Abstract: Related are a high-molecular weight allyl alcohol polyoxyethylene polyoxypropylene ether and a preparation method. During preparation, an allyl alcohol raw material and a supported catalyst Rb-NHPA are firstly added into a high-pressure reaction kettle, and it is heated after being replaced with a nitrogen gas; then after the internal temperature of the reaction kettle is raised to a reaction temperature, an ethylene oxide (EO) and propylene oxide (PO) mixture is continuously fed for a reaction; and finally, after the internal temperature of the reaction kettle is reduced, an acetic acid is dropwise added into the reaction kettle so that the crude product of the high-molecular weight allyl alcohol polyoxyethylene polyoxypropylene ether is neutralized to be neutral. The refining process of a polyether is omitted, the process flow is greatly simplified, and the process time is effectively saved. In addition, the supported catalyst Rb-NHP may be recycled.

Abstract: The present invention relates to a synthesis method and synthesis reactor of high-selectivity 2-methylallyl chloride by taking isobutylene and chlorine gas as raw materials and performing a gas-phase chlorination reaction in a microchannel reactor with a cooling surface. The isobutylene and the chlorine gas are reacted in a T-shaped microchannel reactor, and the mixing speed is extremely fast. Meanwhile, the huge heat exchange area per unit volume can ensure that the reaction proceeds stably at a substantially constant temperature and has good controllability. Therefore, side reactions caused by excessive local temperature can be effectively suppressed, the reaction selectivity is high, and no coking phenomenon occurs.

Abstract: The present invention relates to a method for preparing 2-methylallyl chloride from 1,2-dichloroisobutane. The method is characterized in that 1,2-dichloroisobutane and a sodium hydroxide aqueous solution are used as raw materials; reactive rectification is performed in a combined rectifying tower to eliminate hydrogen chloride so as to obtain 2-methylallyl chloride. A plate tower is provided at the lower part of the combined rectifying tower; a packing tower is provided at the upper part of the combined rectifying tower; an inner reflux condenser is provided at the top of the combined rectifying tower. The sodium hydroxide aqueous solution is added from a first plate of the plate tower; and 1,2-dichloroisobutane is added from the middle part of the plate tower. The method has the advantages that the raw material 1 and 1,2-dichloroisobutane is fully converted; the selectivity of the 2-methylallyl chloride is high.

Abstract: The present invention relates to a method for preparing 2-methylallyl chloride from 1,2-dichloro-tert-butane. The method is characterized in that 1,2-dichloro-tert-butane and a sodium hydroxide aqueous solution are used as raw materials; reactive rectification is performed in a combined rectifying tower to eliminate hydrogen chloride so as to obtain 2-methylallyl chloride. A plate type tower is provided at the lower part of the combined rectifying tower; a packing tower is provided at the upper part of the combined rectifying tower; an inner reflux condenser is provided at the top of the combined rectifying tower. The sodium hydroxide aqueous solution is added from a first plate of the plate type tower; and 1,2-dichloro-tert-butane is added from the middle part of the plate type tower. The method has the advantages that the raw material 1 and 1,2-dichloro-tert-butane is fully converted; the selectivity of the 2-methylallyl chloride is high.

Abstract: The present invention relates to a synthesis method and synthesis reactor of high-selectivity 2-methylallyl chloride by taking isobutylene and chlorine gas as raw materials and performing a gas-phase chlorination reaction in a microchannel reactor with a cooling surface. The isobutylene and the chlorine gas are reacted in a T-shaped microchannel reactor, and the mixing speed is extremely fast. Meanwhile, the huge heat exchange area per unit volume can ensure that the reaction proceeds stably at a substantially constant temperature and has good controllability. Therefore, side reactions caused by excessive local temperature can be effectively suppressed, the reaction selectivity is high, and no coking phenomenon occurs.