Patents Assigned to Zeochem
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Patent number: 10099201Abstract: A molecular sieve blend containing a zeolite, particularly a zeolite X or A, blended with a halloysite clay binder, wherein the binder contains at least 90% by weight halloysite clay, with a particle length less than about 1 ?m and processes for the production and use of this blend, particularly for adsorption of water from a feedstream and for the production of oxygen.Type: GrantFiled: February 5, 2016Date of Patent: October 16, 2018Assignee: ZEOCHEM LLCInventors: Kerry Weston, Jim Palmore, Dave Jaussaud
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Patent number: 9925522Abstract: A material for reverse phase chromatography comprises surface modifying apolar and charged groups bound to a solid support, said charged groups being present in amounts of about 0.25 to about 22% of the surface modifying groups, or in amounts of about 0.01 ?mol/m2 to 0.8 ?mol/m2 referred to the surface of the solid support for a material with a total amount of surface modifying groups of 3.6 ?mol/m2. Such material and suitable purification conditions for active pharmaceutical ingredients (APIs) like peptides can be evaluated by (a) determining the isoelectric point (pI) of the API of interest, (b) choosing a pH in a range where the solid phase material is stable, (c) determining the difference pI?pH and (d) if the difference pI?pH is positive, choosing an anion exchange (AIEX) material, or if the difference pI?pH is negative, choosing an cation exchange (CIEX) material.Type: GrantFiled: March 21, 2013Date of Patent: March 27, 2018Assignee: ZEOCHEM AGInventors: Nicola Forrer, Mandy Erdmann, David Gétaz, Massimo Morbidelle, Susanna Bernardi, Rushd Khalaf
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Patent number: 9555401Abstract: A molecular sieve blend with improved performance characteristics produced by preparing or obtaining a hydrophilic zeolite, particularly a hydrophilic zeolite A with a low SiO2:Al2O3 ratio, preparing or obtaining a hydrophobic silicon based binder, particularly a hydrophobic colloidal silica or a hydrophobic siloxane based material, mixing the zeolite with the silicon based binder and, in one embodiment, a seed containing small quantities of a clay binding agent and the zeolite, to form a mixture, and forming the mixture into the molecular sieve blend.Type: GrantFiled: March 24, 2014Date of Patent: January 31, 2017Assignee: ZEOCHEM LLCInventors: Kerry Weston, Patrick Purcell
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Publication number: 20150087816Abstract: A material for reverse phase chromatography comprises surface modifying apolar and charged groups bound to a solid support, said charged groups being present in amounts of about 0.25 to about 22% of the surface modifying groups, or in amounts of about 0.01 ?mol/m2 to 0.8 ?mol/m2 referred to the surface of the solid support for a material with a total amount of surface modifying groups of 3.6 ?mol/m2. Such material and suitable purification conditions for active pharmaceutical ingredients (APIs) like peptides can be evaluated by (a) determining the isoelectric point (pI) of the API of interest, (b) choosing a pH in a range where the solid phase material is stable, (c) determining the difference pI-pH and (d) if the difference pI-pH is positive, choosing an anion exchange (AIEX) material, or if the difference pI-pH is negative, choosing an cation exchange (CIEX) material.Type: ApplicationFiled: March 21, 2013Publication date: March 26, 2015Applicant: ZEOCHEM AGInventors: Nicola Forrer, Mandy Erdmann, David Gétaz, Massimo Morbidelle, Susanna Bernardi, Rushd Khalaf
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Patent number: 8969633Abstract: A process for the production of a molecular sieve blend with improved performance characteristics produced by preparing or obtaining a hydrophilic zeolite, particularly a hydrophilic zeolite A with a low SiO2:Al2O3 ratio, preparing or obtaining a hydrophobic silicon based binder, particularly a hydrophobic colloidal silica or a hydrophobic siloxane based material, mixing the zeolite with the silicon based binder and, in one embodiment, a seed containing small quantities of a clay binding agent and the zeolite, to form a mixture, and forming the mixture into the molecular sieve blend.Type: GrantFiled: March 24, 2014Date of Patent: March 3, 2015Assignee: Zeochem LLCInventors: Kerry Weston, Patrick Purcell
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Publication number: 20140221702Abstract: A process for the production of a molecular sieve blend with improved performance characteristics produced by preparing or obtaining a hydrophilic zeolite, particularly a hydrophilic zeolite A with a low SiO2:Al2O3 ratio, preparing or obtaining a hydrophobic silicon based binder, particularly a hydrophobic colloidal silica or a hydrophobic siloxane based material, mixing the zeolite with the silicon based binder and, in one embodiment, a seed containing small quantities of a clay binding agent and the zeolite, to form a mixture, and forming the mixture into the molecular sieve blend.Type: ApplicationFiled: March 24, 2014Publication date: August 7, 2014Applicant: ZEOCHEM LLCInventors: Kerry Weston, Patrick Purcell
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Publication number: 20140217324Abstract: A molecular sieve blend with improved performance characteristics produced by preparing or obtaining a hydrophilic zeolite, particularly a hydrophilic zeolite A with a low SiO2:Al2O3 ratio, preparing or obtaining a hydrophobic silicon based binder, particularly a hydrophobic colloidal silica or a hydrophobic siloxane based material, mixing the zeolite with the silicon based binder and, in one embodiment, a seed containing small quantities of a clay binding agent and the zeolite, to form a mixture, and forming the mixture into the molecular sieve blend.Type: ApplicationFiled: March 24, 2014Publication date: August 7, 2014Applicant: ZEOCHEM LLCInventors: Kerry Weston, Patrick Purcell
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Patent number: 8680344Abstract: A process for the production and use of a molecular sieve blend with improved performance characteristics produced by preparing or obtaining a hydrophilic zeolite, particularly a hydrophilic zeolite 3A with a low SiO2:Al2O3 ratio, preparing or obtaining a hydrophobic silica binder, particularly a hydrophobic colloidal silica, mixing the zeolite with the silica binder to form a mixture, and forming the mixture into the molecular sieve blend.Type: GrantFiled: January 25, 2011Date of Patent: March 25, 2014Assignee: Zeochem LLCInventors: Kerry C. Weston, Patrick Purcell
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Publication number: 20120190900Abstract: A process for the production and use of a molecular sieve blend with improved performance characteristics produced by preparing or obtaining a hydrophilic zeolite, particularly a hydrophilic zeolite 3A with a low SiO2:Al2O3 ratio, preparing or obtaining a hydrophobic silica binder, particularly a hydrophobic colloidal silica, mixing the zeolite with the silica binder to form a mixture, and forming the mixture into the molecular sieve blend.Type: ApplicationFiled: January 25, 2011Publication date: July 26, 2012Applicant: ZEOCHEM LLCInventors: Kerry C. Weston, Patrick Purcell
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Patent number: 7651550Abstract: A desorption process and a process for producing a catalytically deactivated formed zeolitic adsorbent, whereby both processes are suitable to improve the lifetime of a formed zeolitic adsorbent in the removal of sulfur compounds from sulfur contaminated gas and liquid feed streams. The adsorbent is in particular a synthetic 13X or LSX faujasite with a silica to alumina ratio from 1.9:1.0 to about 3.0:1.0. The cations of the faujasite include alkali and alkaline earth metals. The formed zeolite mixture is preferably catalytically deactivated due to a phosphate treatment. The desorption is carried out thermally, wherein the heat treatment is done at different temperature stages to avoid decomposition of the organic sulfur compounds.Type: GrantFiled: June 6, 2003Date of Patent: January 26, 2010Assignee: Zeochem AGInventors: Peter Hawes, Andreas Scheuble, Beat Kleeb, Armin Pfenninger
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Patent number: 7300899Abstract: A lithium exchanged zeolite X adsorbent blend with improved performance characteristics produced by preparing a zeolite X, preparing a binder which includes highly dispersed attapulgite fibers wherein the tapped bulk density of the highly dispersed attapulgite fibers measured according to DIN/ISO 787 is more than about 550 g/ml, mixing the zeolite X with the binder to form a mixture, forming the mixture into a shaped material, ion exchanging the zeolite X at least 75% with lithium ions, and calcining the shaped material.Type: GrantFiled: July 8, 2005Date of Patent: November 27, 2007Assignee: Zeochem, LLCInventors: Kerry Weston, Dave Jaussaud, Robert L. Chiang
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Publication number: 20070193939Abstract: Abstract Described is a desorption process and a process for producing a catalytically deactivated formed zeolitic adsorbent, whereby both processes are suitable to improve the lifetime of a formed zeolithic adsorbant in the removal of sulfur compounds from sulfur contaminated gas and liquid feed streams. The adsorbent is in particular a synthetic 13X or LSX faujasite with a silica to alumina ratio from 1.9:1.0 to about 3.0:1.0. The cations of the faujasite include alkali and alkaline earth metals. The formed zeolite mixture is preferably catalytically deactivated due to a phosphate treatment. The desorption is carried out thermally, wherein the heat treatment is done at different temperature stages to avoid decomposition of the organic sulfur compounds.Type: ApplicationFiled: June 6, 2003Publication date: August 23, 2007Applicant: ZEOCHEM AGInventors: Peter Hawes, Andreas Scheuble, Beat Kleeb, Armin Pfenninger
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Publication number: 20070062369Abstract: Disclosed is a synthetic zeolite by means of which gas streams containing steam and carbon dioxide as impurities can be purified. The zeolitic adsorbing agent is a 13X type or LSX type faujasite or a mixture of both types that are deformed with a binder, at least some parts of which are highly dispersed. Said novel adsorption system allows extraordinarily high adsorption capacities to be obtained while keeping the mass transfer zones short resulting in a longer service life of the adsorption systems before carbon dioxide is able to break through.Type: ApplicationFiled: April 7, 2004Publication date: March 22, 2007Applicant: ZEOCHEM AGInventors: Armin Pfenninger, Sonja Odolo-Hitz
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Publication number: 20060043001Abstract: A method for producing a substantially desulfurized hydrocarbon fuel stream at temperatures less than 100° C. including providing a nondesulfurized fuel cell hydrocarbon fuel stream and passing the fuel stream through a sequential sulfur adsorbent bed system containing at least one selective sulfur adsorbent and a calcium exchanged zeolite to produce a substantially desulfurized hydrocarbon fuel stream.Type: ApplicationFiled: August 18, 2005Publication date: March 2, 2006Applicants: Sud-Chemie Inc., Zeochem, LLC.Inventors: Eric Weston, R. Spivey, Kerry Weston
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Publication number: 20050272594Abstract: A lithium exchanged zeolite X adsorbent blend with improved performance characteristics produced by preparing a zeolite X, preparing a binder which includes highly dispersed attapulgite fibers wherein the tapped bulk density of the highly dispersed attapulgite fibers measured according to DIN/ISO 787 is more than about 550 g/ml, mixing the zeolite X with the binder to form a mixture, forming the mixture into a shaped material, ion exchanging the zeolite X at least 75% with lithium ions, and calcining the shaped material.Type: ApplicationFiled: July 8, 2005Publication date: December 8, 2005Applicant: Zeochem, LLCInventors: Kerry Weston, Dave Jaussaud, Robert Chiang
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Patent number: 6918948Abstract: A Process for the production and uses of a molecular sieve adsorbent blend product with improved performance characteristics produced by preparing a zeolite powder, preparing a highly dispersed attapulgite fiber binder, mixing the zeolite powder with the highly dispersed attapulgite binder to form a mixture, forming molecular sieve adsorbent products into a shaped material and calcining the shaped material, wherein the tapped bulk density of the highly dispersed attapulgite fibers measured according to DIN/ISO 787 is more than about 550 g/ml.Type: GrantFiled: January 26, 2004Date of Patent: July 19, 2005Assignee: Zeochem LLCInventors: Dave Jaussaud, Kerry Weston, Armin Pfenninger, Beat Kleeb
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Publication number: 20050119112Abstract: A process for the production of a molecular sieve adsorbent blend with improved performance characteristics produced by preparing a zeolite material, which may include zeolite 13X, zeolite LSX or mixtures thereof, preparing a binder which includes highly dispersed attapulgite fibers alone or blended with a non-highly dispersed attapulgite clay, mixing the zeolite material with the binder to form a mixture, forming molecular sieve adsorbent blends into a shaped material and treating the shaped material, wherein the tapped bulk density of the highly dispersed attapulgite fibers measured according to DIN/ISO 787 is more than about 550 g/ml.Type: ApplicationFiled: September 13, 2004Publication date: June 2, 2005Applicant: Zeochem, LLCInventors: Armin Pfenninger, Sonja Odolo-Hitz, Kerry Weston, Beat Kleeb, Dave Jaussaud
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Patent number: 6743745Abstract: A process for the production of a molecular sieve adsorbent blend product with improved performance characteristics produced by preparing a zeolite powder, preparing a highly dispersed attapulgite fiber binder, mixing the zeolite powder with the highly dispersed attapulgite binder to form a mixture, forming molecular sieve adsorbent products into a shaped material and calcining the shaped material, wherein the tapped bulk density of the highly dispersed attapulgite fibers measured according to DIN/ISO 787 is more than about 550 g/ml.Type: GrantFiled: January 22, 2002Date of Patent: June 1, 2004Assignee: ZeochemInventors: Dave Jaussaud, Kerry Weston, Armin Pfenninger, Beat Kleeb
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Publication number: 20030171205Abstract: A process for the production of a molecular sieve adsorbent blend product with improved performance characteristics produced by preparing a zeolite powder, preparing a highly dispersed attapulgite fiber binder, mixing the zeolite powder with the highly dispersed attapulgite binder to form a mixture, forming molecular sieve adsorbent products into a shaped material and calcining the shaped material, wherein the tapped bulk density of the highly dispersed attapulgite fibers measured according to DIN/ISO 787 is more than about 550 g/ml.Type: ApplicationFiled: January 22, 2002Publication date: September 11, 2003Applicant: ZEOCHEM LLCInventors: Dave Jaussaud, Kerry Weston, Armin Pfenninger, Beat Kleeb
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Patent number: 6530975Abstract: A molecular sieve adsorbent for the purification of gas streams containing water vapor and carbon dioxide. The adsorbent is a combination of sodium form of a low-silica faujasite, having a residual content of potassium ions less than about 8.0 percent (equiv.), a low content of crystalline and amorphous admixtures and crystal sizes generally within the range of 1-4 &mgr;m, and a binder. A process for the adsorbent preparation which comprises specific parameters of low silica faujasite synthesis, sodium-potassium ion exchange, blending and granulation.Type: GrantFiled: January 19, 2001Date of Patent: March 11, 2003Assignee: ZeochemInventors: Edward J. Rode, Albert M. Tsybulevskiy