent metallic derivative, which comprises the step of reacting a metal or a metallic compound with one to four kinds of raw materials selected from the group consisting of phthalonitriles represented by the following formula (1) and diiminoisoindolines represented by the following formula (2) ##STR2## wherein R.sup.1 is a secondary alkyl group, X is a halogen atom, and each of p and q is 0 or 1, but in at least one raw material, p or q is 1, and halogenated alkoxyphthalocyanine prepared by said method.
    Type: Grant
    Filed: July 1, 1991
    Date of Patent: December 14, 1993
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Hisato Itoh, Katashi Enomoto, Takahisa Oguchi, Tutomu Nishizawa
  • Patent number: 5220010
    Abstract: There is here disclosed a method for preparing an alkoxyphthalocyanine represented by the formula (1): ##STR1##
    Type: Grant
    Filed: December 24, 1991
    Date of Patent: June 15, 1993
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Takahisa Oguchi, Kenichi Sugimoto, Shin Athara, Hisato Itoh, Mansuke Matsumoto, Toshihiro Masaoka, Masakazu Nakamura
  • Patent number: 5124067
    Abstract: Near infrared absorbers which have a molecular extinction coefficient of 200,000 or more and are represented by the formula (I) ##STR1## wherein each of Y.sup.1, Y.sup.2, Y.sup.3, Y.sup.4, Y.sup.5, Y.sup.6, Y.sup.7 and Y.sup.8 is hydrogen, an alkyl group, alkoxyl group or alkylthio group; each of A.sup.1, A.sup.2, A.sup.3, A.sup.4, A.sup.5, A.sup.6, A.sup.7 and A.sup.8 is hydrogen, halogen, a nitro group, alkyl group, aralkyl group, alkenyl group, alkynyl group, alkoxyl group, aryloxy group, alkylthio group or arylthio group; and Met represents two hydrogen atoms or a metal, are useful for the production of optical display and recording materials.
    Type: Grant
    Filed: December 15, 1989
    Date of Patent: June 23, 1992
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Hisao Itoh, Katashi Enomoto, Takahisa Oguchi, Tutomu Nishizawa
  • Patent number: 5024926
    Abstract: Near-infrared absorbers which contain phthalocyanine derivatives in which the four benzene rings contained in the molecule independently have 1 to 4 substituents are light and thermal resistant and possess high molar extinction coefficients. Such near-infrared absorbers are useful in optical recording media, near-infrared absorption filters, and liquid crystal display devices.
    Type: Grant
    Filed: October 1, 1990
    Date of Patent: June 18, 1991
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Hisato Itoh, Katashi Enomoto, Takahisa Oguchi, Tsutomu Nishizawa
  • Patent number: 4977064
    Abstract: This invention relates to an optical recording medium characterized by high sensitivity, high stability, etc, and a process for making the optical recording medium. Specifically, the present invention provides an optical recording medium composed of a transparent substrate having prepits and/or pregrooves for system control signals and first and second recording layers formed thereon in order, the both layers having individually a specific reflectance, transmittance and absorbance. To the optical recording medium, a laser beam is irradiated on the transparent substrate side to record or read out information and, by detecting the variation of the amount of light as a sum of the reflected light from the boundary between the first recording layer and the substrate and the reflected light from the boundary between the second recording layer and the air, the system control signals are primarily obtained from the prepits and/or pregrooves.
    Type: Grant
    Filed: April 28, 1988
    Date of Patent: December 11, 1990
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Hiroshi Sukawa, Sumio Hirose, Shigeru Takahara, Tomoyoshi Sasakawa
  • Patent number: 4970021
    Abstract: Phthalocyanine compounds are described, which are represented by the following general formula (I): ##STR1## wherein R.sub.1 -R.sub.8 are individually a hydrogen atom or an alkyl or aryl group, a-h stand individually for an integer of 1-20, and M denotes two hydrogen atoms or a metal atom, metal halide, metal oxide, metal hydroxide, dialkylmetal, diarylmetal, bis(alkyloxy)metal or bis(trialkylsilyloxy)metal. Optical recording media and liquid crystal display panels, which contain at least one of the phthalocyanine compounds, are also described.
    Type: Grant
    Filed: August 29, 1988
    Date of Patent: November 13, 1990
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Masakatsu Nakatsuka, Tsutomu Nishizawa, Takahisa Oguchi, Hisato Itoh, Katashi Enomoto