Patents Assigned to Zaklady Chemiczne "Blachownia"
  • Patent number: 5502016
    Abstract: In the process of bisphenol-A systhesis a method for controlling the water content of the resultant cation-exchanger bed wherein an acid ion-exchanger resin in the form of a sulphonated styrene-divinylbenzene copolymer is washed with phenol and the resulted washing is contacted with a basic ion-exchanger resin. Water is removed from the washing by distillation, and the dewatered phenol is recycled to wash the cation-exchanger bed. The catalyst bed is then washed with a mixture of phenol acetone and water, and this washing is contacted with the basic ion-exchange resin and recycled to wash the cation exchanger bed so as to obtain the desired moisture content.
    Type: Grant
    Filed: May 23, 1994
    Date of Patent: March 26, 1996
    Assignees: Instytut Ciezkiej Syntezy Organicznej Blachownia, Zaklady Chemiczne Blachownia
    Inventors: Maciej Kiedik, Andrzej Krueger, Jo/ zef Ko t, Antoni Korek, Wojciech Balcerowiak, Jacek Hetper, Maria Majchrzak, Jan Niedziela, Ryszard Kosciuk, Anna Rzodeczko, Jerzy Mro/ z, Zbigniew Swiderski
  • Patent number: 5470809
    Abstract: An ion-exchanger catalyst in the form of an acid ion-exchanger resin used for the synthesis process of alkylated phenols and having substitutes containing 6-12 carbon atoms in a chain is treated with phenol alkylation having olefins in the presence of acid catalysts such as acid ion-exchange resins.
    Type: Grant
    Filed: May 10, 1994
    Date of Patent: November 28, 1995
    Assignees: Instytut Ciezniej Syntezy Organicznej Blachownia, Zaklady Chemiczne Blachownia
    Inventors: Maciej Kiedik, Andrzej Krueger, Jozef Ko t, Bogus aw Tkacz, Tatiana Pers, Teresa Rdesinska-Cwik, Jan Niedziela, Ryszard Kosciuk, Anna Rzodeczko, Zbigniew Swiderski, W adys ad Jankowski
  • Patent number: 5198591
    Abstract: The invention relates to a process for obtaining a high purity bisphenol from a post-reaction mixture resulting from the step of synthesis of phenol and acetone in the presence of a strong acid cation exhanger catalyst, by the way of crystallation and separation by distillation followed by recovery of bisphenol-A from the step of thermal catalytic decomposition of by product of the principal process technology in a multistage process.
    Type: Grant
    Filed: November 22, 1991
    Date of Patent: March 30, 1993
    Assignees: Instytut Ciezkiej Syntezy Organicznej "Blachownia", Zaklady Chemiczne "Blachownia", ABB Lummus Crest Inc.
    Inventors: Maciej Kiedik, Jozef Kolt, Jerzy Marszycki, Eugeniusz Zajac, Teodor Bek, Zbigniew Swiderski, Anna Rzodeczko, Jerzy Mroz, Janina Olkowska
  • Patent number: 4906789
    Abstract: A process for the production of bisphenol A from phenol and acetone, comprises introducing a substantially anhydrous reaction mixture of phenol, acetone, and recycled solution of bisphenol A and reaction by-products in phenol into a reaction zone containing a cation-exchange resin catalyst, such catalyst being a mixture of resin having a macroporous structure and resin having a microporous structure in a ratio of 0.05:1 to 0.5:1 by weight, the mol ratio of phenol to acetone being 5:1 to 30:1, and the concentration of bisphenol A being 12 to 20% by weight. The temperature of the reaction zone is maintained between 60 degrees and 95 degrees C. The resulting reacted reaction mixture is withdrawn from the reaction zone, the concentration of bisphenol A being 21 to 35% by weight and the amount of reaction by-products being 12 to 24% by weight. Such withdrawn reaction mixture is treated to recover bisphenol A product and to provide the recycled solution of bisphenol A and reaction by-products in phenol.
    Type: Grant
    Filed: September 28, 1988
    Date of Patent: March 6, 1990
    Assignees: Instytut Ciezkiej Syntezy Organicznej "Blachownia", Zaklady Chemiczne "Blachownia"
    Inventors: Edward Grzywa, Maciej Kiedik, Jo Kolt, Adam Mazur, Jerzy Marszycki, Eugeniusz Zajac, Anna Rzodeczko, Jerzy Czyz, Kazimierz Terelak, Zbigniew Swiderski, Teodor Bek