Abstract: Disclosed herein are compositions, processes, and systems for deploying and creating a temporary fluid barrier at an interface between a high fluid conductivity zone and a lower fluid conductivity zone. The disclosed compositions include mixtures of solvents and biodegradable non-spherical particles, wherein the particles include a coating that may slow or inhibit degradation, for example by hydrolysis, of the particle. The disclosed particles are designed to possess sufficient flexibility to traverse the high conductivity zone.
Abstract: Lost circulation material (LCM) compositions may include an epoxy resin, an emulsifier comprising a polyaminated fatty acid, water, a crosslinker, and an optional cementitious and/or weighting agent. These LCM compositions may have a density of from about 63 pounds per cubic foot (pcf) to about 99 pcf and may be capable of being injected through a drill bit of a drill string into a lost circulation zone in wellbores. Corresponding methods of eliminating or reducing lost circulation in a lost circulation zone from a well may include introducing these LCM compositions into the well.
Type:
Grant
Filed:
February 25, 2021
Date of Patent:
August 29, 2023
Assignee:
SAUDI ARABIAN OIL COMPANY
Inventors:
Ali Al-Safran, Khawlah A. Alanqari, Vikrant Wagle, Abdulwahab Al-Joher, Abdullah S. Al-Yami
Abstract: Methods include pumping a fracturing pad fluid into a subterranean formation under conditions of sufficient rate and pressure to create at least one fracture in the subterranean formation, the fracturing pad fluid including a carrier fluid and a plurality of bridging particles, the bridging particles forming a bridge in a fracture tip of a far field region of the formation. Methods further include pumping a first plurality of fibers into the subterranean formation to form a low permeability plug with the bridging particles, and pumping a proppant fluid comprising a plurality of proppant particles.
Type:
Grant
Filed:
April 3, 2019
Date of Patent:
August 22, 2023
Assignee:
Schlumberger Technology Corporation
Inventors:
Konstantin Vidma, Anna Dunaeva, Changsheng Xiang, Jazmin Godoy-Vargas, Mohan Kanaka Raju Panga, John Thomas Mayo, Dmitriy Usoltsev, Jacob Kariampally
Abstract: Compositions and methods involving polyvalent cation reactive polymers for use as lost circulation materials in subterranean treatment operations are provided. In some embodiments, the methods include forming a treatment fluid including a base fluid, a source of a polyvalent cation, a polyvalent cation reactive polymer, and an acid precursor; introducing the treatment fluid into a wellbore penetrating at least a portion of a subterranean formation; and allowing the treatment fluid to at least partially set.
Type:
Grant
Filed:
April 11, 2022
Date of Patent:
August 8, 2023
Assignee:
Halliburton Energy Services, Inc.
Inventors:
Preston Andrew May, Hui Zhou, Jay Deville
Abstract: A method and hydraulic fracturing fluid that is a viscoelastic surfactant (VES) fracturing fluid having a surfactant and an inorganic oxidizer salt for hydraulic fracturing of a geological formation. The VES fracturing fluid is provided through a wellbore into the geological formation to hydraulically fracture the geological formation to form hydraulic fractures in the geological formation. The method includes oxidizing organic material in the hydraulic fractures with the VES fracturing fluid.
Abstract: Unconventional hydrocarbon source rock reservoirs can contain the organic material kerogen, intertwined with the rock matrix. The kerogen can alter the tensile strength of the rock and contribute to higher fracture energy needs. To degrade kerogen and other organic materials, oxidizing gasses are dissolved in carbon dioxide (CO2) which is then used as part of a fracturing fluid. The oxidizing gasses can be dissolved directly in the CO2 or generated in situ using precursors.
Abstract: A method for zonal isolation in a subterranean formation includes identifying a zone of interest within the subterranean formation, determining a static temperature of the zone of interest, determining a time duration for gelation of a treatment fluid, determining a concentration of a cross-linker in the treatment fluid, determining a volume of the treatment fluid to be delivered to the zone of interest, determining a correlation between cooling of a wellbore near the zone of interest and a delivery rate of the treatment fluid, determining a target wellbore temperature, delivering a cooling stage until the target wellbore temperature is reached, and delivering a treatment stage. Delivering the cooling stage and the treatment stage results in forming, within the zone of interest, a gel that is impermeable to fluid flow.
Type:
Grant
Filed:
December 14, 2021
Date of Patent:
July 25, 2023
Assignee:
Saudi Arabian Oil Company
Inventors:
Mohamed Hassan Sherief, Ayman Mohammed Almohsin, Haider J. Abdulal, Mohammed I. Alabdrabalnabi
Abstract: Some embodiments of the present disclosure provide a method for preparing a self-phase change proppant based on an emulsified and toughened bio-based epoxy resin. Toughening modification is performed on the bio-based epoxy resin by graphite particles, and then the bio-based epoxy resin after the toughening modification is emulsified by SiO2 particles as an emulsifier to prepare the self-phase change proppant; a proportion of different mesh numbers in the self-phase change proppant is adjusted by changing a concentration of the emulsifier during emulsification; and the chemical formula of the bio-based epoxy resin is: The proppant particles in the present disclosure have good sphericity and high fracture permeability after being laid, which can effectively extract the remaining oil in the fractures, thus improving the development efficiency of the oilfield.
Type:
Grant
Filed:
August 29, 2022
Date of Patent:
July 25, 2023
Assignee:
CHINA UNIVERSITY OF PETROLEUM (EAST CHINA)
Abstract: A method of stimulating petroleum production includes introducing a fracturing fluid into a petroleum bearing carbonate formation, thereby creating at least one fracture to stimulate the petroleum production. The fracturing fluid is introduced into the petroleum bearing carbonate formation at a pressure above the breakdown pressure of the formation. The fracturing fluid includes a plurality of proppants where from 1 to 50 wt. % of the plurality of proppants includes micro proppants having a particle size ranging from 0.5 to 150 ?m, and from 50 to 99 wt. % of the plurality of proppants includes macro proppants having a particle size greater than 100 mesh.
Type:
Grant
Filed:
December 17, 2021
Date of Patent:
July 18, 2023
Assignee:
Saudi Arabian Oil Company
Inventors:
Rajesh Kumar Saini, Katherine Hull, Mohammad H. Haque
Abstract: A system for utilizing oolitic aragonite as a proppant in hydraulic fracking is provided. The system includes a proppant storage tank including a stockpile of the oolitic aragonite. The system further includes a proppant pumping unit operable to pump the oolitic aragonite from the proppant storage tank, through an underground shaft, and into an underground fracture proximate to the underground shaft.
Type:
Grant
Filed:
January 24, 2022
Date of Patent:
July 11, 2023
Assignee:
Pisa Carolina, LLC
Inventors:
James Duane Stover, Jayson Alexander Meyers
Abstract: A method comprising: introducing a first fluid into a wellbore above a fracture gradient of a subterranean formation penetrated by the wellbore to create a first plurality of fractures within a first portion of the subterranean formation; introducing a second fluid comprising at least one acid component into the wellbore above the fracture gradient of the subterranean formation penetrated by the wellbore to create a second plurality of fractures within a second portion of the subterranean formation; allowing the second fluid to enter at least one natural fracture in the first or second portion of the subterranean formation allowing the acid component to dissolve at least a portion of the subterranean formation to form one or more induced fractures in fluidic communication with the natural fracture, at least some of the first plurality of fractures, and at least some of the second plurality of fractures.
Type:
Grant
Filed:
March 3, 2022
Date of Patent:
July 11, 2023
Assignee:
Halliburton Energy Services, Inc.
Inventors:
Ronald Glen Dusterhoft, Neil Alan Stegent, Robert Barree, Victor Daniel Escobar Acosta, Maharaja Palanivel
Abstract: Provided herein are drilling muds, including water-based drilling muds. The components of the drilling muds are a degradable fluid loss additive, for example, synthetic degradable nanoparticles, a clay mineral, for example, a smectite, and a base fluid, for example, water. Also provide are methods for preventing leak-off during a drilling operation and for automatically cleaning-up filter cake after completion of a drilling process both of which utilize the drilling muds and water-based drilling muds.
Abstract: The present invention discloses a method for realizing uniform stimulation for the oil and gas well by low-cost multi-stage fracturing, comprising the following steps: first calculate and predict the inlet widths of the fracture created in the planned hydraulic fracturing; then design the plugging scheme for blocking the fracture inlet after each fracturing treatment; the selected plugging particles are composed of filling particles and skeleton particles, with designed plugging scheme; after complete the design of plugging scheme, perform the fracturing treatment to create hydraulic fracturing in the reservoir; skeleton particles and filling particles are added into the fractures successively according to plan. The present invention provides a multi-stage single-cluster fracturing method, with the advantages of controllable fracture sizes and low cost. The present invention can realize a good uniformity of stimulation for the oil and gas wells.
Abstract: A method, wellbore, and pill for treating a region of a subterranean formation adjacent a wellbore zone of the wellbore, including injecting a gellable treatment composition (e.g., as the pill) through the wellbore zone into the region of the subterranean formation adjacent the wellbore zone, allowing the gellable treatment composition to form nanoparticles in-situ in the region and gel in the region via heat provided by the region to prevent or reduce flow of an unwanted fluid from the region into the wellbore zone. The gellable treatment composition may include a zwitterionic gemini surfactant (ZGS).
Type:
Grant
Filed:
October 25, 2021
Date of Patent:
June 27, 2023
Assignee:
Saudi Arabian Oil Company and King Fahd University of Petroleum & Minerals
Inventors:
Rajendra Arunkumar Kalgaonkar, Eyad Alali, Mohammed A. Bataweel, Nisar Ullah, Muhammad Mansha
Abstract: A system includes a casing, a tubing within the casing, a packer, and a colloidal silica gel. The casing inner surface and the tubing outer surface define an annular space, and the packer is within the annular space. The colloidal silica gel which seals a gap. The gap can be a gap between the inner surface of the casing and a surface of the packer, a gap between the outer surface of the tubing and a surface of the packer, and/or a gap extending through the packer. A well can include such a system. A method of sealing a leak in or near a packer present in an annular space between a production casing inner surface and a tubing outer surface includes disposing a composition within the annular space, the composition comprising colloidal silica, water, and an activator.
Type:
Grant
Filed:
March 31, 2022
Date of Patent:
June 20, 2023
Assignee:
Saudi Arabian Oil Company
Inventors:
Faisal Alissa, Abdulrahman Ghazal, Haitham Aljuaydi, Abdullah Alzahrani
Abstract: Methods and system for using salting out inhibitors in subterranean formations are provided. In some embodiments, the methods comprise introducing a treatment fluid comprising an aqueous base fluid, a salting out inhibitor, a gelling agent, and one or more salts into at least a portion of a subterranean formation, wherein the salting out inhibitor is selected from the group consisting of: an oligomer comprising one or more quaternary ammonium cations, a polymer comprising one or more quaternary ammonium cations, a source of one or more phosphate anions, and any combination thereof.
Abstract: A treatment fluid can be provided for controlling annular pressure-buildup in a wellbore. The treatment fluid can include a base fluid and a pozzolanic material that can be dispersed within the base fluid. The pozzolanic material can cause the treatment fluid to controllably consolidate in an annulus of the wellbore for controlling annular pressure-buildup in the wellbore.
Type:
Grant
Filed:
October 28, 2021
Date of Patent:
June 13, 2023
Assignee:
Halliburton Energy Services, Inc.
Inventors:
James Benkley, Thomas Jason Pisklak, Samuel J. Lewis
Abstract: A variety of methods, compositions, and systems are disclosed, including, a method comprising: introducing a treatment fluid into a wellbore penetrating a subterranean formation wherein the treatment fluid comprises: a base fluid; and multi-grade diverting particulates, wherein the multi-grade diverting particulates comprise a degradable polymer, wherein the degradable polymer comprises a first portion of the degradable polymer and a second portion of the degradable polymer of different grades, wherein the multi-grade diverting particulate at least partially plugs a zone in the subterranean formation; and diverting at least a portion of the treatment fluid and/or a subsequently introduced fluid away from the zone.
Type:
Grant
Filed:
June 22, 2022
Date of Patent:
June 6, 2023
Assignee:
Halliburton Energy Services, Inc.
Inventors:
Travis Hope Larsen, Aaron Michael Beuterbaugh, Larry Steven Eoff
Abstract: Release of hydrochloric acid, hydrofluoric acid and fluoroboric acid into a well may be controlled by introducing into the well an aqueous fluid containing ammonium chloride, ammonium bifluoride, ammonium fluoroborate, ammonium tetrafluoroborate or a mixture thereof and a breaker. After being introduced into the well, the ammonium salt reacts with the breaker and the acid is released into the well.