Abstract: Objects of titanium or titanium alloys having the surface converted to a hard and wear-resistant nitride layer with good adhesion, which is distributed uniformly and also provides internal capillaries. The objects are produced by being treated in a vacuum furnace with an atmosphere of pure nitrogen gas at a temperature of 650.degree.-1000.degree. C. and at a pressure below atmospheric pressure. The thickness of the nitride layer can be controlled by controlling the treatment time and temperature.