Abstract: A composition of matter for an incendiary device includes a thermate component consisting of strontium nitrate Gr A, black iron oxide Gr B, aluminum Gr D Cl 5, aluminum Gr E Cl 6, sulfur Gr E, and polyacrylic rubber; and an ignition component consisting of potassium nitrate, titanium, aluminum, silicon, sulfur, charcoal, and polyacrylic rubber, wherein the thermate component consists of a barium nitrate free thermate formulation, and wherein the ignition component consists of a lead free ignition formulation. A parts by weight composition of the thermate component consists of 20.59% strontium nitrate Gr A, 48.04% black iron oxide Gr B, 17.57% aluminum Gr D Cl 5, 9.88% aluminum Gr E Cl 6, 1.96% sulfur Gr E, and 1.96% polyacrylic rubber, and a parts by weight composition of the ignition component consists of 66% potassium nitrate, 11% titanium, 8% aluminum, 6% silicon, 2% sulfur, 5% charcoal, and 2% polyacrylic rubber.
Type:
Grant
Filed:
January 16, 2009
Date of Patent:
June 18, 2013
Assignee:
The United States of America as Represented by the Secretary of the Army
Abstract: Solid composite propellants are provided that include a matrix comprising an energetic oxidizer and a binder. A multi-layered reactive thin film is provided in the matrix. The reactive thin film includes metal and inorganic oxidizer. Methods of making the solid composite propellants are also provided.
Abstract: Solid composite propellants are provided that include a matrix comprising an energetic oxidizer and a binder. A multi-layered reactive thin film is provided in the matrix. The reactive thin film includes metal and inorganic oxidizer. Methods of making the solid composite propellants are also provided.
Abstract: Hypergolic liquid or gel fuel mixtures utilized in bipropellant propulsion systems are disclosed as replacements for fuels containing toxic monomethylhydrazine. The fuel mixtures include one or more amine azides mixed with one or more tertiary diamine, tri-amine or tetra-amine compounds. The fuel mixtures include N,N,N?,N?-tetramethylethylenediamine (TMEDA) mixed with 2-N,N-dimethylaminoethylazide (DMAZ), TMEDA mixed with tris(2-azidoethyl)amine (TAEA), and TMEDA mixed with one or more cyclic amine azides. Each hypergolic fuel mixture provides a reduced ignition delay for combining with an oxidant in fuel propellant systems. The fuel mixtures have advantages in reduced ignition delay times compared to ignition delay times for each unmixed component, providing a synergistic effect which was not predictable from review of each component's composition.
Type:
Grant
Filed:
July 25, 2011
Date of Patent:
May 7, 2013
Assignee:
The United States of America as represented by the Secretary of the Army
Inventors:
William H. Stevenson, III, LaShanda D. Felton, Zhu Slocum-Wang
Abstract: A pyrophoric material comprises a pyrophoric metal coated onto a wire mesh substrate. Iron and nickel are the preferred metals and a steel wire mesh is suitable. A process for making the pyrophoric material involves spraying an alloy of iron and/or nickel with aluminium onto a mesh using a high velocity oxy-fuel (HVOF) process following by leaching out at least a proportion of the aluminium by treatment with an alkaline solution. The product has application as a supported catalyst or as either an ignition medium or as a flare material in military countermeasures in which applications it is capable of burning at a high temperature.
Type:
Grant
Filed:
April 14, 2009
Date of Patent:
April 30, 2013
Assignee:
The Secretary of State for Defence
Inventors:
James Dominic Callaway, James Neil Towning, Raymond Cook, Paul Smith, David Graham McCartney, Andrew J. Horlock
Abstract: An ionic liquid is disclosed. A precursor composition that comprises at least one ionic liquid and at least one energetic material is also disclosed, as is a method of synthesizing an ionic liquid and a method of desensitizing an explosive composition.
Type:
Grant
Filed:
July 6, 2011
Date of Patent:
April 23, 2013
Assignee:
Alliant Techsystems Inc.
Inventors:
Steven M. Nicolich, Alexander J. Paraskos, Daniel W. Doll, Gary K. Lund, Wendy A. Balas
Abstract: A method for preparing a gelled liquid propane (GLP) composition comprises the introduction of liquid propane into an evacuated mixing vessel containing a gellant and mixing the liquid propane with the gellant. A bi-propellant system comprising GLP is particularly well-suited for outer planet missions greater than 3 AU from the sun and also functions in earth and near earth environments. Additives such as powders of boron, carbon, lithium, and/or aluminum can be added improve performance or enhance hypergolicity. The gelling agent can be silicon dioxide, clay, carbon, or organic or inorganic polymers. The bi-propellant system may be, but need not be, hypergolic.
Abstract: The invention relates to catalyst components, containing: (A) at least one Brönsted acid, (B) water, (C) at least one antacid-acting compound from the group consisting of the oxides, hydroxides, carbonates and/or carboxylates of the elements aluminum, chromium, copper, germanium, manganese, lead, antimony, tin, tellurium, titanium and/or zinc, (D) optionally at least one inert diluent, (E) optionally at least one modifier, the mixture of one part by weight of the catalyst component with three parts by weight bisaziridino polyether with an average imino equivalent mass of 3100, preparable from a polyetherdiol which comprises ethylene oxide and tetrahydrofuran units in the molar ratio 1:3.5 solidifying within 0.5 to 20 minutes to a solid elastomer material which has a shore A hardness of at least 20 according to DIN 53505 after 24 hours' storage time at room temperature.
Type:
Grant
Filed:
April 12, 2001
Date of Patent:
April 9, 2013
Assignee:
3M Deutschland GmbH
Inventors:
Gunther Eckhardt, Erich Wanek, Bernd Kuppermann
Abstract: Combustible structural composites and methods of forming same are disclosed. In an embodiment, a combustible structural composite includes combustible material comprising a fuel metal and a metal oxide. The fuel metal is present in the combustible material at a weight ratio from 1:9 to 1:1 of the fuel metal to the metal oxide. The fuel metal and the metal oxide are capable of exothermically reacting upon application of energy at or above a threshold value to support self-sustaining combustion of the combustible material within the combustible structural composite. Structural-reinforcing fibers are present in the composite at a weight ratio from 1:20 to 10:1 of the structural-reinforcing fibers to the combustible material. Other embodiments and aspects are disclosed.
Type:
Grant
Filed:
July 28, 2011
Date of Patent:
April 2, 2013
Assignee:
Battelle Energy Alliance, LLC
Inventors:
Michael A. Daniels, Ronald J. Heaps, Eric D. Steffler, W. David Swank
Abstract: Perchlorate-free flare compositions are disclosed which, when burned, produce yellow smoke and flames. Methods of producing the compositions are also disclosed.
Type:
Grant
Filed:
January 14, 2011
Date of Patent:
February 5, 2013
Assignee:
The United States of America as represented by the Secretary of the Navy
Inventors:
Christina M. Yamamoto, Robert G. Shortridge
Abstract: A self igniting pyrotechnical sparkler. The sparkler includes a nonflammable support member or rod substantially covered with a pyrotechnic coating composition along one end and a pyrotechnical igniter coating covering over part of the pyrotechnic coating. The igniter coating including a mixture of potassium chlorate, antimony sulfate, powder aluminum, particulate magnesium, binder and/or glass beads.
Abstract: Apparatus for storing and dispensing flowable explosive, the apparatus including an explosive pump for pumping flowable explosive into an explosive tank having a fluid pressure-actuated piston movable therein for expelling flowable explosive out of the explosive tank through a delivery hose fitted with an injector through which one or more additives from one or more additive tanks can be pumped by an additive pump.
Abstract: Gas generating compositions include a combination of melamine and maleic hydrazide as a primary fuel; and a primary oxidizer consisting of ammonium nitrate and potassium chlorate. Gas generators and vehicle occupant protection systems incorporating the present compositions are also described.
Abstract: The invention relates to a fuel component for an explosive, in which case the fuel component contains a volume-expanded molecularly dispersed hydrocarbon, and a method for its production. Furthermore, the invention relates to an explosive formed of the fuel component and an oxidizer, an explosive body filled with the explosive as well as an explosion method.
Type:
Grant
Filed:
May 7, 2008
Date of Patent:
August 7, 2012
Assignees:
Bauer Maschinen GmbH, Perforator GmbH
Inventors:
Claus Willi Becker, Bernhard Werner Schwark-Werwach, Thomas Matthias Klapoetke
Abstract: A process for manufacture of explosive formulations containing a halogenated wax binder, involving dilution of the halogenated wax in a non-aqueous lacquer, slurring the explosive in an aqueous solution and applying heat and vacuum to yield a granular explosive which provides complete coating to avoid hot spots and is quickly pressable at lower temperature and pressure.
Type:
Grant
Filed:
January 25, 2011
Date of Patent:
July 10, 2012
Assignee:
The United States of America as Represented by the Secretary of the Army
Inventors:
Sanjeev K. Singh, Philip Samuels, Christos Capellos, Barry Fishburn
Abstract: Perchlorate-free flare compositions are disclosed which, when burned, produce red smoke and flames. Methods of producing the compositions are also disclosed.
Type:
Grant
Filed:
January 14, 2011
Date of Patent:
July 10, 2012
Assignee:
The United States of America as represented by the Secretary of the Navy
Inventors:
Robert G. Shortridge, Christina M. Yamamoto
Abstract: The present invention relates to a dry process for the manufacture of pyrotechnic objects from at least one reducing charge selected from guanidine derivatives, metal hydrides, alkali metal hydrides and alkaline earth metal hydrides, and at least one oxidizing charge selected from alkali metal nitrates, alkaline earth metal nitrates and basic metal nitrates, at least one of said reducing and oxidizing charges having the property of flowing under stress. Said process makes it possible to obtain pellets and small tablets directly by compaction/compression, to obtain granules, usable as such, by compaction and then granulation, and to obtain compressed objects by compaction, granulation and then compression. The high-performance pyrotechnic objects obtained constitute a further subject of the invention.
Type:
Grant
Filed:
June 15, 2006
Date of Patent:
July 10, 2012
Assignee:
Herakles
Inventors:
Marie Gaudre, Eric Giraud, Dimitri Charrette
Abstract: Techniques and processes that combine particulate coating processes with particulate handling steps resulting in the formation of free-flowing particulates for introduction into energetic product vessels to affect an in-situ, net-shape manufactured product. The processes involve selecting suitably sized materials, processing such materials such that they are surface-coated and/or locally “structured” particulates, and pouring, preferably “dry” pouring, these processed materials into an energetic product vessel and infusing the filled vessel with a polymerizable and surface-compatible monomer or oligomer which flows into the unoccupied volume, followed by polymerization of the monomer, which then becomes the binder giving mechanical integrity to the final, net-shape energetic composition.
Type:
Grant
Filed:
April 7, 2004
Date of Patent:
April 24, 2012
Assignee:
New Jersey Institute of Technology
Inventors:
Costas Gogos, Ming-Wan Young, Rajesh Dave, Robert Pfeffer, David Todd, Bainian Qian, Theodore Davidson
Abstract: Ignition means for propellant powders include at least one oxidation means, at least one reduction means and at least one binder, and are free from primary explosives.
Type:
Grant
Filed:
January 10, 2006
Date of Patent:
April 3, 2012
Inventors:
Klaus Redecker, Ulrich Bley, Rainer Hagel