Patents Examined by Alexa Neckel
  • Patent number: 9611340
    Abstract: A catalyst system for the polymerization of olefins may include a first solid catalytic component and a second solid catalytic component. The first solid catalytic component may include: a spherical MgCl2-xROH support; a group 4-8 transition metal; and a diether internal electron donor. The second solid catalytic component may include: a spherical MgCl2-xROH support; a group 4-8 transition metal; and a diether internal electron donor. The first solid catalytic component produces a propylene homopolymer having a Xylene Solubles (XS) value of greater than 2 wt %; and the second solid catalytic component produces a propylene homopolymer having a XS value of less than 2 wt %. The second catalytic component may act as an external electron donor during use, and embodiments herein do not require use of any additional external electron donors to control polymerization and reliably vary the properties of the resulting polymer.
    Type: Grant
    Filed: May 27, 2014
    Date of Patent: April 4, 2017
    Assignee: Lummus Novolen Technology GmbH
    Inventors: Yvonne Denkwitz, Oliver Schuster, Andreas Winter
  • Patent number: 9593175
    Abstract: Provided are a solid titanium catalyst component for ethylene polymerization which can polymerize ethylene at a high activity and which can provide an ethylene polymer having an excellent particle property, an ethylene polymerization catalyst and an ethylene polymerization method in which the catalyst is used. The solid titanium catalyst component (I) for ethylene polymerization according to the present invention is obtained by bringing a liquid magnesium compound (A) including a magnesium compound, an electron donor (a) having 1 to 5 carbon atoms and an electron donor (b) having 6 to 30 carbon atoms into contact with a liquid titanium compound (C) under the presence of an electron donor (B) and includes titanium, magnesium and a halogen. The ethylene polymerization catalyst of the present invention includes the component (I) and an organic metal compound catalyst component (II).
    Type: Grant
    Filed: April 3, 2009
    Date of Patent: March 14, 2017
    Assignee: MITSUI CHEMICALS, INC.
    Inventors: Kazuhisa Matsunaga, Hideki Yamamoto, Kunio Yamamoto, Tetsunori Shinozaki, Kiyoshi Takahashi
  • Patent number: 9580599
    Abstract: Provided is a thermoplastic resin composition which exhibits little dependence of air permeability on fatigue. The present invention is a thermoplastic resin composition which comprises an ethylene-vinyl alcohol copolymer and a polyamide resin, said thermoplastic resin composition being characterized in that only one maximal peak point assignable to crystallization is observed in the curve of heat flow versus temperature as determined by differential scanning calorimetry of a melt-kneaded mixture of 25 parts by mass of the ethylene-vinyl alcohol copolymer and 75 parts by mass of the polyamide resin in a cooling process.
    Type: Grant
    Filed: November 19, 2012
    Date of Patent: February 28, 2017
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventor: Shun Sato
  • Patent number: 9574018
    Abstract: The present invention relates to a method for consecutively producing at least two different polyethylene resins in one slurry loop reactor, comprising producing a first polyethylene resin in the presence of a Ziegler-Natta and/or a Chromium catalyst, and consecutively producing a second polyethylene resin in the presence of a metallocene catalyst, characterized in that the ratio of the melt flow index of the first produced polyethylene resin to the melt flow index of the second produced polyethylene resin is at least 0.3.
    Type: Grant
    Filed: July 29, 2011
    Date of Patent: February 21, 2017
    Assignee: TOTAL RESEARCH & TECHNOLOGY FELUY
    Inventors: Peter Stevens, Franky Fant, Daan Dewachter, Alain Brusselle
  • Patent number: 9574077
    Abstract: The present invention relates to aqueous polymer dispersions having a polymer content of at least 55% by weight that are suitable for pressure sensitive adhesives. The invention also relates to a process for preparing these aqueous polymer dispersions and also to the use of the aqueous polymer dispersions in pressure sensitive adhesives and, respectively, pressure sensitive adhesive compositions, especially in pressure sensitive adhesives for transparent substrates, such as plastics labels. The aqueous polymer dispersions have a polymer content of at least 55% by weight, based on the total weight of the dispersion, the polymer being composed of ethylenically unsaturated monomers M and having a glass transition temperature below ?10° C., in which the dispersed polymer particles have a polymodal particle size distribution, in which at least 70% by weight have a particle diameter of below 350 nm.
    Type: Grant
    Filed: January 4, 2016
    Date of Patent: February 21, 2017
    Assignee: BASF SE
    Inventors: Matthias Gerst, Gerhard Auchter, Gledison Fonseca, Cornelis Petrus Beyers
  • Patent number: 9562119
    Abstract: The present invention relates to solid catalyst components comprising a reaction product of a titanium compound, a magnesium compound, an alcohol, an aluminum alkoxide, a siloxane mixture, and a maleate derivative; and catalyst systems comprising the solid catalyst components and organoaluminum compounds. The present invention also relates to methods of making the solid catalyst components and the catalyst systems, and methods of polymerizing or copolymerizing ethylene using the catalyst systems.
    Type: Grant
    Filed: May 25, 2010
    Date of Patent: February 7, 2017
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Main Chang, Thomas Garoff
  • Patent number: 9556295
    Abstract: Procatalyst comprising an inorganic support, a chlorine compound carried on said support, a magnesium compound carried on said support, a titanium compound carried on said support, and a compound comprising two oxygen containing rings, wherein said two rings are linked via a bridge selected from the group consisting of carbon bridge, silicon bridge, ethane-1.2-diyl bridge, ethene-1,2-diyl bridge, alkylaminomethyl bridge and imine bridge.
    Type: Grant
    Filed: April 28, 2014
    Date of Patent: January 31, 2017
    Assignee: Borealis AG
    Inventors: Irfan Saeed, Esa Kokko, Paivi Waldvogel, Marja Mustonen, Thomas Garoff
  • Patent number: 9550909
    Abstract: A slurry composition, including: a polyvinyl acetal resin; a ceramic powder; and an organic solvent. The polyvinyl acetal resin has a degree of polymerization of from 200 to 6000, a content percentage of vinylester unit of from 0.01 to 30 mol %, and a degree of acetalization of from 55 to 83 mol %.
    Type: Grant
    Filed: October 13, 2015
    Date of Patent: January 24, 2017
    Assignee: KURARAY CO., LTD.
    Inventor: Yuhi Shimazumi
  • Patent number: 9534132
    Abstract: A hydrophilic surface treatment agent for an aluminum-containing metallic heat exchanger, which is obtained by mixing: a water-soluble resin (A) having at least one or more functional groups of an amide group, a hydroxyl group, and a carboxyl group, or a water-soluble resin (A) including, in a skeleton thereof, an amide linkage; colloidal silica (B); organo alkoxy silane and/or a hydrolysate thereof (C); a cross-linking agent (D) capable of forming cross-linkage with the water-soluble resin (A); and water (E), wherein the ratio {(B)+(C)}/{(A)+(B)+(C)+(D)} is 0.1 to 0.5 in terms of solid content ratio (mass ratio), and the ratio (C)/(B) is 0.5 to 4.0 in terms of solid content ratio (mass ratio).
    Type: Grant
    Filed: March 21, 2013
    Date of Patent: January 3, 2017
    Assignee: Nihon Parkerizing Co., Ltd.
    Inventors: Tomohiro Osako, Hyonsoo Ahn, Takaomi Nakayama
  • Patent number: 9512244
    Abstract: The invention relates to a process for preparing a polymerization catalyst component wherein a solid compound with formula Mg(OR1)xCl2-x wherein x is larger than 0 and smaller than 2, and each R1, independently, represents an alkyl group, said compound being obtained by reacting a Grignard compound with an alkoxy- or aryloxy-containing silane compound, is contacted with at least one activating compound selected from the group formed by internal electron donors and compounds of formula M(OR2)v-w(R3)w, wherein M can be Ti, Zr, Hf, Al or Si, each R2 and R3, independently, represent an alkyl, alkenyl or aryl group, v is the valency of M and w is smaller than v, in the presence of an inert dispersant to give an intermediate reaction product, and wherein the intermediate reaction product is contacted with a halogen-containing Ti-compound. A catalyst system comprising said component shows improved performance in olefin polymerization.
    Type: Grant
    Filed: May 23, 2007
    Date of Patent: December 6, 2016
    Assignee: SAUDI BASIC INDUSTRIES CORPORATION
    Inventors: Yves Johann Elizabeth Ramjoie, Mark Vlaar, Nicolaas Hendrika Friederichs, Sergei Andreevich Sergeev, Vladimir Aleksandrovich Zakharov, Gennadii Dimitrievich Bukatov, Mansour Taftaf, Atieh Aburaqabah
  • Patent number: 9505865
    Abstract: The present invention provides polyvinyl acetal fine particles for an aqueous dispersion which exhibit excellent dispersion stability in a water-containing dispersion medium, and allow for formation of a film having sufficient mechanical strength and flexibility without voids and non-uniform structures such as irregularities, and an aqueous dispersion of the polyvinyl acetal fine particles for an aqueous dispersion. The polyvinyl acetal fine particles for an aqueous dispersion, adapted for use as dispersoids in an aqueous dispersion, the polyvinyl acetal fine particles including a polyvinyl acetal resin with an ionic functional group, and having a volume average particle size of 10 nm to 100 ?m, and a CV value of a volume-based particle size distribution of at most 40%.
    Type: Grant
    Filed: September 24, 2013
    Date of Patent: November 29, 2016
    Assignee: SEKISUI CHEMICAL CO., LTD.
    Inventor: Yasuharu Nagai
  • Patent number: 9505950
    Abstract: A polishing composition includes a water-soluble polymer having a weight average molecular weight of 1000000 or less and a molecular weight distribution represented by weight average molecular weight (Mw)/number average molecular weight (Mn) that is less than 5.0. The polishing composition is mainly used in an application for polishing a substrate, preferably in an application for performing final polishing on a substrate.
    Type: Grant
    Filed: August 12, 2013
    Date of Patent: November 29, 2016
    Assignee: FUJIMI INCORPORATED
    Inventors: Kohsuke Tsuchiya, Shuhei Takahashi
  • Patent number: 9505855
    Abstract: The present invention relates to catalysts systems for the polymerization of olefins CH2?CHR, wherein R is an alkyl, cycloalkyl or aryl radical having 1-12 carbon atoms, comprising (A) a solid catalyst component comprising Ti, Mg, and halogen (B) an aluminum alkyl compound and (C) a mono or dihalogenated hydrocarbon compound. Said catalyst systems have improved polymerization activity.
    Type: Grant
    Filed: June 8, 2009
    Date of Patent: November 29, 2016
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Masaki Fushimi, Gerhardus Meier, Maclovio Herrera Salinas, Martin Schneider, Giampiero Morini
  • Patent number: 9505856
    Abstract: Methods for preparing a fluorided chromium catalyst can include a step of calcining a supported chromium catalyst at a peak calcining temperature to produce a calcined supported chromium catalyst, followed by contacting the calcined supported chromium catalyst at a peak fluoriding temperature with a vapor comprising a fluorine-containing compound to produce the fluorided chromium catalyst. The peak fluoriding temperature can be at least 50° C. less, and often from 200° C. to 500° C. less, than the peak calcining temperature. Polymers produced using the fluorided chromium catalyst can have a beneficial combination of higher melt index, narrower molecular weight distribution, and lower long chain branch content.
    Type: Grant
    Filed: January 13, 2016
    Date of Patent: November 29, 2016
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Eric D. Schwerdtfeger, Kathy S. Clear, Max P. McDaniel
  • Patent number: 9493629
    Abstract: An object of the present invention is to improve, in the raw material rubber compound particularly using a silica-based filler, which is used for tire tread, the balance between the rolling resistance and the skid resistance on a wet road surface and at the same time, improve the wear resistance is enhanced. The present invention provides an oil-extended polymer composition comprising 100 parts by weight of (A) a polymer having a number average molecular weight Mn of 500,000 to 700,000 and a content of a functional group-containing polymer component to be adsorbed to silica of 50 wt % or more, and from 20 to 60 parts by weight of (B) an extender oil.
    Type: Grant
    Filed: March 29, 2006
    Date of Patent: November 15, 2016
    Assignee: ASAHI KASEI CHEMICALS CORPORATION
    Inventors: Haruo Yamada, Takaaki Matsuda, Yuichi Kitagawa
  • Patent number: 9486746
    Abstract: Technologies and implementations for providing melt processable poly(vinyl alcohol) blends and poly(vinyl alcohol) based membranes are generally disclosed.
    Type: Grant
    Filed: October 28, 2013
    Date of Patent: November 8, 2016
    Assignee: EMPIRE TECHNOLOGY DEVELOPMENT LLC
    Inventor: Carlos A. Cruz
  • Patent number: 9487597
    Abstract: The present invention pertains to new alkali swellable thickening emulsions, free of surfactants and solvents other than water: as a result, all drawbacks related to the use of solvents, or to the formation of foam in the case of surfactants, are avoided. These new emulsions contain a certain quantity of 2-acrylamido-2-methylpropane sulfonic acid (or AMPS, CAS #: 40623-75-4). They have proven effective at thickening aqueous mediums, particularly water-based paints, paper coatings, aqueous suspensions of mineral materials, detergents, cosmetic formulations, or formulations containing a hydraulic binder.
    Type: Grant
    Filed: June 15, 2011
    Date of Patent: November 8, 2016
    Assignee: COATEX S.A.S.
    Inventor: Jean-Marc Suau
  • Patent number: 9487604
    Abstract: The present invention relates to preparing high 1,4-trans-polybutadiene by polymerizing 1,3-butadiene or a butadiene derivative in a non-polar solvent in the presence of a catalyst system comprising a novel bimetallic cobalt-aluminum adduct, which makes it possible to prevent gel formation, control the molecular weight of the trans-polybutadiene and increase the trans content of the trans-polybutadiene. The catalyst system comprising the novel cobalt-aluminum adduct has a high oxidation state and structural stability, and the reactivity of the catalyst is controlled using novel activation systems comprising various allyloxy aluminum compounds.
    Type: Grant
    Filed: November 25, 2013
    Date of Patent: November 8, 2016
    Assignee: Korea Kumho Petrochemical Co., Ltd.
    Inventors: Hanbaek Lee, Gwanghoon Kwag, Hoochae Kim, Seunghyun Do, Bunyeoul Lee, Jihae Park, Ahreum Kim
  • Patent number: 9469797
    Abstract: A pressure sensitive adhesive composition comprising the polymerization product of: (A) a monomer selected from the group consisting of alkyl acrylates, alkyl methacrylates, and combinations thereof; and (B) a macromonomer comprising the reaction product of (a) a hydroxy-functional, ethylenically unsaturated monomer (e.g., an alkyl acrylate or methacrylate where the alkyl group is a C1-C6 alkyl group), (b) a bio-based monomer, and (c) a modifying monomer that lowers the Tg of the macromonomer relative to the Tg of the same macromonomer prepared in the absence of the modifying monomer.
    Type: Grant
    Filed: August 11, 2011
    Date of Patent: October 18, 2016
    Assignee: Regents of the University of Minnesota
    Inventors: Monique Roerdink Lander, Jiguang Zhang, Steven J. Severtson
  • Patent number: 9464204
    Abstract: The present invention is a composition comprising a stable aqueous dispersion of polymer particles comprising structural units of a nonionic monoethylenically unsaturated monomer; 2-(methacryloyloxy)ethyl phosphonic acid (MEP) or a salt thereof; and a sulfur acid monomer or carboxylic acid monomer or a combination thereof or a salt thereof, as well as a composite comprising the polymer particles adsorbed to the surface of a pigment particle such as TiO2. The composition and composite are prepared using the phosphorus acid monomer MEP, which can be prepared in high purity with low residual non-polymerizable phosphorus acid, thereby reducing the load of neutralizing agent required to achieve the targeted pH as compared with phophoethyl methacrylate (PEM).
    Type: Grant
    Filed: November 26, 2013
    Date of Patent: October 11, 2016
    Assignee: Rohm and Haas Company
    Inventors: James C. Bohling, Arnold S. Brownell, Muhunthan Sathiosatham