Patents Examined by A. H. Walker
  • Patent number: 5183869
    Abstract: Compositions comprisingA) compounds of formula I ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are identical or different and each is hydrogen or methyl, and X is a divalent organic radical comprising from 2 to 60 carbon atoms, andB) compounds of formula II ##STR2## wherein R.sub.5 and R.sub.6 are identical or different and each, independently of the other, is C.sub.1 -C.sub.8 alkyl, and Y is hydrogen or an allyl radical, are distinguished by a favorable processing behaviour and high glass transition temperatures.
    Type: Grant
    Filed: May 14, 1991
    Date of Patent: February 2, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Andreas Kramer, Rudolf Brunner, Abdul-Cader Zahir
  • Patent number: 5183870
    Abstract: Disclosed is a composition comprising(A) 10 to 60 parts by weight of a polybutylene glycol di(meth)acrylate represented by the general formula (I): ##STR1## (B) 20 to 80 parts by weight of a specific urethane poly(meth)acrylate or epoxy poly(meth)acrylate,(C) 5 to 60 parts by weight of a specific mono(meth)acrylate, and(D) 0 to 60 parts by weight of a compound having at least one polymerizable double bond in the molecule,with the total amount of components (A), (B), (C) and (D) being 100 parts by weight. This composition is suitable for the making of plastic lenses because of its excellent properties such as high thermal resistance, high impact resistance, good dyeability, low water absorption and high surface accuracy.
    Type: Grant
    Filed: February 7, 1991
    Date of Patent: February 2, 1993
    Assignees: Mitsubishi Rayon Co., Ltd, Seiko Epson Corporation
    Inventors: Hiroshi Fukushima, Akira Motonaga, Eriko Suda, Mikito Nakajima, Katsuyoshi Takeshita, Yusuke Kutsukake
  • Patent number: 5182349
    Abstract: A copolymer is manufactured by allowing ethylene (A) and vinyl compounds (B) represented by the following general formula to undergo radical polymerization at a pressure of 1000-5000 kg/cm.sup.2 and a temperature of 100.degree.-400.degree. C., ##STR1## wherein R.sub.1 and R.sub.2 are each an independent hydrogen atom or a methyl group, R.sub.3 is a hydrogen atom or an alkyl group of 1-4 carbon atoms; a ratio of (B) to the sum of (A) and (B) is less than 1 mol %; a proportion of the amount of vinyl compounds (B), which are not successively bonded at all to the units (B) in the chain, but bonded to unlike units (A) on both sides thereof, to the total amount of (B) units in the copolymer is at least a 83%; and an MFR of the copolymer ranges from 0.1 to 200 g/10 min.Although the copolymer contains only a small amount of the vinyl compound (B) it nevertheless has excellent photo stabilizing effects.
    Type: Grant
    Filed: July 15, 1991
    Date of Patent: January 26, 1993
    Assignee: Mitsubishi Petrochemical Company, Ltd.
    Inventors: Tadao Okada, Hajime Ikeno, Yuji Ozeki, Yoshikazu Higaki, Koshi Matsubara, Kenichi Nakamura
  • Patent number: 5180790
    Abstract: A water-soluble complexing agent of metallic cations having a high complexing power and a high threshhold effect, constituted from acrylic copolymers, characterized by the fact that said agent is formed by terpolymers comprising acrylic and methacrylic and itaconic units of the general formula: ##STR1## in which the indices, expressed in percent by weight have at least a value of 10 for x and y, and a value of 5 for z.
    Type: Grant
    Filed: May 13, 1991
    Date of Patent: January 19, 1993
    Assignee: Coatex S.A.
    Inventors: Jacky Rousset, Georges Ravet
  • Patent number: 5180822
    Abstract: Described are preferred monomers including a vinylbenzyl moiety N-bonded to an alkylaminopyridinyl or pyridylimidazolyl function. Also described are preferred acid salts of such monomers. Additionally, preferred processes involving and resins formed from these preferred monomers are described. The preferred resins are highly selective for valuable heavy metal ions such as copper and demonstrate superior iron rejection values.
    Type: Grant
    Filed: August 27, 1991
    Date of Patent: January 19, 1993
    Assignee: Reilly Industries, Inc.
    Inventors: Donald W. McQuigg, Edward E. Sowers
  • Patent number: 5179182
    Abstract: The reaction cycle time for the copolymerization of unsaturated esters such as alkyl fumarates and vinyl acetate, and for the polymerization of methacrylates and acrylates may be dramatically reduced by carrying out the polymerization at elevated temperatures and pressures. An additional feature is the addition of initiator during polymerization which leads to improved products especially for lubricating oil pour depressants and fuel and crude oil flow improvers.
    Type: Grant
    Filed: May 30, 1990
    Date of Patent: January 12, 1993
    Assignee: Exxon Research & Engineering
    Inventors: Ramah J. Brod, Robert L. Elliott, Jean P. P. Coquerel
  • Patent number: 5171806
    Abstract: A composition for an optical material, which comprises an N-phenylmaleimide, a di(meth)allyl diphenate and a bisphenol ester.The N-phenylmaleimide, the di(meth)allyl diphenate and the bisphenol ester are contained in amounts of 1 to 50% by weight, 5 to 50% by weight and 1 to 30% by weight, based on the total weight of these components, respectively, The composition affords a three-dimensionally crosslinked resin by radical polymerization. The resin is useful for an optical material.
    Type: Grant
    Filed: July 12, 1991
    Date of Patent: December 15, 1992
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Hisayuki Kayanoki, Koichi Maeda, Akio Takigawa
  • Patent number: 5166275
    Abstract: Copolymer of maleic anhydride and the polymerizable component of naphtha oil chiefly composed of indene and aromatic hydrocarbons having a reactive double bond, a resin modifier containing said copolymer as an effective ingredient, a dispersant containing a salt of the sulfonation product of said copolymer, an esterified product of said copolymer, and preferred processes for producing these products.
    Type: Grant
    Filed: January 10, 1992
    Date of Patent: November 24, 1992
    Assignee: Kawasaki Steel Corporation
    Inventors: Norihide Enomoto, Yoshihiro Naruse, Keiji Sugiura, Kimiyo Ohtsu, Masato Takagi
  • Patent number: 5166285
    Abstract: The present invention relates to a process for preparing a hard transparent resin comprising polymerizing a monomer (A) having both a functional group of the following formula (I): ##STR1## wherein X is selected from the group consisting of an oxygen atom and a sulfur atom,and a functional group selected from the group consisting of a functional group of the formula (II):CH.sub.2 CR--COO-- (II)wherein R is selected from the group consisting of hydrogen and methyl group,and a functional group of the formula (III): ##STR2## The invention also provides a process for preparing a transparent resin comprising copolymerizing monomer (A) with a monomer (B) having at least one functional group selected from the group consisting ofCH.sub.2 CH.dbd.COO--,CH.sub.2 .dbd.C(CH.sub.3)--COO--, and ##STR3## This resin can be suitably used as a glazing material, and in the manufacture of optical lenses, optical information recording medium substrates, etc.
    Type: Grant
    Filed: February 14, 1992
    Date of Patent: November 24, 1992
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Katsuyoshi Sasagawa, Yoshinobu Kanemura, Masao Imai, Toshiyuki Suzuki
  • Patent number: 5166345
    Abstract: A novel photochromic compound and a polymer comprising the photochromic compound are disclosed. The novel photochromic compound of the present invention is a spirooxazine compound having an addition polymerizable organic functional group or a ring-opening polymerizable organic functional group therein.
    Type: Grant
    Filed: August 7, 1991
    Date of Patent: November 24, 1992
    Assignee: Toray Industries, Inc.
    Inventors: Ryojiro Akashi, Takashi Taniguchi
  • Patent number: 5164420
    Abstract: Photodegradable polymers comprising substituted furan functionality or ring opened derivatives thereof and thermoplastic articles formed therefrom.
    Type: Grant
    Filed: October 26, 1990
    Date of Patent: November 17, 1992
    Assignee: The Dow Chemical Company
    Inventor: Virginia A. Dais
  • Patent number: 5164467
    Abstract: Aziridine compounds having the following structural formula: ##STR1## wherein R.sub.1 represents an alkylidene group;R.sub.2 represents hydrogen or an alkyl radical;R.sub.3 represents an aromatic hydrocarbon moiety;R.sub.4 represents an alkyl radical;R.sub.5 represents an alkylene radical;R.sub.6 represents hydrogen, an alkyl radical, phenyl or combinations thereof; andX represents oxygen, --S--, NH--, or NR--, wherein R represents an alkyl or phenyl are disclosed. Acrylic polymers containing moieties of at least two such aziridine compounds depending therefrom are also disclosed. The acrylic polymers are relatively non-toxic and have negligible inhalation irritation and are useful in the formulation of coating compositions which harden or cure at low temperatures.
    Type: Grant
    Filed: October 9, 1991
    Date of Patent: November 17, 1992
    Assignee: PPG Industries, Inc.
    Inventor: Charles M. Kania
  • Patent number: 5164469
    Abstract: A transparent resin material consisting of a hydrogenation product of a (co)polymer obtained by subjecting at least one compound represented by general formula (I) or a combination of at least 5% by weight of said compound and 95% by weight or less of other copolymerizable cyclic olefin monomer to metathesis polymerization: ##STR1## wherein A and B are independently hydrogen atoms or C.sub.1-10 hydrocarbon groups; and X and Y are independently hydrogen atoms, C.sub.1-10 hydrocarbon groups, --C(CH.sub.2).sub.n COOR.sup.1 groups or --(CH.sub.2).sub.n OCOR.sup.1 groups [R.sup.1 is a C.sub.1-20 hydrocarbon group and n is 0 or an integer of 1-10] with the proviso that at least one of X and Y is selected from the above --(CH.sub.2).sub.n COOR.sup.1 and --(CH.sub.2).sub.n OCOR.sup.1 groups. Said transparent resin material is moldable and has sufficient optical properties, low hygroscopicity, good heat resistance and excellent adhesion to recording layer.
    Type: Grant
    Filed: January 31, 1991
    Date of Patent: November 17, 1992
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Kohei Goto, Zen Komiya, Noboru Yamahara, Akira Iio, Masao Hisatomi, Hiroshi Oka
  • Patent number: 5159033
    Abstract: A process is described for carrying out aqueous and non-aqueous polymerization of polymerizable monomers, particularly vinyl monomers, and, preferably, vinylpyrrolidone, in the presence of a mixture of a stable, high purity, free-flowing, fine white powder of a substantially anhydrous 1:1 molar ratio complex of polyvinylpyrrolidone-hydrogen peroxide (PVP--H.sub.2 O.sub.2), respectively, and a transition metallic ion, as a free radical initiator, is described herein. Preferred polymerizations are the homopolymerization of vinylpyrrolidone and the copolymerization of maleic anhydride and a C.sub.1 -C.sub.5 alkyl vinyl ether.
    Type: Grant
    Filed: January 15, 1992
    Date of Patent: October 27, 1992
    Assignee: ISP Investments Inc.
    Inventors: John J. Merianos, Robert B. Login, Stephen L. Kopolow, Mohammed Tazi
  • Patent number: 5159025
    Abstract: A styrene-based copolymer comprising 74.3 to 98.7 mol % of the structural unit (I) represented by the general formula: ##STR1## 1.3 to 25.4 mol % of the structural unit (II) represented by the formula: ##STR2## and 10 to 7000 mol ppm of the structural unit (III) represented by the general formula: ##STR3## (wherein R.sup.1 to R.sup.3 are as defined in the appended claims), characterized by having toluene-insoluble content of not more than 0.5% by weight, is disclosed.Efficient processes for producing the above styrene-based copolymer are also disclosed.
    Type: Grant
    Filed: June 12, 1989
    Date of Patent: October 27, 1992
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventor: Eiichi Terada
  • Patent number: 5153290
    Abstract: Ethylenically unsaturated cyclic ortho esters are prepared by the reaction of a hydroxy-substituted cyclic ortho ester such as 4-hydroxymethyl-2-methoxy-2-methyl-1,3-dioxolane with acryloyl chloride, methacryolyl chloride, vinylbenzyl chloride or the like. They form polymers, especially random copolymers with styrene and EPDM graft copolymers; the latter are useful in the formation of copolymer-containing compositions with polyesters, polyamides and the like. The copolymer-containing compositions have excellent physical properties and may be employed to compatibilize blends of the same polymers.
    Type: Grant
    Filed: June 17, 1991
    Date of Patent: October 6, 1992
    Assignee: General Electric Company
    Inventors: Farid F. Khouri, Robert J. Halley, Timothy J. Shea, John R. Campbell
  • Patent number: 5147941
    Abstract: According to this invention, there is provided a denture adhesive which is a mixed partial salt of a copolymer of maleic anhydride and acrylic acid (or methacrylic acid), optionally including a C.sub.1 -C.sub.4 alkyl vinyl ether, having a weight average molecular weight of about 30,000 to 400,000, preferably about 50,000 to 350,000. The copolymer comprises about 10 to 70 mole percent, preferably 20 to 60 mole percent, of maleic anhydride, about 30 to 90 mole percent, preferably 40 to 80 percent, of acrylic acid (or methacrylic acid), and 0 to 25 mole percent of a C.sub.1 -C.sub.4 alkyl vinyl ether.
    Type: Grant
    Filed: November 1, 1991
    Date of Patent: September 15, 1992
    Assignee: ISP Investments Inc.
    Inventors: Mohammed Tazi, Robert B. Login, Krystyna Plochocka, Rama K. Haldar, Balgopal Gangadharan, William E. Prosise
  • Patent number: 5147955
    Abstract: Copolymers ofa) phosphonic acid derivatives corresponding to formula (I) ##STR1## wherein Y represents H or CH.sub.3,X represents a single bond or --CH.sub.2 --,R represents an aryl or alkyl,b) maleic anhydride andc) a polymerizable compound containing two or more allyl or methally groups in the molecule.
    Type: Grant
    Filed: July 15, 1991
    Date of Patent: September 15, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Lindner, Siegfried Korte
  • Patent number: 5147954
    Abstract: A cross-linked polymer-supported 4-(N-benzyl-N-methylamino) pyridine material and process for its preparation in high yield and having effective physical and catalytic properties. The polymer-supported catalyst is characterized by the suspension copolymerization of an organic phase containing the corresponding vinyl-substituted pyridine monomer, a styrene monomer, and a suitable cross-linking agent and free radical-generating catalyst in the presence of an aqueous phase containing a cellulose ether derivative as the stabilizing agent. A purified acid salt of the vinyl-substituted pyridine monomer useful in polymerizations and stable for storage as either a solid or an aqueous solution.
    Type: Grant
    Filed: November 5, 1990
    Date of Patent: September 15, 1992
    Assignee: Reilly Industries Inc.
    Inventors: Donald W. McQuigg, Edward E. Sowers, Gerald L. Goe, Eric F. V. Scriven, James G. Keay
  • Patent number: 5143969
    Abstract: Heat-curable bismaleimide resins contain a bismaleimide, an aromatic dialkenyl compound as comonomer and also from 1 to 40% by weight of a monoalkenyl compound, preferably 2-hydroxy-3-allylbiphenyl, as reactive diluent.
    Type: Grant
    Filed: June 24, 1991
    Date of Patent: September 1, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Bernd Reck, Rita A. Laschober, Dale Gerth, Jack D. Boyd