Abstract: Cool burning hydrate fuels are provided for gas generant compositions for automotive inflatable restraint systems. The cool burning hydrate fuel is a compound comprising carbon, hydrogen, oxygen, a transition metal, and optionally nitrogen. The cool burning hydrate fuel is a transition metal salt of an organic compound or transition metal complex salt having (i) at least one functional group selected from the group consisting of: amide, imide, hydroxyl, carboxylic acid, and combinations thereof, (ii) an oxygen-to-carbon mole ratio of greater than or equal to about 0.5, (iii) at least one-half a water molecule of hydration, and (iv) an exothermic heat of formation of at least about ?400 KJ/mole. The fuel may have a water release temperature of ?about 140° C. The cool burning hydrate fuel may be one or more of copper cyanurate dihydrate, a copper melamine oxalate dihydrate, and a copper malonate hydrate.
Type:
Grant
Filed:
March 29, 2019
Date of Patent:
June 20, 2023
Assignee:
Autoliv ASP, Inc.
Inventors:
Ivan V. Mendenhall, Gary K. Lund, Jadd Shelton
Abstract: An opto-thermal laser detonator uses resonantly absorptive tuned nano-material associated with secondary explosives for optical absorption and initiation by an integral laser diode. The opto-thermal laser detonator includes main explosive material; resonantly absorptive tuned nano-material; secondary explosive material, wherein the resonantly absorptive tuned nano-material and the secondary explosive material are associated to form associated material made of the resonantly absorptive tuned nano-material and the secondary explosive material; and a laser diode operatively connected to the associated material, wherein the laser diode initiates the associated material which in turn initiates the main explosive material.
Type:
Grant
Filed:
August 30, 2021
Date of Patent:
April 18, 2023
Assignee:
Lawrence Livermore National Security, LLC
Abstract: Embodiments include a method of forming an initiator. The method includes placing an energetic powder in a container. A solvent is added to the container and the solvent and energetic powder are mixed to form a slurry mixture. The slurry mixture is filtered. The filtered slurry mixture is placed in a transfer tube. The slurry mixture is applied to a bridge wire. The slurry mixture applied to the bridge wire is then dried.
Type:
Grant
Filed:
May 12, 2021
Date of Patent:
April 11, 2023
Assignee:
Ensign-Bickford Aerospace & Defense Company
Abstract: The present invention is a pyrotechnic time delay system that is improved over prior-art designs. Specifically, the system described herein comprises at least one delay element. The delay element or delay elements each have an input charge, a delay composition, and an output charge. Both the input charge and the output charge are igniter compositions and are comprised of the same components despite having different functional goals. The input charge and output charge compositions preferably contain titanium, manganese dioxide, and polytetrafluoroethylene. The delay composition may be modified from current formulations to include manganese and manganese dioxide, or tungsten and manganese dioxide. The system disclosed herein may be comprised of one delay element, or it may be modular wherein multiple delay elements are connected in series.
Type:
Grant
Filed:
July 30, 2021
Date of Patent:
March 28, 2023
Assignee:
The United States of America as Represented by the Secretary of the Army
Inventors:
Anthony Shaw, Jay Poret, Lori Groven, Joshua Koenig, Jason Brusnahan
Abstract: An explosive sheet simulant that uses an ethylene vinyl acetate polymer combined with boron carbide or iron oxide for X-ray attenuating properties, and components of the mixture selected for predetermined flexural modulus combined with particle density, effective atomic number, X-ray transmission properties, or millimeter wave properties.
Type:
Grant
Filed:
January 25, 2022
Date of Patent:
March 28, 2023
Assignee:
The Government of the United States of America, as represented by the Secretary of Homeland Security
Abstract: An explosive, in particular a water-in-oil emulsion explosive, comprising a water-based explosive composition and a gas, wherein the gas is infused with two different ranges of sizes of nanobubbles, to provide controlled hotspots for detonation to improve emulsion stability and detonation sensitivity. Into the Nano Bubble tank (31) are fed the pressurised gas in water through valve (26) and also a sample is fed into the Nano Bubble tank (31). This then provides the NanoBubble Input NBIbp1 to be fed by NB Feed Pump (33) into static mixer (51). Also fed to the Static Mixer (51) by matrix pump (41) is the explosives containing PIBSA (Poly-Iso-Butylene Succinic Anhydride) in emulsion form as Emulsion Input EInp1 from Emulsion Matrix truck.
Abstract: A gas generant composition for an automotive inflatable restraint system is provided with a fuel having a thermally stable crystalline hydrate compound with a water release temperature of greater than or equal to about 140° C. The thermally stable crystalline hydrate compound serves as a ballistic modifier, which can serve to increase burn rate, reduce pressure sensitivity, reduce temperature sensitivity, and the like. The thermally stable crystalline hydrate compound may be selected from the group consisting of: a copper phthalate hydrate, copper pyromellitate dihydrate, copper fumarate dihydrate, copper (3-nitrophthalate) dihydrate, and combinations thereof.
Abstract: The invention relates to a transport vehicle designed preferably for producing a mixture of waste lubricating oils/fuel oil (ALR/FO), mounted preferably on a chassis and comprising at least one metal tank.
Type:
Grant
Filed:
December 15, 2016
Date of Patent:
December 27, 2022
Assignee:
ENAEX SERVICIOS S.A.
Inventors:
Luis Antonio Loyola Irribarra, Camilo Garcia G., Fernando Zangheri G., Diego Mendez A.
Abstract: Subject matter of the invention are lead-free initiating agents or initiating agent mixtures and initiating and igniting compositions which contain the lead-free initiating agents or initiating agent mixtures.
Type:
Grant
Filed:
July 10, 2017
Date of Patent:
December 27, 2022
Assignee:
DYNITEC GMBH
Inventors:
Helmut Zoellner, Manuel Joas, Rainer Schirra, Kemal Kaplan
Abstract: A high strength engineered reactive matrix composite that includes a core material and a reactive binder matrix combined in high volumes and with controlled spacing and distribution to produce both high strength and controlled reactivity. The engineered reactive matrix composite includes a repeating metal, ceramic, or composite particle core material and a reactive binder/matrix, and wherein the reactive/matrix binder is distributed relatively homogeneously around the core particles, and wherein the reactivity of the reactive binder/matrix is engineered by controlling the relative chemistry and interfacial surface area of the reactive components. These reactive materials are useful for oil and gas completions and well stimulation processes, enhanced oil and gas recovery operations, as well as in defensive and mining applications requiring high energy density and good mechanical properties.
Abstract: A precursor formulation of an energetic composition with improved electrostatic charge dissipation, including an amorphous carbon black having a specific surface area of at least about 1,200 m2/g, in an amount from about 0.05% by weight to about 0.25% by weight. Also disclosed is a precursor formulation of a propellant composition with improved electrostatic charge dissipation. The amorphous carbon black having a specific surface area of at least about 1,200 m2/g may enhance electrostatic charge dissipation of the HTPB-based propellant composition, without affecting a breakdown voltage of the propellant composition.
Type:
Grant
Filed:
March 15, 2013
Date of Patent:
September 6, 2022
Assignee:
Northrop Grumman Systems Corporation
Inventors:
Nathan M. Seidner, Jay D. Shuler, Richard Brad Cragun
Abstract: Emulsion explosives with gas bubbles that are resistant to in-borehole migration or coalescence are disclosed herein. Such emulsions can be sensitized by mechanically-introducing gas bubbles into the emulsion. Resistance to gas bubble migration and coalescence can be achieved by homogenization, without the need for bubble stabilization agents.
Type:
Grant
Filed:
January 25, 2019
Date of Patent:
August 30, 2022
Assignee:
Dyno Nobel Inc.
Inventors:
John B. Halander, Casey L. Nelson, Cornelis L. Kome
Abstract: The present invention relates to gas-producing materials, methods of forming gas-producing materials, and uses of gas-producing materials. The gas-producing materials comprise a comminuted foamed polymer, a nitrogen-containing fuel and an oxidiser. The gas-producing materials may be used to suppress a fire.
Abstract: A smoke composition which is effective in the visible and infrared ranges and includes at least one oxidant and at least one reducing agent and at least one smoke agent generating carbon particles. This composition has superchlorinated polyvinyl chloride (C-PVC) as smoke agent, wherein the chlorine content of this smoke agent is between 57% and 70% of the weight of superchlorinated polyvinyl chloride, wherein the composition has 49% to 90% by weight of superchlorinated polyvinyl chloride (C-PVC) based on the total weight of the composition.
Abstract: This invention relates to a thermal hydrogen generator and a process and system for generating hydrogen gas, more specifically to a process and system for generating hydrogen gas by thermally decomposing a metal hydride.
Abstract: Cool burning gas generant compositions for an automotive inflatable restraint system are provided that include a bismuth-containing compound selected from the group consisting of: bismuth citrate, bismuth subsalicylate, bismuth hydroxide, copper bismuth hydroxy nitrate, bismuth subcarbonate, bismuth suboxalate, and combinations thereof. The gas generant comprises at least one copper-containing component. The gas generant includes at least one oxidizer, fuel, and optional coolant. The maximum flame temperature at combustion (Tc) of less than or equal to about 1700K (1,427° C.). The cool burning gas generant composition generates liquid phase combustion products making it suitable for use in a filterless inflatable restraint system. Copper and bismuth present in the cool burning gas generant composition react to form an alloy having a melting point at or near the maximum flame temperature at combustion (Tc).
Type:
Grant
Filed:
August 29, 2019
Date of Patent:
June 28, 2022
Assignee:
Autoliv ASP, Inc.
Inventors:
Ivan V. Mendenhall, Gary K. Lund, Steven M. Cannon
Abstract: A solid rocket propellant includes a binder that has hydroxyl-terminated polybudadiene (HTPB) with a curative that is selected from isocyanate-terminated polyether, isocyanate-terminated polysiloxane, or combinations thereof.
Abstract: An obscurant-emitting composition may comprise an oxidizer comprising a cation comprising at least one of an alkali metal or an alkaline earth metal, and an anion comprising at least one of nitrate, chlorate, bromate, iodate, perchlorate, periodate, or chlorite; a fuel; and a hydrated salt composition, wherein the obscurant-emitting composition comprises between 0.001% and 8% by weight hydrated salt composition.
Abstract: An explosive sheet simulant that uses an ethylene vinyl acetate polymer combined with a mixture of a boron carbide and iron oxide for X-ray attenuating properties, and components of the mixture selected for predetermined flexural modulus combined with particle density, effective atomic number, X-ray transmission properties, or millimeter wave properties.
Type:
Grant
Filed:
March 5, 2021
Date of Patent:
February 22, 2022
Assignee:
The Government of the United States of America, as represented by the Secretary of Homeland Security
Abstract: An energetic material composite comprising fuel particles and a hydrated compound is disclosed. The energetic material composite is formed by dispersing fuel particles, which have a negative standard reduction potential relative to a standard hydrogen electrode, in a solvent containing dissolved hydrate, followed by a removal of solvent. When initiated, the fuel particles react with the water bound in the hydrated compound to release energy and hydrogen gas.