Abstract: Well-cementing compositions for use in high-pressure, high-temperature (HPHT) wells are often densified, and contain weighting agents such as hematite, ilmenite, barite and hausmannite. The weighting agents are usually finely divided to help keep them suspended in the cement slurry. At high temperatures, finely divided weighting agents based on metal oxides react with the calcium-silicate-hydrate binder in set Portland cement, leading to cement deterioration. Finely divided weighting agents based on metal sulfates are inert with respect to calcium silicate hydrate; consequently, set-cement stability is preserved.

Abstract: Incorporation of carbonaceous materials in a cement slurry increases the linear thermal-expansion coefficient of the set cement. When placed in a subterranean well having at least one casing string, cement sheaths with linear thermal-expansion coefficients similar to that of the casing will be subjected to lower compressive and tensile stresses during downhole-temperature changes. Such cement slurries are particularly advantageous in the context of thermal-recovery wells.

Abstract: One or more specific embodiments herein includes a method for recovering hydrocarbon gas from a shale formation comprising injecting oxidizer through a horizontal wellbore into a fracture in the shale formation comprising pores containing hydrocarbon gas, and recovering some of the hydrocarbon gas from the shale formation. Some of the injected oxidizer combusts and increases the temperature of a portion of the shale formation and of the hydrocarbon gas contained in some of the pores in the shale formation, the pressure of some of the hydrocarbon gas increases to a point sufficient to cause formation of new fractures, and some of the hydrocarbon gas passes from the pores through some of the new fractures and is recovered. Preferably, one or more specific embodiments further comprises injecting hydraulic fracturing fluid into the first fracture after the one or more second fractures is formed, sometimes referred to as re-fracing.

Abstract: The present invention relates to in situ methods of separating, refining and extracting hydrocarbons from an oil formation. In embodiments of the present invention the in situ methods includes: (a) making a perforation in the oil sand formation, (b) disposing a non-polar substance into the perforation without addition of polar fluid, (c) subjecting the non-polar fluid composition disposed in the perforation to ultrasonic vibrations, and (d) extracting the hydrocarbon from the perforation in the oil sand formation. The present invention relates also to methods of separating, refining and extracting hydrocarbons from hydrocarbon matrices such as oil sand or oil shale.

Abstract: Methods of propping subterranean fractures using swellable particulates. Some methods alternate the placement into a fracture of proppant and swellable particulates. Other methods alternate the placement into a fracture of proppant-free fluid and swellable particulates. Still other methods combine proppant and swellable particulates into a single fluid and place that fluid into a subterranean fracture. The methods are useful for treatment of low closure stress formations.

Abstract: A spacer fluid made of a viscosity thinner, a weighting agent, an antifoaming agent, and a non-ionic surfactant in a base aqueous fluid. In some instances, the viscosity thinner is a sulfomethylated tannin, the weighting agent is barium sulfate, the antifoaming agent is a silicone, and the non-ionic surfactant is an ethoxylated alcohol. A method of treating a well bore annulus in preparation of introducing water-based cement slurry into a well bore using the spacer fluid. A method of using the spacer fluid to position a first fluid into a well bore annulus of a well bore containing a second fluid. A method for fluidly isolating at least a portion of a well bore annulus in a well bore containing an oil-based drilling fluid using water-based cement slurry and the spacer fluid.

Abstract: A one trip system for perforating and fracking multiple intervals uses a releasable barrier. The barrier can be an inflatable. A pressure booster system is associated with the BHA so that the existing hydrostatic pressure is boosted when the gun or portions thereof are fired. After firing in one interval, the BHA is raised and the barrier is redeployed and the pattern repeats. Instruments allow sensing the conditions in the interval for optimal placement of the gun therein and for monitoring flow, pressure and formation conditions during the fracturing. Circulation between gun firings cleans up the hole. If run in on wireline a water saving tool can be associated with the BHA to rapidly position it where desired. A multitude of perforation charges mounted in the BHA can be selectively fired by selected corresponding detonator based on a predetermined sequence or surface telemetry command.

Abstract: A one trip system for perforating and fracking multiple intervals uses a releasable barrier. The barrier can be an inflatable. A pressure booster system is associated with the BHA so that the existing hydrostatic pressure is boosted when the gun or portions thereof are fired. After firing in one interval, the BHA is raised and the barrier is redeployed and the pattern repeats. Instruments allow sensing the conditions in the interval for optimal placement of the gun therein and for monitoring flow, pressure and formation conditions during the fracturing. Circulation between gun firings cleans up the hole. If run in on wireline a water saving tool can be associated with the BHA to rapidly position it where desired. A multitude of perforation charges mounted in the BHA can be selectively fired by selected corresponding detonator based on a predetermined sequence or surface telemetry command.

Abstract: A well chemical treatment system includes a chemical dispenser having a control signal input and a chemical outlet in fluid communication with a well. A chemical dispenser controller operates the dispenser and detects a well fluid lift pump controller signal. The chemical dispenser controller transmits a control signal to the chemical dispenser at selected times and is configured to increment the counter and inhibit transmission of the control signal when a selected time occurs and a pump in operation signal is not detected. When the chemical dispenser controller detects a pump in operation signal at one of the selected times, the chemical dispenser controller sends a control signal to the chemical dispenser to dispense an amount of chemical into the well equal to a product of a number in the counter plus one and an amount of chemical to be dispensed into the well at each selected time.

Abstract: A method for heating heavy oil inside a production well. The method raises the subsurface temperature of heavy oil by utilizing an activator that has been injected below the surface. The activator is then excited with a generated non-microwave frequency from 0.1 MHz to 300 MHz such that the excited activator heats the heavy oil.

Abstract: An electrophilic acid gas-reactive fracturing and recovery fluid, proppant, and process are detailed. The fluid expands in volume to provide rapid and controlled increases in pressure that enhances fracturing in subterranean bedrock for recovery of energy-producing materials. Proppants stabilize openings in fractures and fissures following fracturing.

Abstract: A method of installing a pressure transducer in a borehole to measure the fluid prepare of a geological formation. The pressure transducer is installed into the borehole at a desired depth, and then the borehole is filled with a cement grout. The fluid connection between the pressure transducer and the formation is opened by pumping a fluid through tubing to displace the cement grout. A process of hydrofracture can be employed to provide a communication path of fluid between the formation and the pressure transducer surrounded by the fractured grout. In one embodiment of the invention, a pressure transducer is cemented into the borehole along with a check and pressure relief valve. In another embodiment, the pressure transducer is installed in the tubing at a subsequent stage.

Abstract: A method of treating a zone of a subterranean formation penetrated by a wellbore, the method including the steps of: (a) forming a treatment fluid comprising: (i) water; (ii) a strong acid); (iii) a water-soluble polymer having at least one functional group that can be crosslinked with aluminum(III); (iv) a water-soluble aluminum carboxylate; and (v) a complexion agent for calcium ions; wherein the pH of the treatment fluid is less than the pH required for the aluminum to crosslink the polymer to form a crosslinked gel; (b) introducing the treatment fluid through the wellbore into the zone; and (c) allowing time for the strong acid in the treatment fluid to spend in the formation such that the pH of the fluid increases sufficiently for the aluminum of the aluminum carboxylate to crosslink the polymer.

Abstract: A method using a propping fluid comprising a first carrier fluid and a plurality of propping agents and a spacer fluid comprising a second carrier fluid and an expandable filler material. The method introduces the propping fluid into a fracture in a subterranean formation and introduces the spacer fluid into the fracture. Then the expandable filler material is exposed to an expanding agent that causes the expandable filler material to expand and press against the adjacent propping agents.

Abstract: Methods of treating a fluid loss zone in a wellbore in a subterranean formation including providing swellable particles having an initial unswelled volume, wherein the swellable particles upon swelling adopt a specific shape; introducing the swellable particles into the wellbore in the subterranean formation; and swelling the swellable particles so as to adopt a swelled volume beyond the initial unswelled volume; and sealing at least a portion of the fluid loss zone.

Abstract: A method for injecting treatment chemical into a well includes selecting times at which to operate a chemical dispenser to inject a selected amount of treatment chemical into a well. At each selected time whether a wellbore pump is operating is determined. If the pump is operating the selected amount of treatment chemical is dispensed into the well. If the pump is not operating, no chemical is dispensed and a counter is incremented. At each subsequent selected time, the determining whether the well pump is operating is repeated. When a subsequent selected time coincides with a time at which the well pump is determined to be operating, the chemical dispenser is operated to inject a product of the number in the counter plus one, and the selected amount of treatment chemical into the well.

Abstract: Disclosed herein are methods for extracting a kerogen-based product from subsurface shale formations. The methods utilize in-situ reaction of kerogen involving liquid phase chemistry at ambient temperatures at pressures for the subsurface shale formation. These methods rely on chemically modifying the shale-bound kerogen to render it mobile using metal particulate catalysts. In the methods disclosed herein a fluid comprising metal is provided to the subsurface shale formation comprising kerogen in an inorganic matrix. A reducing agent is provided to the subsurface shale formation. The kerogen is converted by contacting the kerogen with a metal particulate catalyst formed from the metal; and a mobile kerogen-based product is formed. At least a portion of the mobile kerogen-based product is recovered. The kerogen-derived product can be upgraded to provide commercial products.

Abstract: An aqueous composition for removing scale deposits, especially on subsea equipment and a method of using the same. The aqueous composition comprises (a) a potassium phosphate compound; and (b) acetic acid. The composition is capable of dissolving away into seawater and poses little or no risk to the environment.

Abstract: Methods of processing a fluid recovered from an oil or gas extraction operation for reuse in a hydraulic fracturing fluid are described. The methods include providing an amount of a produced fluid composition containing iron and suspended solids and controlling at least one of the conductivity, iron content, oxidative strength, and pH of the composition, such that Fenton's reagent is formed in situ. Also described are hydraulic fracturing fluids produced using fluid recovered from an oil or gas production process and treated in accordance with the methods described herein as well as systems for preparing a hydraulic fracturing fluid having, as a fluid source, fluid recovered from an oil or gas production process that has been treated in accordance with the methods described herein.

Abstract: A cement composition comprises: cement; water; and an additive, wherein the additive is a pozzolan and a strength-retrogression inhibitor, and wherein a mixture consisting essentially of: the additive; water; and a source of calcium develops a compressive strength of at least 500 psi at a time of 24 hours, a temperature of 190° F., and a pressure of 3,000 psi. A method of cementing in a subterranean formation comprises: introducing the cement composition into the subterranean formation and allowing the cement composition to set. The compressive strength of the test cement composition consisting essentially of: the cement; the water; and the additive at a final time of 72 hours has a percent change greater than ?5% from the compressive strength of the test cement composition at an initial time of 24 hours when tested at a temperature of 300° F. and a pressure of 3,000 psi.