Abstract: A reactor system includes plural batch-cyclic reduction/oxidation (redox) reactors. One reactor is operated in fuel mode while another is operated in air mode, and vice-versa. For each reactor in air mode, air is introduced via air-only tuyeres and via fuel-air tuyeres to oxidize oxidation particles. For each reactor in fuel mode, fuel is introduced via the reactor's fuel-air tuyeres and not via its air-only tuyeres. As a result, air is introduced at a higher rate than fuel is introduced so that the oxidation rate can match the reduction rate. Thus, for example, as few as two reactors can be used for continuous power generation without having to shuttle oxidation particles between reactors.

Abstract: A chemical-looping combustion system is provided in which an oxygen carrier, for example a metallic oxide or peroxide, is used for fuel combustion and produces carbon dioxide and water as by-products. The system delivers steam and CO2 at for direct utilization by steam cycle power generation equipment and heat exchangers. After fuel combustion, the oxygen-poor carrier is regenerated by exposure to air in a second, sequestered reactor. Choice of oxygen-carrier material and conditions allows for the fuel oxidizer reactor to run at temperatures greater than the running temperature of the regenerator reactor.