Abstract: Melt-processable, radiation cross-linkable ethylene/chlorotrifluoroethylene copolymer compositions are provided which contain about 0.1 to 5% by weight of the copolymer of a radiation cross-linking promoter, about 0.01 to 5% by weight of an anti-oxidant and about 0.1 to 30% by weight of an acid scavenger. Such compositions do not give off odors when irradiated to cross-link the copolymer and do not develop bubbles after irradiation.
Type:
Grant
Filed:
January 30, 1973
Date of Patent:
March 30, 1976
Assignee:
Allied Chemical Corporation
Inventors:
Arthur B. Robertson, Robert J. Schaffhauser
Abstract: A process for the stereospecific polymerization of olefins is described, wherein the selected monomer is homopolymerized, or the selected monomers are copolymerized, by reacting the selected monomer or monomers in the presence of a catalyst consisting of an uranium .pi. - allyl compound represented by one of the formulae: ##EQU1## in which R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5, the same or different, may be hydrogen atoms, alkyl radicals having from 1 to 10 carbon atoms, aryl radicals having from 6 to 10 carbon atoms, cycloalkyl radicals having from 4 to 10 carbon atoms, and alkylaryl radicals; the dotted line indicates the possible delocalization of the valence electrons; X is an anion selected from among Cl.sup.-, Br.sup.- and I.sup.-; and n is an integer ranging from 1 to 3; and, optionally, a co-catalyst which is a Lewis acid, or a complex thereof with an ether, a tertiary amine or a phosphine.