Abstract: A reference electrode for the measurement of the oxidation-reduction potentials of solutions is especially suitable for oxidizing solutions such as highly concentrated and fuming nitric acids, the solutions of nitrogen oxides, N.sub.2 O.sub.4 and N.sub.2 O.sub.5, in nitric acids. The reference electrode is fabricated of entirely inert materials, has a half cell of Pt/Ce(IV)/Ce(III)/70 wt. % HNO.sub.3, and includes a double-junction design with an intermediate solution of 70 wt. % HNO.sub.3. The liquid junctions are made from Corning No. 7930 glass for low resistance and negligible solution leakage.
Type:
Grant
Filed:
May 23, 1989
Date of Patent:
January 2, 1990
Assignee:
The United States of America as represented by The United States Department of Energy
Inventors:
Lester P. Rigdon, Jackson E. Harrar, Jack C. Bullock, Sr., Raymond R. McGuire